Kuhn, Gerhard

The continental margin of the Ross Sea has been consistently sensitive to the advance and retreat of the Ross Ice Sheet (RIS) between the interglacial and glacial periods. This study examines changes of the glaciomarine sedimentation on the continental slope and rise to the eastern side of Hillary Canyon in the central Ross Sea, using three gravity cores collected at increasing water depths. Besides older AMS 14C ages of bulk sediments, based on the analytical results, sediment lithology was divided into units A, B1, and B2, representing Holocene, deglacial, and glacial periods, respectively. The sedimentation rate decreased as the water depth increased, with a higher sedimentation rate in the deglacial period (unit B1) than the Holocene (unit A). Biological productivity proxies were significantly higher in glacial unit B2 than in interglacial unit A, with transitional values observed in deglacial unit B1. Biological productivity generally decreased in the Antarctic continental margin during the glacial period because of extensive sea ice coverage. The higher biogenic contents in unit B2 are primarily attributed to the increased transport of eroded and reworked shelf sediments that contained abundant biogenic components to the continental slope and rise beneath the advancing RIS. Thus, glacial sedimentation on the continental slope and rise of the central Ross Sea was generally governed by the activity of the RIS, which generated melt-water plumes and debris flows at the front of the grounding line, although the continental rise might have experienced seasonally open conditions and lateral effects due to the bottom current.

The continental margin is a key area for studying the sedimentary processes related to the advance and retreat of the Ross Ice Shelf (Antarctica); nevertheless, much remains to be investigated. The aim of this study is to increase the knowledge of the last glacial/deglacial dynamics in the Central Basin slope–basin system using a multidisciplinary approach, including integrated sedimentological, micropaleontological and tephrochronological information. The analyses carried out on three box cores highlighted sedimentary sequences characterised by tree stratigraphic units. Collected sediments represent a time interval from 24 ka Before Present (BP) to the present time. Grain size clustering and data on the sortable silt component, together with diatom, silicoflagellate and foraminifera assemblages indicate the influence of the ice shelf calving zone (Unit 1, 24–17 ka BP), progressive receding due to Circumpolar Deep Water inflow (Unit 2, 17–10.2 ka BP) and (Unit 3, 10.2 ka BP–present) the establishment of seasonal sea ice with a strengthening of bottom currents. The dominant and persistent process is a sedimentation controlled by contour currents, which tend to modulate intensity in time and space. A primary volcanic ash layer dated back at around 22 ka BP is correlated with the explosive activity of Mount Rittmann.

Water masses and depositional environments over the last 500 ka were reconstructed using absolute and relative abundances of lithogenous, biogenous and redox-sensitive elements in four sediment cores from two channel-levee systems of the Wilkes Land continental slope (East Antarctica). Sediments older than the Mid-Bruhnes event (MBE, 430 ka BP) show reduced glacial/interglacial variability in the abundance of elements associated to the terrigenous mineral phases (i.e. Al, Ti, Fe and partly Si). This suggests minor ice-sheet size changes occurred in the Antarctic margin during the pre-MBE “lukewarm” interval. Post-MBE sediments record instead a high variability between glacial and interglacial periods in the concentration of terrigenous and biogenous (i.e. Ca, Ba) elements suggesting larger amplitude changes in both ice-sheet size and ocean conditions toward the gradual establishment of last glacial cycle conditions. Moreover, a marked increase of Mn during the glacial to interglacial transitions, indicates a post-depositional migration of the redox front and re-oxidation of the surface sediment layers linked to major changes in bottom water oxygen conditions associated to Antarctic Bottom Water formation along the margin at the onset of deglaciations.

In Antarctica, the near-source exposures of volcanic eruption deposits are often limited as they are not well preserved in the dynamic glacial environment, thus making volcanological reconstructions of explosive eruptions extremely challenging. Fortunately, pyroclastic deposits from explosive eruptions are preserved in Southern Ocean sediments surrounding Antarctica, and the tephrostratigraphy of these sequences offers crucial volcanological information including the timing and tempo of past eruptions, their magnitude, and eruption dynamics. Here we report the results of a tephrostratigraphy and tephrochronology study focused on four sediment cores recovered from the Wood Bay area in the western Ross Sea, Antarctica. In all these sedimentary sequences, we found a well-stratified primary tephra of considerable thickness, up to 80 cm, hereafter named the Aviator Tephra (AVT). According to the characteristics of the tephra deposit and its distribution, the AVT was associated with an eruption of considerable intensity, potentially representing one of the largest Holocene eruptions recorded in Antarctica. Based on the major and trace element geochemistry and the mineral assemblage of the tephra, Mount Rittmann was identified as the source of the AVT. A Holocene age of ∼11 ka was determined by radiocarbon dating organic material within the sediments and 40Ar-39Ar dating of alkali-feldspar crystals included in the tephra. Eruption dynamics were initially dominated by hydromagmatic magma fragmentation conditions producing a sustained, relatively wet and ash-rich eruptive cloud. The eruption then evolved into a highly energetic, relatively dry magmatic Plinian eruption. The last phase was characterized by renewed efficient magma-water interaction and/or collapse of the eruptive column producing pyroclastic density currents and associated co-ignimbritic plumes. The distal tephra deposits might be linked to the widespread lag breccia layer previously identified on the rim of the Mount Rittmann caldera which share the same geochemical composition. Diatoms found in the sediments surrounding the AVT and the primary characteristics of the tephra indicate that the Wood Bay area was open sea at the time of the eruption, which is much earlier than previously thought. AVT is also an excellent tephrostratigraphic marker for the Wood Bay area, in the Ross Sea, and a useful marker for future synchronization of continental ice and marine archives in the region.

