Contrasting Styles of Inter-Caldera Volcanism in a Peralkaline System: Case Studies from Pantelleria (Sicily Channel, Italy)
Author(s)
Language
English
Obiettivo Specifico
1V. Storia eruttiva
Status
Published
JCR Journal
JCR Journal
Peer review journal
Yes
Journal
Issue/vol(year)
/12 (2022)
ISSN
2075-163X
Publisher
MDPI
Pages (printed)
406
Date Issued
March 2022
Abstract
The recent (<190 ka) volcanic history of Pantelleria is characterized by the eruption of nine
peralkaline ignimbrites, ranging in composition from comenditic trachyte to comendite to pantellerite.
The ~46 ka Green Tuff (GT) was the last of these ignimbrites, which was followed by many effusive
and explosive low-volume eruptions of pantellerite from vents within the caldera moat and along
the caldera rim. Although recent studies have shed additional light on the age, petrochemistry, and
volcanology of the older ignimbrites, there is very little knowledge of magmatism that occurred
between these older ignimbrites, primarily due to the very scarce exposures. In this paper, we present
new field descriptions and geochemical data for three local peralkaline centers never studied before,
two pre-GT and one post-GT, which share a similar setting with respect to the caldera scarps but
differ in terms of their age, composition, and eruptive style. These centers include: (i) the older
(~125 ka) Giache center (comenditic trachyte), (ii) the ~67 ka Attalora center (comendite, pantellerite),
and (iii) the younger (~14 ka) Patite center (pantellerite).
peralkaline ignimbrites, ranging in composition from comenditic trachyte to comendite to pantellerite.
The ~46 ka Green Tuff (GT) was the last of these ignimbrites, which was followed by many effusive
and explosive low-volume eruptions of pantellerite from vents within the caldera moat and along
the caldera rim. Although recent studies have shed additional light on the age, petrochemistry, and
volcanology of the older ignimbrites, there is very little knowledge of magmatism that occurred
between these older ignimbrites, primarily due to the very scarce exposures. In this paper, we present
new field descriptions and geochemical data for three local peralkaline centers never studied before,
two pre-GT and one post-GT, which share a similar setting with respect to the caldera scarps but
differ in terms of their age, composition, and eruptive style. These centers include: (i) the older
(~125 ka) Giache center (comenditic trachyte), (ii) the ~67 ka Attalora center (comendite, pantellerite),
and (iii) the younger (~14 ka) Patite center (pantellerite).
References
1. Rotolo, S.G.; Scaillet, S.; La Felice, S.; Vita-Scaillet, G. A revision of the structure and stratigraphy of pre-Green Tuff ignimbrites at
Pantelleria (Strait of Sicily). J. Vocanol. Geotherm. Res. 2013, 250, 61–74. [CrossRef]
2. Jordan, N.; Rotolo, S.G.; Williams, R.; Speranza, F.; McIntosh, W.C.; Branney, M.J.; Scaillet, S. Explosive eruptive history of
Pantelleria, Italy: Repeated caldera collapse and ignimbrite emplacement at a peralkaline volcano. J. Volcanol. Geotherm. Res. 2018,
349, 47–73. [CrossRef]
3. Jordan, N.; White, J.C.; Macdonald, R.; Rotolo, S.G. Evolution of the magma system of Pantelleria (Italy) from 190 ka to present. C.
R. Geosci. 2021, 349, 133–149. [CrossRef]
4. Mahood, G.A.; Hildreth, W. Geology of the peralkaline volcano at Pantelleria, Strait of Sicily. Bull. Volcanol. 1986, 48,
143–172. [CrossRef]
5. Scaillet, S.; Vita-Scaillet, G.; Rotolo, S.G. Millennial-scale phase relationships between ice-core and Mediterranean marine
records: Insights from high-precision 40Ar/39Ar dating of the Green Tuff of Pantelleria, Sicily Strait. Quat. Sci. Rev. 2013, 78,
141–154. [CrossRef]
6. Williams, R. Emplacement of Radial Pyroclastic Density Currents over Irregular Topography: The Chemically Zoned, Low
Aspect-Ratio Green Tuff Ignimbrite. Ph.D. Thesis, University of Leicester, Leicester, UK, 2010.
