Beaubien, Stan

Radon (222Rn) is a natural radioactive gas formed in rocks and soil by the decay of its parent nuclide (238-Uranium). The rate at which radon migrates to the surface, be it along faults or directly emanated from shallow soil, represents the Geogenic Radon Potential (GRP) of an area. Considering that the GRP is often linked to indoor radon risk levels, we have conducted multi-disciplinary research to: (i) define local GRPs and investigate their relationship with associated indoor Rn levels; (ii) evaluate inhaled radiation dosages and the associated risk to the inhabitants; and (iii) define radon priority areas (RPAs) as required by the Directive 2013/59/Euratom. In the framework of the EU-funded LIFE-Respire project, a large amount of data (radionuclide content, soil gas samples, terrestrial gamma, indoor radon) was collected from three municipalities located in different volcanic districts of the Lazio region (central Italy) that are characterised by low to high GRP. Results highlight the positive correlation between the radionuclide content of the outcropping rocks, the soil Rn concentrations and the presence of high indoor Rn values in areas with medium to high GRP. Data confirm that the Cimini-Vicani area has inhalation dosages that are higher than the reference value of 10 mSv/y.

National Italian funding has recently been allocated for the construction of a 350 MWe coal-fired power plant / CCS demonstration plant in the Sulcis area of SW Sardinia, Italy. In addition, the recently approved EC-funded ENOS project (ENabling Onshore CO2 Storage in Europe) will use the Sulcis site as one of its main field research laboratories. Site characterization is already ongoing, and work has begun to design gas injection experiments at 100-200 m depth in a fault. This article gives an overview of results to date and plans for the future from the Sapienza University of Rome research group.

In many countries, assessment programmes are carried out to identify areas where people may be exposed to high radon levels. These programmes often involve detailed mapping, followed by spatial interpolation and extrapolation of the results based on the correlation of indoor radon values with other parameters (e.g., lithology, permeability and airborne total gamma radiation) to optimise the radon hazard maps at the municipal and/or regional scale. In the present work, Geographical Weighted Regression and geostatistics are used to estimate the Geogenic Radon Potential (GRP) of the Lazio Region, assuming that the radon risk only depends on the geological and environmental characteristics of the study area. A wide geodatabase has been organised including about 8000 samples of soil-gas radon, as well as other proxy variables, such as radium and uranium content of homogeneous geological units, rock permeability, and faults and topography often associated with radon production/migration in the shallow environment. All these data have been processed in a Geographic Information System (GIS) using geospatial analysis and geostatistics to produce base thematic maps in a 1000 m × 1000 m grid format. Global Ordinary Least Squared (OLS) regression and local Geographical Weighted Regression (GWR) have been applied and compared assuming that the relationships between radon activities and the environmental variables are not spatially stationary, but vary locally according to the GRP. The spatial regression model has been elaborated considering soil-gas radon concentrations as the response variable and developing proxy variables as predictors through the use of a training dataset. Then a validation procedure was used to predict soil-gas radon values using a test dataset. Finally, the predicted values were interpolated using the kriging algorithm to obtain the GRP map of the Lazio region. The map shows some high GRP areas corresponding to the volcanic terrains (central-northern sector of Lazio region) and to faulted and fractured carbonate rocks (central-southern and eastern sectors of the Lazio region). This typical local variability of autocorrelated phenomena can only be taken into account by using local methods for spatial data analysis. The constructed GRP map can be a useful tool to implement radon policies at both the national and local levels, providing critical data for land use and planning purposes.

Continuous monitoring has been carried out at a fluvial flood-plain site near Rome for over a year. There is a mix of biogenic CO2 and deep geogenic CO2 at the site at relatively low concentrations and fluxes compared with other natural CO2 seepage sites studied previously. Factors such as temperature and soil moisture clearly affect the CO2 concentration and flux and seasonal and diurnal influences are apparent. Statistical approaches are being used to try to define these relationships and separate out the two gas components, which would be necessary in any quantification of leakage from CO2 storage.

The Sulcis Basin is an area situated in SW Sardinia (Italy) and is a potential site for the development of CCS in Italy. This paper illustrates the preliminary results of geological characterization of fractured carbonate reservoir (Miliolitico Fm.) and the sealing sequence, composed by clay, marl, and volcanic rocks, with a total thickness of more than 900 m. To characterize the reservoir-caprock system an extensive structural-geological survey at the outcrop was conducted. It was also performed a study of the geochemical monitoring, to define the baseline conditions, measuring CO2 concentrations and flux in the study site.

Discoveries from multibeam bathymetry and geochemical surveys performed off Zannone Island (western Pontine Archipelago, Tyrrhenian Sea) provide evidence of an undocumented hydrothermal field characterized by ongoing fluid emissions and morphologically complex giant depressions located in shallow water (<150m water depth). Based on a detailed morpho-bathymetric study we identify the seabed morphologies produced by hydrothermal fluid emission activity. We recognize five giant depressions (length >250 m) that host pockmarks, mounds, small cones, and active fluid vents, which are interpreted as complex fluid-escape features developed both through vigorous-explosive events and steady seepage. Their spatial distribution suggests that the NE-SW trending faults bounding the Ponza-Zannone structural high and the shallow fractured basement are favorable conditions for the upward migration of hydrothermal fluids. Moreover, we performed a detailed geochemical study to investigate the source of the hydrothermal fluids. The geochemical signature of the collected fluids provides information of active CO2-dominated degassing with a significant contribution of mantle volatiles, with measured 3He/4He values>3.0 Ra that are similar to those recorded at Stromboli and Panarea volcanoes. The hydrothermal system produces volatiles that may originate from residual magma batches, similar to the Pleistocene trachytes cropping out in the SE sector of Ponza Island that were probably intruded in the shallow crustal levels and never erupted. The discovery of the Zannone hydrothermal field updates the record of active hydrothermal areas of the Mediterranean Sea. Moreover, the recognition of several giant hydrothermal depressions characterized by a complex morphology is peculiar for the Mediterranean Sea.

