Corbo, Andrea

We present the results from a mid-term monitoring activity carried out at the submarine hydrothermal system located off Panarea Island (Aeolian Islands, Italy). The collected data concern multiparametric information from a self-operating seafloor station (acoustics and chemical–physical parameters) acquiring data at regular intervals and transmitting it twice a day in near real-time. The acoustic records were analysed with the principal aim of investigating bubbling variations related to gas flow rate. Several anomalies have been documented, in the bubbling activity detected at high frequencies (100–2000 Hz), as well as in very low acoustic frequencies, related to fluids dynamic along cracks. An astonishing correlation between soil CO2 flux emissions recorded at Stromboli craters and the acoustic signals in the 1–30 Hz range has been identified, suggesting how this tectonic link could act as an escape route for fluids characterized by a shared source.

The SEISMOFAULTS project (www.seismofaults.it) was set up in 2016 with the general plan of exploring the seismicity of marine areas using deep seafloor observatories. The activity of the first two years (Seismofaults 2017 and 2018) consisted of the installation of a geophysical-geochemical temporary monitoring network over the Ionian Sea floor. Eleven ocean-bottom seismometers with hydrophones (OBS/H) and two seafloor geochemical-geophysical multiparametric observatories were deployed to: (1) identify seismically active faults; (2) identify potential geochemical precursors of earthquakes; and (3) understand possible cause–effect relationships between earthquakes and submarine slides. Furthermore, five gravity cores were collected from the Ionian Sea bottom and ~4082 km of geophysical acquisition, including multibeam and single channel seismic reflection data, were acquired for a total of 4970 km2 high-resolution multibeam bathymetry. Using Niskin bottles, four water column samples were collected: two corresponding at the location of the two multiparametric observatories (i.e., along presumably-active fault zones), one corresponding at a recently discovered mud volcano, and one located above a presumably-active fault zone away from the other three sites. Preliminary results show: (1) a significant improvement in the quality and quantity of seismological records; (2) endogenous venting from presumably active faults; (3) active geofluid venting from a recently-discovered mud volcano; and (4) the correct use of most submarine devices. Preliminary results from the SEISMOFAULTS project show and confirm the potential of multidisciplinary marine studies, particularly in geologically active areas like southern Italy and the Mediterranean Sea.

Geochemical investigations carried out on submarine hydrothermal fluids vented offshore the Pontine Islands (Tyrrhenian Sea) revealed the existence of gas vents to the W of Zannone Island and SW of Ventotene Island. The geochemical features of the CO2-rich gas samples show a clear mantle-derived signature with 3He/4He of 3.72-3.75 Ra and 1.33 Ra at Zannone and Ventotene, respectively. Gas geochemistry denotes how CO2-rich gases undergo fractionation processes due to CO2 dissolution to a variable extent favoring enrichment in the less soluble gas species, i.e., CH4, N2, and He. The carbon isotope composition of CO2, expressed as δ13C vs. V-PDB, ranges from -0.71 and -6.16‰ at Zannone to 1.93‰ at Ventotene. Preliminary geothermometric and geobarometric estimations indicate equilibrium temperatures in the range of 150-200°C at Zannone and >200°C at Ventotene besides H2O pressures in the range of 5 bar and 20 bar at Zannone and Ventotene, respectively. Although the latest volcanic activity at the Pontine Archipelago is dated Middle Pleistocene, the combination of the new geochemical information along with geothermometric estimations indicates that cooling magmas are likely releasing enough thermal energy to form an efficient hydrothermal system.

Geohazards associated to submarine hydrothermal systems still represent a tricky enigma to face and solve for the scientific community. The poor knowledge of a submarine environment, the rare and scarce monitoring activities, and the expensive and sometimes complicated logistics are the main problems to deal with. The submarine low-energy explosion, which occurred last November 3, 2002, off the volcanic island of Panarea, highlighted the absence of any hazard scenario to be used to manage the volcanic crisis. The “unrest” of the volcanic activity was triggered by a sudden input of deep magmatic fluids, which caused boiling water at the sea surface with a massive CO2 release besides changes in the fluids’ geochemistry. That event dramatically pushed scientists to develop new methods to monitor the seafloor venting activity. Coupling the information from geochemical investigations and data collected during the unrest of volcanic activity, we were able to (a) develop theoretical models to gain a better insight on the submarine hydrothermal system and its relationships with the local volcanic and tectonic structures and (b) to develop a preliminary submarine volcanic hazard assessment connected to the Panarea system (Aeolian Islands). In order to mitigate the potential submarine volcanic hazard, three different scenarios are described here: (1) ordinary hydrothermal venting, (2) gas burst, and (3) volcanic eruption. The experience carried out at Panarea demonstrates that the best way to face any submarine volcanic-hydrothermal hazard is to improve the collection of data in near real-time mode by multidisciplinary seafloor observatories and to combine it with periodical sampling activity.

The Ionian Sea in southern Italy is at the center of active interaction and convergence between the Eurasian and African–Adriatic plates in the Mediterranean. This area is seismically active with instrumentally and/or historically recorded Mw > 7:0 earthquakes, and it is affected by recently discovered long strike-slip faults across the active Calabrian accretionary wedge. Many mud volcanoes occur on top of the wedge. A recently discovered one (called the Bortoluzzi Mud Volcano or BMV) was surveyed during the Seismofaults 2017 cruise (May 2017). Bathymetric backscatter surveys, seismic reflection profiles, geochemical and earthquake data, and a gravity core are used here to geologically, geochemically, and geophysically characterize this structure. The BMV is a circular feature ' 22m high and ' 1100m in diameter with steep slopes (up to a dip of 22 ). It sits atop the Calabrian accretionary wedge and a system of flowerlike oblique-slip faults that are probably seismically active as demonstrated by earthquake hypocentral and focal data. Geochemistry of water samples from the seawater column on top of the BMV shows a significant contamination of the bottom waters from saline (evaporite-type) CH4-dominated crustalderived fluids similar to the fluids collected from a mud volcano located on the Calabria mainland over the same accretionary wedge. These results attest to the occurrence of open crustal pathways for fluids through the BMV down to at least the Messinian evaporites at about 􀀀3000 m. This evidence is also substantiated by helium isotope ratios and by comparison and contrast with different geochemical data from three seawater columns located over other active faults in the Ionian Sea area. One conclusion is that the BMV may be useful for tracking the seismic cycle of active faults through geochemical monitoring. Due to the widespread diffusion of mud volcanoes in seismically active settings, this study contributes to indicating a future path for the use of mud volcanoes in the monitoring and mitigation of natural hazards.