7. Rotolo, S.G.; Scaillet, S.; Speranza, F.; White, J.C.; Williams, R.; Jordan, N.J. Volcanological evolution of Pantelleria Island (Strait of
Sicily) peralkaline volcano: A review. C. R. Geosci. 2021, 353 (Suppl. 2), 111–132. [CrossRef]
8. Scaillet, S.; Rotolo, S.G.; La Felice, S.; Vita, G. High-resolution 40Ar/39Ar chronostratigraphy of the post-caldera (<20 ka) volcanic
activity at Pantelleria, Sicily Strait. Earth Planet. Sci. Lett. 2011, 309, 280–290. [CrossRef]
9. Speranza, F.; Landi, P.; D’Ajello Caracciolo, F.; Pignatelli, A. Paleomagnetic dating of the most recent silicic eruptive activity at
Pantelleria (Strait of Sicily). Bull. Volcanol. 2010, 72, 847–858. [CrossRef]
10. Rotolo, S.G.; La Felice, S.; Mangalaviti, A.; Landi, P. Geology and petrochemistry of the recent (<25 ka) silicic volcanism at
Pantelleria Island. Boll. Soc. Geol. It. 2007, 126, 191–208.
11. Civetta, L.; Cornette, Y.; Gillot, P.Y.; Orsi, G. The eruptive history of Pantelleria (Sicily Channel) in the last 50 ka. Bull. Volcanol.
1998, 50, 47–57. [CrossRef]
12. Jordan, N.J. Pre-Green Tuff Explosive Eruptive History, Petrogenesis and Proximal-Distal Tephra Correlations of a Peralkaline
Caldera Volcano: Pantelleria, Italy. Ph.D. Thesis, University of Leicester, Leicester, UK, 2014.
13. Macdonald, R. Nomenclature and petrochemistry of the peralkaline oversaturated extrusive rocks. Bull. Volcanol. 1974, 38,
498–505. [CrossRef]
14. Le Maitre, R.W. (Ed.) Igneous Rocks, a Classification and Glossary of Terms: Recommendations of the International Union of Geological
Sciences Subcommission on the Systematics of Igneous Rocks, 2nd ed.; Cambridge University Press: Cambridge, UK, 2008; 236p.
Minerals 2022, 12, 406 15 of 15
15. Liszewska, K.M.; White, J.C.; MacDonald, R.; Baginski, B. Compositional and thermodynamic variability in a stratified magma
chamber: Evidence from the Green Tuff Ignimbrite (Pantelleria, Italy). J. Petrol. 2018, 59, 2245–2272. [CrossRef]
16. Andersen, D.J.; Lindsley, D.H.; Davidson, P.M. QUILF: A Pascal program to assess equilibria among Fe-Mg-Mn-Ti oxides,
pyroxenes, olivine, and quartz. Comp. Geosci. 1993, 19, 1333–1350. [CrossRef]
17. Lindsley, D.H.; Frost, B.R. Equilibria among Fe-Ti oxides, pyroxenes, olivine, and quartz: Part I, Theory. Am. Mineral. 1992,
77, 987–1003.
18. Anderson, A.T. the oxygen fugacity of alkaline basalt and related magmas, Tristan da Cunha. Am. J. Sci. 1968, 266,
704–727. [CrossRef]
19. Bacon, C.R.; Hirschmann, M.M. Mg/Mn partitioning as a test for equilibrium between coexisting Fe-Ti oxides. Am. Mineral. 1988,
73, 57–61.
20. Andersen, D.J.; Lindsley, D.H. Internally consistent solution models for Fe-Mg-Mn-Ti oxides: Fe-Ti oxides. Am. Mineral. 1988,
73, 714–726.