We report the discovery of an important new cryptotephra within marine sediments close to Cape Hallett (northern Victoria Land), in the western Ross Sea, Antarctica. The cryptotephra is fully characterized for its texture, mineralogy and major- and trace-element data obtained on single glass shards. On the basis of geochemical composition, the cryptotephra is unequivocally correlated with the proximal deposits of an explosive eruption of the poorly known Mount Rittmann volcano, situated in northern Victoria Land. The cryptotephra is also correlated with a widespread tephra layer, which was erupted in 1254 C.E. and is present in numerous ice-cores and blue ice fields across East and West Antarctica. The characteristics of the tephra indicate that it was produced by a prolonged, moderate energy, mostly hydromagmatic eruption. This is the first time that a cryptotephra has been identified in marine sediments of the Ross Sea and in ice cores. It provides an important new and widespread stratigraphical datum with which the continental cryosphere and marine sedimentological records in Antarctica can be correlated. Moreover, from a purely volcanological point of view, the discovery further confirms the occurrence of a long-lasting, significant explosive eruption from Mount Rittmann in historical times that produced abundant widely dispersed fine ash. The study also highlights the inadequacy of current hazard assessments for poorly known volcanoes such as Mount Rittmann, located at high southern latitudes.

Geological records from the Antarctic margin offer direct evidence of environmental variability at high southern latitudes and provide insight regarding ice sheet sensitivity to past climate change. The early to mid-Miocene (23-14 Mya) is a compelling interval to study as global temperatures and atmospheric CO2 concentrations were similar to those projected for coming centuries. Importantly, this time interval includes the Miocene Climatic Optimum, a period of global warmth during which average surface temperatures were 3-4 °C higher than today. Miocene sediments in the ANDRILL-2A drill core from the Western Ross Sea, Antarctica, indicate that the Antarctic ice sheet (AIS) was highly variable through this key time interval. A multiproxy dataset derived from the core identifies four distinct environmental motifs based on changes in sedimentary facies, fossil assemblages, geochemistry, and paleotemperature. Four major disconformities in the drill core coincide with regional seismic discontinuities and reflect transient expansion of grounded ice across the Ross Sea. They correlate with major positive shifts in benthic oxygen isotope records and generally coincide with intervals when atmospheric CO2 concentrations were at or below preindustrial levels (∼280 ppm). Five intervals reflect ice sheet minima and air temperatures warm enough for substantial ice mass loss during episodes of high (∼500 ppm) atmospheric CO2 These new drill core data and associated ice sheet modeling experiments indicate that polar climate and the AIS were highly sensitive to relatively small changes in atmospheric CO2 during the early to mid-Miocene.

The AND-1B drill core recovered a 13.57 million year Miocene through Pleistocene record from beneath the McMurdo Ice Shelf in Antarctica (77.9°S, 167.1°E). Varying sedimentary facies in the 1285 m core indicate glacial–interglacial cyclicity with the proximity of ice at the site ranging from grounding of ice in 917 m of water to ice free marine conditions. Broader interpretation of climatic conditions of the wider Ross Sea Embayment is deduced from provenance studies. Here we present an analysis of the iron oxide assemblages in the AND-1B core and interpret their variability with respect to wider paleoclimatic conditions. The core is naturally divided into an upper and lower succession by an expanded 170 m thick volcanic interval between 590 and 760 m. Above 590 m the Plio-Pleistocene glacial cycles are diatom rich and below 760 m late Miocene glacial cycles are terrigenous. Electron microscopy and rock magnetic parameters confirm the subdivision with biogenic silica diluting the terrigenous input (fine pseudo-single domain and stable single domain titanomagnetite from the McMurdo Volcanic Group with a variety of textures and compositions) above 590 m. Below 760 m, the Miocene section consists of coarse-grained ilmenite and multidomain magnetite derived from Transantarctic Mountain lithologies. This may reflect ice flow patterns and the absence of McMurdo Volcanic Group volcanic centers or indicate that volcanic centers had not yet grown to a significant size. The combined rock magnetic and electron microscopy signatures of magnetic minerals serve as provenance tracers in both ice proximal and distal sedimentary units, aiding in the study of ice sheet extent and dynamics, and the identification of ice rafted debris sources and dispersal patterns in the Ross Sea sector of Antarctica.

