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  • PublicationOpen Access
    Magnitude and epicentral uncertainty of historical earthquakes in northeastern Italy from macroseismic data
    historical earthquakes are essential for long-term seismicity and seismic-hazard assessment, but their location and magnitude are often poorly constrained by sparse and uneven intensity data. We apply the Bakun and Wentworth grid-search method to selected Intensity Data Points (IDPs) from DBMI15 for four earthquakes in northeastern Italy, using Mw-calibrated Italian attenuation models. We estimate intensity centres, intensity-based Mw values, and empirical 67% and 95% confidence contours. The resulting maps make the spatial resolution of each macroseismic field explicit and provide a quantitative layer for comparison with CPTI15/Boxer solutions and DISS seismogenic sources. 2. Methodology: From Historical Sources to Empirical Confidence Contours Input: Selected IDPs from DBMI15 (conventional MCS intensity values, I ≥ III). Algorithm: Bakun & Wentworth (1997) grid-search method. Attenuation Models: Italian macroseismic intensity attenuation models calibrated in Mw by Gomez-Capera et al. (2024). Log-Lin_10 is used as the reference model; CRV9 provides an independent sensitivity check. Output: Intensity centre, adopted as the macroseismic epicentre; intensity-based Mw; Mw intervals; and empirical 67% and 95% confidence contours derived from the RMS surface. The contours express the spatial resolution of the IDP field; they are not posterior probability maps or rupture boundaries. Study area in northeastern Italy, showing historical earthquakes with Mw > 5.5 from CPTI15 and seismogenic sources defined on Galadini et al. (2005) and Poli et al. (2008), and subsequently incorporated into the DISS database (DISS Working Group, 2025). Epicentres are coloured by magnitude class and labelled by year; blue boxes show DISS individual and composite sources. The map provides the regional seismotectonic context for the four earthquakes analysed in this study:
  • PublicationRestricted
    Towards the construction of a high frequency groundwater monitoring network: first results in the framework of the MEET project
    (Societa Geologica Italiana, 2026-05-29) ; ; ; ; ;
    Damato, Adriana
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    Desiderio, Giovanni
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    Muzio, Dario
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    Grappein, Barbara
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    Nosengo, Piero
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    Pedemonte, Federico
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    Riolo, Giuseppe
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    Scaramella, Antonio
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    Scotti, Emanuele
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    Terzoni, Fabrizio
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    Tognetto, Federico
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    ISPRA, Dipartimento per il Servizio Geologico d’Italia + SINA, via V. Brancati 48, Roma
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    Sapienza University, Piazzale Aldo Moro 5, Roma
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    ARPA Abruzzo, Viale G. Marconi n. 49, Pescara.
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    ARPA Abruzzo, Viale G. Marconi n. 49, Pescara
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    ARPA Valle d’Aosta, Rue de la Maladière, 48, Saint Christophe (AO)
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    ARPA Liguria, Via Bombrini 8, Genova
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    ARPA Liguria, Via Bombrini 8, Genova
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    ISPRA, Dipartimento per il Servizio Geologico d’Italia + SINA, via V. Brancati 48, Roma
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    ARPA Liguria, Via Bombrini 8, Genova
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    ISPRA, Dipartimento per il Servizio Geologico d’Italia + SINA, via V. Brancati 48, Roma
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    ARPA Valle d’Aosta, Rue de la Maladière, 48, Saint Christophe (AO).
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    Physico-chemical variations in groundwater are potential indicators of crustal stress linked to seismic activity. In Italy, non-volcanic regions still lack standardised, continuous monitoring. The MEET (Monitoring Earth's Evolution and Tectonics) project, funded by the National Recovery and Resilience Plan, aims to fill this gap by installing 25 high-frequency groundwater monitoring stations. These automatically record temperature, electrical conductivity, water level, and, at selected sites, dissolved CO₂ pressure, supported by a FAIR-compliant data infrastructure. Ten stations are already active in Valle d'Aosta, Liguria, Abruzzo, Marche, and Calabria. This work illustrates the network's technical features, siteselection criteria, and first results from monitored springs and wells, highlighting the importance of the integration of geochemical, geological, and seismotectonic data. Completion by 2026 will advance knowledge of crustal fluid dynamics and research on the relation between physico-chemical groundwaters variations and earthquake events in Italy.