Detailed soil gas surveyswere conducted at twomine districts to understand gas migrationmechanisms fromdeposits buried at different depths. The Tolfa (Lazio, Central Italy) and Neves-Corvo (Baixo Alentejo, Portugal) mine districts have different characteristics: the former is relatively shallow (30–100 m) whereas the latter is at a depth of 400–500 m and covered by low-permeability metamorphic rocks. The studied gases included major (N2, O2, CO2) and trace (4He, 222Rn) gases, hydrocarbons (CH4, C2H6 and C3H8) and S compounds (H2S, COS, SO2). The measured concentrations (some examples of max values at Tolfa: Rn 233 Bq/L, CO2 9.5%, CH4 12.3 ppm, COS 3.7 ppm; and at Neves-Corvo: Rn 130 Bq/L, CO2 24.3%, CH4 0.1%) indicate that gases migrate preferentially through zones of brittle deformation by advective processes, as suggested by the relatively high rate of migration needed to obtain anomalies of short-lived 222Rn in the soil pores. Considering the different depths of the two ore deposits, obtained results can be considered as features of near-field (Tolfa) and far-field (Neves- Corvo) gas migration.

The monitoring of the integrity of onshore geological carbon capture and storage projects will require an approach that integrates various methods with different spatial and temporal resolutions. One method proven to be quite effective for site assessment, leakage monitoring, and leakage verification is near-surface gas geochemistry, which includes soil gas concentration and gas flux measurements. Anomalous concentrations or fluxes, relative to the natural background values, can indicate the potential occurrence of a leak. However, the natural background can be quite variable, especially for CO2, due to biological production and accumulation in the soil that changes as a function of soil type, land use, geology, temperature, water content, and various other parameters. To better understand how these parameters influence natural, near-surface background values, and to examine the potential of different sampling strategies as a function of the survey goals, this paper reports results from two highly different case studies, one from northern Europe (Volund, Denmark) and one from southern Europe (Sulcis, Sardinia, Italy). The small Voulund site, with its homogeneous soil, climate, and topography, was surveyed twice (in fall and in spring) within the EU-funded SiteChar project to examine the effects of different land-use practices and seasons on baseline values. Forested land was found to have lower CO2 concentrations during both campaigns compared to cultivated and heathland, and higher CH4 values during the spring sampling campaign. Continuous monitoring probes showed much more detail, highlighting seasonal changes in soil gas CO2 concentrations linked primarily to temperature variations. The much larger Sulcis site, studied within an ENEA-funded project on potential CO2-ECBM (Enhanced Coal Bed Methane) deployment, was surveyed at the regional scale and on detailed grids and transects for site assessment purposes. Despite the completely different soil and climate conditions, the statistical distribution of the Sulcis data was similar to that of Volund. Much higher soil gas CO2 anomalies were found at this site, however, due to the less permeable sediments (i.e., better water retention and greater gas accumulation) and the warmer temperatures. Detailed surveys at this site highlighted various significant anomalies, some of which can be explained by near-surface biological processes, whereas others, especially helium anomalies, were more difficult to explain. These results show the utility of baseline surveys and highlight the need for follow-up studies to clarify any unexplained anomalies before any CO2 storage.

The occurrence of high volumes of methane during tunneling operations is a critical safety factor that can influence the choice of different technical approaches for tunnel design and construction. Moreover, gas accumulation can be influenced by fluid migration along spatially focused preferential pathways (i.e. points along faults and fracture zones) that can result in highly variable gas concentrations along the tunnel trace. This paper proposes a methodological approach to minimize the risks, and costs, related to tunnel construction in rocks with potentially high methane concentrations. This approach combines soil gas geochemistry and structural geology surveys along and across the main faults and fracture systems that occur in the study area. The procedure is based on near-surface sampling and consists of a two-pronged approach: the measurement of fault zone gas emissions and their classification as barrier or conduit zones. Moreover, it is illustrated the importance of measuring a wide spectrum of different gas species, not just methane, for a more accurate interpretation of the geological, geochemical, and structural systems. This is due to the potential for multiple gas origins, different gas associations, and various alteration and oxidation processes (e.g., CH4 oxidation into CO2) that can modify the geochemical signal along the flow path as gas migrates towards the surface.

Monitoring of the water column in the vicinity of offshore Carbon Capture and Storage (CCS) sites is needed to ensure site integrity and to protect the surrounding marine ecosystem. In this regard, the use of continuous, autonomous systems is considered greatly advantageous due to the costs and limitations of periodic, ship-based sampling campaigns. While various geochemical monitoring tools have been developed their elevated costs and complexities mean that typically only one unit can be deployed at a time, yielding single point temporal data but no spatial data. To address this the authors have developed low-cost pCO2 sensors (GasPro-pCO2) that are small, robust, stable, and which have a low power consumption, characteristics which allow for the deployment of numerous units to monitor the spatial-temporal distribution of pCO2, temperature, and water pressure in surface water environments. The present article details the results of three field deployments at the natural, CO2-leaking site near Panarea, Island. While the first consisted of 6 probes placed on the sea floor for a 2.5 month period, the other two involved the deployment of 20 GasPro units along a transect through the water column in the vicinity of active CO2 seeps over 2 – 4 days. Results show both transport and mixing processes and highlight the dynamic nature of the leakage-induced marine geochemical anomalies. Implications for monitoring programs as well as potential impacts are discussed.