Mazzini, Adriano

Ongoing studies conducted in northern polar regions reveal that permafrost stability plays a key role in the modern carbon cycle as it potentially stores considerable quantities of greenhouse gases. Rapid and recent warming of the Arctic permafrost is resulting in significant greenhouse gas emissions, both from physical and microbial processes. The potential impact of greenhouse gas release from the Antarctic region has not, to date, been investigated. In Antarctica, the McMurdo Dry Valleys comprise 10 % of the ice-free soil surface areas in Antarctica and like the northern polar regions are also warming albeit at a slower rate. The work presented herein examines a comprehensive sample suite of soil gas (e.g., CO2, CH4 and He) concentrations and CO2 flux measurements conducted in Taylor Valley during austral summer 2019/2020. Analytical results reveal the presence of significant concentrations of CO2, CH4 and He (up to 3.44 vol%, 18,447 ppmv and 6.49 ppmv, respectively) at the base of the active layer. When compared with the few previously obtained measurements, we observe increased CO2 flux rates (estimated CO2 emissions in the study area of 21.6 km2 ≈ 15 tons day-1). We suggest that the gas source is connected with the deep brines migrating from inland (potentially from beneath the Antarctic Ice Sheet) towards the coast beneath the permafrost layer. These data provide a baseline for future investigations aimed at monitoring the changing rate of greenhouse gas emissions from Antarctic permafrost, and the potential origin of gases, as the southern polar region warms.

North-east Java is part of a large sedimentary basin containing hydrocarbon provinces that feature diffuse hydrothermal systems, mud volcanoes, and degassing sites. Seismic profiles acquired to explore the basin reveal a broad distribution of palaeo- and modern piercement structures. The Watukosek fault system links the volcanic arc, to the south, with the Sidoarjo province, to the north. Several piercement structures, including the Kalang Anyar mud volcano, are hosted along this left-lateral strike-slip system that favors the migration of crustal fluids in this part of the basin. Here, we present a multidisciplinary geological, geophysical and geochemical study conducted at Kalang Anyar where dozens of seepage sites are active in the crater area and intermittently emit bursts oil, gas, mud, and water. The emitted gasses are methane-dominated with smaller amounts of heavier hydrocarbons and CO2. Unlike most mud volcanoes, at Kalang Anyar the mixed-thermogenic origin of the methane is coupled with geothermal anomalies, as indicated by helium and CO2 isotopic values (δ13CCO2 as high as −4‰) that suggest the input of mantle-derived gas. Our gas flux measurements reveal that Kalang Anyar emits about 1.62 and 5.75 t yr−1 of CO2 and CH4, respectively. The intense bubbling gives rise to a typical drumbeat seismic signal characterized by dominant frequencies around of 3–4 Hz (and up to 15 Hz). We interpret the drumbeat as fluids rising and resonating through shallow plumbing system of Kalang Anyar. Erupted clasts with different lithologies and shells are scattered across the mud volcano area, while the edges of the crater zone include cubic meter-sized carbonate-cemented blocks and ridges that contain siliciclastic sediments and abundant chemosymbiotic bivalves. Carbon isotope analyses of the carbonate cement (δ13C as low as −48.8‰) identify the latter as methanogenic chemoherms. Radiocarbon (14C) dating of bivalves cemented in the blocks indicates an age of 1890-1488 BP. These results indicate that the activity of Kalang Anyar MV dates from when the area was below sea level and that the microbially-mediated precipitation of carbonates was ongoing during subaqueous methane seepage at the crater site. To the best of our knowledge, Kalang Anyar is the first example of a mud volcano that progressed from subaqueous to subaerial conditions during marine regression, displaying evidence of former marine activity (i.e. methanogenic carbonates) and current subaerial degassing at numerous seepage sites. Potentially eruptive phases represent a clear geohazard for the numerous settlements constructed inside the mud volcano. In light of this, it may be prudent to apply stricter rules for development activities, such as housing construction permits that consider the possibility of potentially catastrophic events, and apply steps to mitigate these hazards.

The Dead Sea Fault (DSF) is a crustal-scale continental transform fault separating the African and the Arabian plates. Neogene to Quaternary volcanic activity is well-spread in Northern Israel. Yet, the origin of the magmas that fed the eruptions is still unpinned. Our local earthquake tomography depicts velocity distributions typical of rifting settings. At 9 km depth, a prominent high Vp/Vs anomaly marks the presence of cooling melts. We propose that protracted transtension along the DSF caused crustal thinning promoting the emplacement of magmatic bodies. Crustal emplacements of magmas in Northern Israel reconcile multiple observations, including the high geothermal gradient, the prominent magnetic anomalies and the traces of mantle-derived fluids in the springs across the Sea of Galilee. We provide a compelling evidence for rifting in segments of the DSF and identify the potential source of magmatism that fed part of the volcanic activity of the area.