  • PublicationOpen Access
    Quantifying natural hydrogen prospectivity in Italy: A novel pre-exploration workflow for the energy transition
    (Oxford; New York: Elsevier Science Limited Oxford; New York: Pergamon Press, 2026-08-12)
    Schirripa Spagnolo, G
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    Rielli, A
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    Ogunyele, A
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    Riolo, G
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    Department of Earth Science, Sapienza University of Rome, Rome, Italy
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    Institute of Geosciences and Earth Resources, CNR, Pisa, Italy
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    Institute of Geosciences and Earth Resources, CNR, Pisa, Italy
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    Institute of Environmental Geology and Geoengineering, CNR, Rome, Italy
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    Institute of Geosciences and Earth Resources, CNR, Pisa, Italy
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    Department of Earth Science, Sapienza University of Rome, Rome, Italy
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    Institute of Geosciences and Earth Resources, CNR, Pisa, Italy
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    Institute of Environmental Geology and Geoengineering, CNR, Rome, Italy
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    National Institute of Geophysics and Volcanology (INGV), Palermo, Italy
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    Department of Earth Science, Sapienza University of Rome, Rome, Italy
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    Institute of Geosciences and Earth Resources, CNR, Pisa, Italy
    This study presents the first quantitative evaluation of natural hydrogen prospectivity in Italy, developed within the EU-funded NHEAT-Natural Hydrogen for Energy trAnsiTion-project. It integrates geological, geochemical, and geophysical data through a reaction-specific workflow, and introduces a semi-quantitative hydrogen prospectivity index to classify and rank potential exploration target areas, primarily based on source rocks. The results identify Tuscany as the top-priority region, where granitoid-hosted hydrothermal systems are associated with documented H 2 emissions. The Voltri Massif shows moderate potential linked to active serpentinization, while the Northern Apennines may potentially preserve fossil H 2. In the Ivrea-Verbano Zone, granitoids of Calabria and Sardinia, and in the Western and Central Alps, H 2 could be generated from low-temperature secondary oxidation reactions. The Po Basin may sustain organic-related H 2 production. This national-scale assessment highlights Italy as a natural laboratory for diverse hydrogen systems and provides a transferable workflow for identifying and developing natural hydrogen resources worldwide.
  • PublicationOpen Access
    Structurally-Controlled Permeability Evolution and Mineralization in Geothermal Caprocks: The Fenice Capanne Mining District (Southern Tuscany, Italy)
    (American Geophysical Union, 2026-08) ; ; ; ; ;
    Novella, Davide
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    Moretto, Vincenzo
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    Ruggieri, Giovanni
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    Dipartimento di Scienze della Terra, Sapienza Università di Roma, Roma, Italy, CNR‐GEO, Istituto di Geoscienze, Rome, Italy
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    Dipartimento di Scienze, Università Roma Tre, Roma, Italy
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    Dipartimento di Scienze, Università Roma Tre, Roma, Italy
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    CNR‐GEO, Istituto di Geoscienze, Rome, Italy
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    Certema S.c.a.r.l., Cinigiano, Italy
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    Department of Geosciences, Università di Padova, Padova, Italy
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    Dipartimento di Scienze della Terra, Sapienza Università di Roma, Roma, Italy
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    Dipartimento di Scienze della Terra, Sapienza Università di Roma, Roma, Italy
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    Dipartimento di Scienze della Terra, Sapienza Università di Roma, Roma, Italy
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    Dipartimento di Scienze della Terra, Sapienza Università di Roma, Roma, Italy
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    CNR‐GEO, Istituto di Geoscienze, Florence, Italy
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    Dipartimento di Scienze della Terra, Sapienza Università di Roma, Roma, Italy
    The Neogene mineralized region of the Colline Metallifere in southern Tuscany (Italy) provides a natural laboratory to investigate feedback between fluid-rock interaction, structurally controlled fluid flow, and hydrothermal ore mineralization. This study focuses on the Fe-Cu-Pb-Zn deposit of Fenice Capanne, located south of the active Larderello-Travale geothermal system, where marly-limestone caprocks of the Liguride Complex preserve evidence of permeability creation and destruction above a regional geothermal reservoir. A multidisciplinary approach was applied to reconstruct the evolution of the hydrothermal system. Two main alteration stages were identified. An early prograde, high-temperature skarn metasomatism was associated with the growth of clinopyroxene-garnet assemblages and characterized by substantial gains in Si, Fe, Mn, and Ca, resulting in a large volume increase (up to ∼400%). Reaction-induced fracturing generated secondary permeability, which superimposed on primary permeability related to bedding and lithological anisotropies, enhancing hydraulic connectivity. A subsequent retrograde stage, below ∼300°C, was driven by mixing between meteoric and saline magmatic-derived fluids, or those derived from evaporite interaction, and resulted in renewed fracturing, brecciation, and extensive quartz-sulphide veining. These processes recorded cyclic variations in fluid composition, redox conditions, salinity, and boiling associated with transient pressure drops during hydraulic fracturing. Overall, the Ligurian marly-limestone sequence evolved from a low-permeability sedimentary seal into a reactive mineralized system capable of sustaining transient hydrothermal circulation. Structural connectivity controlled by faulting and reaction-induced fracturing governed both permeability evolution and mineralization. These results demonstrate that sedimentary caprocks can behave as dynamic components of the hydrothermal systems, with important implications for geothermal fluid flow, metal transport, and reservoir evolution. Plain Language Summary Geothermal systems rely on impermeable rock layers, known as caprocks, to trap hot fluids at depth and allow heat to be exploited. These caprocks are usually considered stable and, long-lasting seals. However, in tectonically active regions, faults and circulating hot fluids can change their physical and chemical properties, potentially allowing fluids to escape. In this study, we investigate the Fenice Capanne mining district in southern Tuscany (Italy), a hydrothermal system near the active Larderello-Travale geothermal field. By studying rocks that were once part of a geothermal caprock and are now exposed at the surface, we reconstruct how faulting and fluid-rock interaction altered permeability over time. Our results show that chemical reactions between rocks and hot fluids caused volume expansion, fracturing, and repeated opening and sealing of fluid pathways within originally low-permeability rocks. These processes temporarily transformed the caprock into a fluid conduit, allowing hydrothermal fluids to circulate, mix, and locally deposit metals such as iron, copper, lead, and zinc. This study demonstrates that caprocks are not always passive barriers but can behave as dynamic systems whose permeability is transient and evolve in space and time. Understanding how and when caprocks sustain structural permeability is important for improving geothermal reservoir models and predicting mineralization in geothermal environments.