21. Frost, B.R.; Lindsley, D.H.; Andersen, D.J. Fe-Ti oxide-silicate equilibria: Assemblages with fayalitic olivine. Am. Mineral. 1998,
77, 1004–1020.
22. White, J.C.; Ren, M.; Parker, D.F. Variation in mineralogy, temperature and oxygen fugacity in a suite of strongly peralkaline lavas
and tuffs, Pantelleria, Italy. Can. Mineral. 2005, 43, 1331–1347. [CrossRef]
23. Romano, P.; Scaillet, B.; White, J.C.; Andujar, J.; Di Carlo, I.; Rotolo, S.G. Experimental and thermodynamic constraints on mineral
equilibrium in pantelleritic magmas. Lithos 2020, 376–377, 105793. [CrossRef]
24. White, J.C.; Neave, D.A.; Rotolo, S.G.; Parker, D.F. Geochemical constraints on basalt petrogenesis in the Strait of Sicily Rift Zone
(Italy): Insights into the importance of short lengthscale mantle heterogeneity. Chem. Geol. 2020, 545, 119650. [CrossRef]
25. White, J.C.; Parker, D.F.; Ren, M. The origin of trachyte and pantellerite from Pantelleria, Italy: Insights from major elements,
trace elements, and thermodynamic modelling. J. Volcanol. Geoth. Res. 2009, 179, 33–55. [CrossRef]
26. Di Carlo, I.; Rotolo, S.G.; Scaillet, B.; Buccheri, V.; Pichavant, M. Phase equilibrium constraints on pre-eruptive conditions of
recent felsic explosive volcanism at Pantelleria Island, Italy. J. Petrol. 2010, 51, 2245–2276. [CrossRef]
27. Romano, P.; White, J.C.; Ciulla, A.; Di Carlo, I.; D’Oriano, C.; Landi, P.; Rotolo, S.G. Volatiles and trace elements content
in melt inclusions from the zoned Green Tuff ignimbrite (Pantelleria, Sicily): Petrological inferences. Ann. Geophys.
2019, 62, 1–18. [CrossRef]
28. Gioncada, A.; Landi, P. The pre-eruptive volatile contents of recent basaltic and pantelleritic magmas at Pantelleria (Italy). J.
Volcanol. Geoth. Res. 2010, 189, 191–201. [CrossRef]
29. Lanzo, G.; Landi, P.; Rotolo, S.G. Volatiles in pantellerite magmas: A case study of the GreenTuff Plinian eruption. J. Volcanol.
Geoth. Res. 2013, 262, 153–163. [CrossRef]
30. Neave, D.A.; Fabbro, G.; Herd, R.A.; Petrone, M.C.; Edmonds, M. Melting, differentiation and degassing at the Pantelleria
volcano, Italy. J. Petrol. 2012, 53, 637–663. [CrossRef]
31. Stabile, P.; Arzilli, F.; Carroll, M.R. Crystallization of peralkaline rhyolitic magmas: Pre-and syn-eruptive conditions of the
Pantelleria system. C. R. Geosci. 2021, 353 (Suppl. 2), 151–170. [CrossRef
Pantelleria (Strait of Sicily). J. Vocanol. Geotherm. Res. 2013, 250, 61–74. [CrossRef]
2. Jordan, N.; Rotolo, S.G.; Williams, R.; Speranza, F.; McIntosh, W.C.; Branney, M.J.; Scaillet, S. Explosive eruptive history of
Pantelleria, Italy: Repeated caldera collapse and ignimbrite emplacement at a peralkaline volcano. J. Volcanol. Geotherm. Res. 2018,
349, 47–73. [CrossRef]
3. Jordan, N.; White, J.C.; Macdonald, R.; Rotolo, S.G. Evolution of the magma system of Pantelleria (Italy) from 190 ka to present. C.