Extensive fields of sub-kilometre- to kilometre-scale mounds, cones, domes, shields, and flow-like edifices cover large parts of the martian lowlands. These features have been compared to structures on Earth produced by sedimentary volcanism – a process that involves subsurface sediment/fluid mobilisation and commonly releases methane to the atmosphere. It was proposed that such processes might help to explain the presence of methane in the martian atmosphere and may also have produced habitable, subsurface settings of potential astrobiological relevance. However, it remains unclear if sedimentary volcanism on Earth and Mars share genetic similarities and hence if methane or other gases were released on Mars during this process. The aim of this review is to summarise the current knowledge about mud-volcano-like structures on Mars, address the critical aspects of this process, identify key open questions, and point to areas where further research is needed to understand this phenomenon and its importance for the Red Planet's geological evolution. We show here that after several decades of exploration, the amount of evidence supporting martian sedimentary volcanism has increased significantly, but as the critical ground truth is still lacking, alternative explanations cannot be ruled out. We also highlight that the lower gravity and temperatures on Mars compared to Earth control the dynamics of clastic eruptions and surface emplacement mechanisms and the resulting morphologies of erupted material. This implies that shapes and triggering mechanisms of mud-volcano-like structures may be different from those observed on Earth. Therefore, comparative studies should be done with caution. To provide a better understanding of the significance of these abundant features on Mars, we argue for follow-up studies targeting putative sedimentary volcanic features identified on the planet's surface and, if possible, for in situ investigations by landed missions such as that by the Zhurong rover.

Mud volcanoes are rapidly-evolving geological phenomena characterized by the surface expulsion of sediments and fluids from over-pressurized underlying reservoirs. We investigate the Nirano Mud Volcano, Northern Italy, with seismic methods to better understand the dynamic evolution of the system and shed light on its subsurface structure. Our study allowed to detect and characterize three different types of high-frequency drumbeat signals that are present in the most active part of the mud volcano plumbing system. With a back-projection method based on the cross-correlation envelope of signals recorded at different station pairs, we can determine the source location of the drumbeats. These coincide with the location of V/H (vertical-to-horizontal) amplitude peaks obtained from an ambient vibration profile and resistivity anomalies identified in a previous study. We observe that the drumbeats are P-wave dominated signals, with characteristics similar to those found in magmatic settings, i.e. LPs (long-period signals). We suggest that such tremors originate from the migration of mud and gas inside the mud volcanic conduits. The source location, waveform and frequency content of the drumbeats evolve over time. We found that drumbeat occurrence is directly linked with morphological changes at surface.

East Java is characterised by a complex interaction of volcanic and tectonic processes and it is marked by isolated eruptive centres scattered across the back-arc sedimentary basins. In 2006 a large sediment hosted geothermal system named Lusi, pierced the Kendeng basin in East Java and since then it continues in a relentless eruption of mud breccia. To investigate the spatial and structural relationships between the volcanic arc and the back-arc domains, we perform a local earthquake tomography. The inversion of regional earthquakes recorded by our seismic network (for about two years) shows sharp Vp and Vp/Vs transitions. We observe a marked reduction of P-wave velocities and a high Vp/Vs ratio in the back-arc basins. Our study highlights a clear connection between the plumbing system of the volcanic arc and the northern sedimentary province. We propose a conceptual model suggesting that magmas and hydrothermal fluids may migrate from the middle to the upper crust into the sedimentary basins capitalising on existing thrust faults. Such low angle faults, promoted by the compressional regime of the region, link the magmatic domain to the northern sedimentary provinces. This process may represent the early phase of volcanic arc migration when magma-derived fluids are focused into fractured and permeable geological structures. Our conceptual model would not only help to understand the occurrence of the abundant mantle-derived fluids sampled across the back-arc, but it is also consistent with the occurrence of isolated magmatic and hybrid systems piercing across sedimentary environments in the back-arc of Java.