Stratigraphic drilling from the McMurdo Ice Shelf in the 2006/2007 austral summer recovered a 1284.87 m sedimentary succession from beneath the sea floor. Key age data for the core include magnetic polarity stratigraphy for the entire succession, diatom biostratigraphy for the upper 600 m and 40Ar/39Ar ages for in-situ volcanic deposits as well as reworked volcanic clasts. A vertical seismic profile for the drill hole allows correlation between the drill hole and a regional seismic network and inference of age constraint by correlation with well‐dated regional volcanic events through direct recognition of interlayered volcanic deposits as well as by inference from flexural loading of pre‐existing strata. The combined age model implies relatively rapid (1 m/2–5 ky) accumulation of sediment punctuated by hiatuses, which account for approximately 50% of the record. Three of the longer hiatuses coincide with basin‐wide seismic reflectors and, along with two thick volcanic intervals, they subdivide the succession into seven chronostratigraphic intervals with characteristic facies: 1. The base of the cored succession (1275–1220 mbsf) comprises middle Miocene volcaniclastic sandstone dated at approx 13.5 Ma by several reworked volcanic clasts; 2. A late-Miocene sub-polar orbitally controlled glacial–interglacial succession (1220–760 mbsf) bounded by two unconformities correlated with basin‐wide reflectors associated with early development of the terror rift; 3. A late Miocene volcanigenic succession (760–596 mbsf) terminating with a ~1 my hiatus at 596.35 mbsf which spans the Miocene–Pliocene boundary and is not recognised in regional seismic data; 4. An early Pliocene obliquity-controlled alternating diamictite and diatomite glacial–interglacial succession(590–440 mbsf), separated from; 5. A late Pliocene obliquity-controlled alternating diamictite and diatomite glacial–interglacial succession (440–150 mbsf) by a 750 ky unconformity interpreted to represent a major sequence boundary at other locations; 6. An early Pleistocene interbedded volcanic, diamictite and diatomite succession (150–80 mbsf), and; 7. A late Pleistocene glacigene succession (80–0 mbsf) comprising diamictite dominated sedimentary cycles deposited in a polar environment.

The compositional record of the AND-2A drillcore is examined using petrological, sedimentological, volcanological and geochemical analysis of clasts, sediments and pore waters. Preliminary investigations of basement clasts (granitoids and metasediments) indicate both local and distal sources corresponding to variable ice-volume and ice-flow directions. Low abundance of sedimentary clasts (e.g., arkose, litharenite) suggests reduced contributions from sedimentary covers while intraclasts (e.g., diamictite, conglomerate) attest to intrabasinal reworking. Volcanic material includes pyroclasts (e.g., pumice, scoria), sediments and lava. Primary and reworked tephra layers occur within the Early Miocene interval (1093 to 640 metres below sea floor). The compositions of volcanic clasts reveal a diversity of alkaline types derived from the McMurdo Volcanic Group. Finer-grained sediments (e.g., sandstone, siltstone) show increases in biogenic silica and volcanic glass from 230 to 780 mbsf and higher proportions of terrigenous material ca. 350 to 750 mbsf and below 970 mbsf. Basement clast assemblages suggest a dominant provenance from the Skelton Glacier -Darwin Glacier area and from the Ferrar Glacier -Koettlitz Glacier area. Provenance of sand grains is consistent with clast sources. Thirteen Geochemical Units are established based on compositional trends derived from continuous XRF scanning. High values of Fe and Ti indicate terrigenous and volcanic sources, whereas high Ca values signify either biogenic or diagenic sources. Highly alkaline and saline pore waters were produced by chemical exchange with glass at moderately elevated temperatures.

Thirty years after oxygen isotope records frommicrofossils deposited in ocean sediments confirmed the hypothesis that variations in the Earth’s orbital geometry control the ice ages1, fundamental questions remain over the response of the Antarctic ice sheets to orbital cycles2. Furthermore, an understanding of the behaviour of the marine-based West Antarctic ice sheet (WAIS) during the ‘warmer-than- present’ early-Pliocene epoch (̃5–3Myr ago) is needed to better constrain the possible range of ice-sheet behaviour in the context of future global warming3. Here we present a marine glacial record from the upper 600 m of theAND-1B sediment core recovered from beneath the northwest part of the Ross ice shelf by the ANDRILL programme and demonstrate well-dated, ̃40-kyr cyclic variations in ice-sheet extent linked to cycles in insolation influenced by changes in the Earth’s axial tilt (obliquity) during the Pliocene. Our data provide direct evidence for orbitally induced oscillations in the WAIS, which periodically collapsed, resulting in a switch from grounded ice, or ice shelves, to open waters in the Ross embayment when planetary temperatures were up to ̃3 C warmer than today4 and atmospheric CO2 concentration was as high as ̃400 p.p.m.v. (refs 5, 6). The evidence is consistent with a new ice-sheet/ice-shelf model7 that simulates fluctuations in Antarctic ice volume of up to + 7 m in equivalent sea level associated with the loss of the WAIS and up to +3 m in equivalent sea level from the EastAntarctic ice sheet, in response to ocean-induced melting paced by obliquity.During interglacial times, diatomaceous sediments indicate high surface-water productivity, minimal summer sea ice and air temperatures above freezing, suggesting an additional influence of surface melt8 under conditions of elevated CO2.