R. Geosci. 2021, 349, 133–149. [CrossRef]
4. Mahood, G.A.; Hildreth, W. Geology of the peralkaline volcano at Pantelleria, Strait of Sicily. Bull. Volcanol. 1986, 48,
143–172. [CrossRef]
5. Scaillet, S.; Vita-Scaillet, G.; Rotolo, S.G. Millennial-scale phase relationships between ice-core and Mediterranean marine
records: Insights from high-precision 40Ar/39Ar dating of the Green Tuff of Pantelleria, Sicily Strait. Quat. Sci. Rev. 2013, 78,
141–154. [CrossRef]
6. Williams, R. Emplacement of Radial Pyroclastic Density Currents over Irregular Topography: The Chemically Zoned, Low
Aspect-Ratio Green Tuff Ignimbrite. Ph.D. Thesis, University of Leicester, Leicester, UK, 2010.
7. Rotolo, S.G.; Scaillet, S.; Speranza, F.; White, J.C.; Williams, R.; Jordan, N.J. Volcanological evolution of Pantelleria Island (Strait of
Sicily) peralkaline volcano: A review. C. R. Geosci. 2021, 353 (Suppl. 2), 111–132. [CrossRef]
8. Scaillet, S.; Rotolo, S.G.; La Felice, S.; Vita, G. High-resolution 40Ar/39Ar chronostratigraphy of the post-caldera (<20 ka) volcanic
activity at Pantelleria, Sicily Strait. Earth Planet. Sci. Lett. 2011, 309, 280–290. [CrossRef]
9. Speranza, F.; Landi, P.; D’Ajello Caracciolo, F.; Pignatelli, A. Paleomagnetic dating of the most recent silicic eruptive activity at
Pantelleria (Strait of Sicily). Bull. Volcanol. 2010, 72, 847–858. [CrossRef]
10. Rotolo, S.G.; La Felice, S.; Mangalaviti, A.; Landi, P. Geology and petrochemistry of the recent (<25 ka) silicic volcanism at
Pantelleria Island. Boll. Soc. Geol. It. 2007, 126, 191–208.
11. Civetta, L.; Cornette, Y.; Gillot, P.Y.; Orsi, G. The eruptive history of Pantelleria (Sicily Channel) in the last 50 ka. Bull. Volcanol.
1998, 50, 47–57. [CrossRef]
12. Jordan, N.J. Pre-Green Tuff Explosive Eruptive History, Petrogenesis and Proximal-Distal Tephra Correlations of a Peralkaline
Caldera Volcano: Pantelleria, Italy. Ph.D. Thesis, University of Leicester, Leicester, UK, 2014.
13. Macdonald, R. Nomenclature and petrochemistry of the peralkaline oversaturated extrusive rocks. Bull. Volcanol. 1974, 38,
498–505. [CrossRef]
14. Le Maitre, R.W. (Ed.) Igneous Rocks, a Classification and Glossary of Terms: Recommendations of the International Union of Geological
Sciences Subcommission on the Systematics of Igneous Rocks, 2nd ed.; Cambridge University Press: Cambridge, UK, 2008; 236p.
Minerals 2022, 12, 406 15 of 15
15. Liszewska, K.M.; White, J.C.; MacDonald, R.; Baginski, B. Compositional and thermodynamic variability in a stratified magma
chamber: Evidence from the Green Tuff Ignimbrite (Pantelleria, Italy). J. Petrol. 2018, 59, 2245–2272. [CrossRef]
16. Andersen, D.J.; Lindsley, D.H.; Davidson, P.M. QUILF: A Pascal program to assess equilibria among Fe-Mg-Mn-Ti oxides,
pyroxenes, olivine, and quartz. Comp. Geosci. 1993, 19, 1333–1350. [CrossRef]
17. Lindsley, D.H.; Frost, B.R. Equilibria among Fe-Ti oxides, pyroxenes, olivine, and quartz: Part I, Theory. Am. Mineral. 1992,
77, 987–1003.