Lusi is a sediment-hosted geothermal system relentlessly erupting since May 2006 in the East Java back-arc sedimentary basin. Lusi provides the unprecedented opportunity to study the development of the early phases of a new-born piercement structure and its impact on society. In order to investigate the shallow plumbing system of this large-scale eruption, we deployed a pool of 25 IRIS V-Fullwavers to conduct a 3D deep electrical resistivity tomography extending over ∼15 km2 around the eruption site. The inverted data reveal the structure of the subsided area hosting the region where a mix of groundwater, mud breccia, hydrocarbons and boiling hydrothermal fluids are stored. Our investigation also points out the link between a well-developed fault system and the upwelling of the deep-seated fluids that initiated, and still drive, the development of the new-born Lusi eruption.

Quantifying natural geological sources of methane (CH4) allows to improve the assessment of anthropogenic emissions to the atmosphere from fossil fuel industries. The global CH4 flux of geological gas is, however, an object of debate. Recent fossil (14C-free) CH4 measurements in preindustrial-era ice cores suggest very low global geological emissions (~ 1.6 Tg year-1), implying a larger fossil fuel industry source. This is however in contrast with previously published bottom-up and top-down geo-emission estimates (~ 45 Tg year-1) and even regional-scale emissions of ~ 1-2 Tg year-1. Here we report on significant geological CH4 emissions from the Lusi hydrothermal system (Indonesia), measured by ground-based and satellite (TROPOMI) techniques. Both techniques indicate a total CH4 output of ~ 0.1 Tg year-1, equivalent to the minimum value of global geo-emission derived by ice core 14CH4 estimates. Our results are consistent with the order of magnitude of the emission factors of large seeps used in global bottom-up estimates, and endorse a substantial contribution from natural Earth's CH4 degassing. The preindustrial ice core assessments of geological CH4 release may be underestimated and require further study. Satellite measurements can help to test geological CH4 emission factors and explain the gap between the contrasting estimates.

Azerbaijan hosts the highest density of subaerial mud volcanoes on Earth. The morphologies characterizing these structures vary depending on their geological setting, frequency of eruption, and transport processes during the eruptions. Lokbatan is possibly the most active mud volcano on Earth exhibiting impressive bursting events every ∼5 years. These manifest with impressive gas flares that may reach more than 100 meters in height and the bursting of thousands of m3 of mud breccia resulting in spectacular mud flows that extend for more than 1.5 kilometres. Unlike other active mud volcanoes, to our knowledge Lokbatan never featured any visual evidence of enduring diffuse degassing (e.g., active pools and gryphons) at and near the central crater. Only a very small new-born gryphon was intermittently active in 2019 (with negligible flow). Gas flux measurements completed with a closed-chamber technique reveal extremely low values throughout the structure with average CH4 = 1.36 tonnes yr−1 and CO2 = 11.85 tonnes yr−1. We suggest that after eruptive events, the mud breccia is able to seal the structure preventing gas release and thereby promoting overpressure build-up in the subsurface. This self-sealing mechanism allows a fast recharge of Lokbatan resulting in more frequent and powerful explosive episodes. Our field observations reveal the presence of large (up to ∼50,000 m3) stratified blocks that were originally part of a large crater cone. These blocks were rafted >1 km from the vent on top of mud breccia flows. We use a model based on lubrication theory to show that it is reasonable to transport blocks this large and this far provided the underlying mud flow was thick enough and the blocks are large enough. The presence of large rafted blocks is not a unique phenomenon observed at Lokbatan mud volcano and is documented at other large-scale structures both onshore and offshore.

The Sea of Galilee in northeast Israel is a freshwater lake filling a morphological depression along the Dead Sea Fault. It is located in a tectonically complex area, where a N-S main fault system intersects secondary fault patterns non-univocally interpreted by previous reconstructions. A set of multiscale geophysical, geochemical and seismological data, reprocessed or newly collected, was analysed to unravel the interplay between shallow tectonic deformations and geodynamic processes. The result is a neotectonic map highlighting major seismogenic faults in a key region at the boundary between the Africa/Sinai and Arabian plates. Most active seismogenic displacement occurs along NNW-SSE oriented transtensional faults. This results in a left-lateral bifurcation of the Dead Sea Fault forming a rhomb-shaped depression we named the Capharnaum Trough, located off-track relative to the alleged principal deformation zone. Low-magnitude (ML = 3-4) epicentres accurately located during a recent seismic sequence are aligned along this feature, whose activity, depth and regional importance is supported by geophysical and geochemical evidence. This case study, involving a multiscale/multidisciplinary approach, may serve as a reference for similar geodynamic settings in the world, where unravelling geometric and kinematic complexities is challenging but fundamental for reliable earthquake hazard assessments.