  • PublicationOpen Access
    Petrologic and geochemical exploration of the plumbing systems under submarine volcanoes Edifice C, Three Sisters and Orca (Bransfield Strait, Antarctica)
    (Elsevier BV:PO Box 211, 1000 AE Amsterdam Netherlands:011 31 20 4853757, 011 31 20 4853642, 011 31 20 4853641, EMAIL: nlinfo-f@elsevier.nl, INTERNET: http://www.elsevier.nl, Fax: 011 31 20 4853598, 2026-07-09) ; ;
    García-Arias, Marcos
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    Malecki, Jérémie
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    Bertea, Esteban
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    Departamento de Geología, Universidad de Salamanca, Plaza Caídos s/n, 37008 Salamanca, Spain
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    Departamento de Geología, Universidad de Salamanca, Plaza Caídos s/n, 37008 Salamanca, Spain
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    Departamento de Geología, Universidad de Salamanca, Plaza Caídos s/n, 37008 Salamanca, Spain
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    Geosciences Barcelona (GEO3BCN), CSIC, Lluis Sol´e i Sabarís s/n, 08028 Barcelona, Spain
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    Departamento de Mineralogía, Petrología y Geología Aplicada, Universidad de Barcelona, Carrer Martí i Franqu`es s/n, 08028 Barcelona, Spain
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    Departamento de Geología, Universidad de Salamanca, Plaza Caídos s/n, 37008 Salamanca, Spain
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    Instituto de Bio y Geociencias del NOA, Consejo Nacional de Investigaciones Científicas y T´ecnicas - Universidad Nacional de Salta, Avenida 9 de Julio 14, 4405 Salta, Argentina
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    Department of Physics and Geology, University of Perugia, Via Alessandro Pascoli, 06123 Perugia, Italy
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    Departamento de Mineralogía, Petrología y Geología Aplicada, Universidad de Barcelona, Carrer Martí i Franqu`es s/n, 08028 Barcelona, Spain
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    Centro Oceanogr´afico de Canarias, Instituto Espa˜nol de Oceanografía, CSIC, Calle Farola del Mar 22, 38180 Santa Cruz de Tenerife, Spain
    Submarine volcanism represents one of the most abundant forms of volcanic activity on Earth, yet it remains poorly studied due to the limited accessibility. In Antarctica, the remoteness and arduous climate conditions have restricted research on submarine volcanoes to only a few regions, particularly the Bransfield Strait. This back-arc basin, separating the South Shetland Islands from the Antarctic Peninsula, hosts numerous submarine volcanic edifices along its main axis. An eruption from these volcanoes could both impact the local ecosystem, potentially disrupting the Antarctic trophic chain, and pose a direct hazard to nearby scientific stations, as the shallow water depths increase the likelihood of explosive hydrovolcanic eruptions and tsunami triggering. Previous geochemical studies of volcanic rocks collected along the basin have characterised the relationship between magma compositions and their geodynamic setting, however, the magmatic plumbing systems of these submarine volcanic edifices are still poorly known. To address this gap, this work presents a petrological and geochemical study of juvenile volcanic samples from three of the seven main submarine volcanoes: Edifice C, Three Sisters and Orca. The results identify the magmatic storage regions at maximum depths of 12-17 km, consistent with previous geophysical estimates, and magma temperatures of up to 1130-1180 • C, matching magmas of similar compositions. Magmas rapidly ascended (from hours to days) beneath the three volcanoes. This research represents the first approach to decipher the magmatic plumbing systems of these submarine volcanoes, providing essential parameters for a strengthening hazard assessment in this region.