18. Anderson, A.T. the oxygen fugacity of alkaline basalt and related magmas, Tristan da Cunha. Am. J. Sci. 1968, 266,
704–727. [CrossRef]
19. Bacon, C.R.; Hirschmann, M.M. Mg/Mn partitioning as a test for equilibrium between coexisting Fe-Ti oxides. Am. Mineral. 1988,
73, 57–61.
20. Andersen, D.J.; Lindsley, D.H. Internally consistent solution models for Fe-Mg-Mn-Ti oxides: Fe-Ti oxides. Am. Mineral. 1988,
73, 714–726.
21. Frost, B.R.; Lindsley, D.H.; Andersen, D.J. Fe-Ti oxide-silicate equilibria: Assemblages with fayalitic olivine. Am. Mineral. 1998,
77, 1004–1020.
22. White, J.C.; Ren, M.; Parker, D.F. Variation in mineralogy, temperature and oxygen fugacity in a suite of strongly peralkaline lavas
and tuffs, Pantelleria, Italy. Can. Mineral. 2005, 43, 1331–1347. [CrossRef]
23. Romano, P.; Scaillet, B.; White, J.C.; Andujar, J.; Di Carlo, I.; Rotolo, S.G. Experimental and thermodynamic constraints on mineral
equilibrium in pantelleritic magmas. Lithos 2020, 376–377, 105793. [CrossRef]
24. White, J.C.; Neave, D.A.; Rotolo, S.G.; Parker, D.F. Geochemical constraints on basalt petrogenesis in the Strait of Sicily Rift Zone
(Italy): Insights into the importance of short lengthscale mantle heterogeneity. Chem. Geol. 2020, 545, 119650. [CrossRef]
25. White, J.C.; Parker, D.F.; Ren, M. The origin of trachyte and pantellerite from Pantelleria, Italy: Insights from major elements,
trace elements, and thermodynamic modelling. J. Volcanol. Geoth. Res. 2009, 179, 33–55. [CrossRef]
26. Di Carlo, I.; Rotolo, S.G.; Scaillet, B.; Buccheri, V.; Pichavant, M. Phase equilibrium constraints on pre-eruptive conditions of
recent felsic explosive volcanism at Pantelleria Island, Italy. J. Petrol. 2010, 51, 2245–2276. [CrossRef]
27. Romano, P.; White, J.C.; Ciulla, A.; Di Carlo, I.; D’Oriano, C.; Landi, P.; Rotolo, S.G. Volatiles and trace elements content
in melt inclusions from the zoned Green Tuff ignimbrite (Pantelleria, Sicily): Petrological inferences. Ann. Geophys.
2019, 62, 1–18. [CrossRef]
28. Gioncada, A.; Landi, P. The pre-eruptive volatile contents of recent basaltic and pantelleritic magmas at Pantelleria (Italy). J.
Volcanol. Geoth. Res. 2010, 189, 191–201. [CrossRef]
29. Lanzo, G.; Landi, P.; Rotolo, S.G. Volatiles in pantellerite magmas: A case study of the GreenTuff Plinian eruption. J. Volcanol.
Geoth. Res. 2013, 262, 153–163. [CrossRef]
30. Neave, D.A.; Fabbro, G.; Herd, R.A.; Petrone, M.C.; Edmonds, M. Melting, differentiation and degassing at the Pantelleria
volcano, Italy. J. Petrol. 2012, 53, 637–663. [CrossRef]
31. Stabile, P.; Arzilli, F.; Carroll, M.R. Crystallization of peralkaline rhyolitic magmas: Pre-and syn-eruptive conditions of the
Pantelleria system. C. R. Geosci. 2021, 353 (Suppl. 2), 151–170. [CrossRef
Type
article
File(s)![Thumbnail Image]()
Loading...
Name
Romano et al 22 copia.pdf
Description
Open Access published article
Size
5.44 MB
Format
Adobe PDF
Checksum (MD5)
d634ea3f01aa9db747879cfc3e2e4d57