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Avellone, Giuseppe
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Avellone, Giuseppe
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- PublicationRestrictedGroundwater of Sicily (Italy) Close to Landfill Sites: Quality and Human Health Risk Assessment(2021-05-30)
; ; ; ; ; ; ; ; ; ; ; ; ; ;; ; ;Groundwater close to three municipal solid waste landfll sites in Sicily (southern Italy) was sampled to determine the presence of contaminants and the risk associated with its possible use as drinking and sanitary water. Polycyclic aromatic hydrocarbons, polychlorinated biphenyls, polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, and metals were investigated. These target compounds are the most common pollutants present in leachates. Risk Assessment Guidance for Superfund (RAGS, US EPA) was used to assess human health risk. Ingestion, dermal, and total exposure to these xenobiotic contaminants in groundwater were evaluated, and the cancer and non-cancer risk indexes were calculated. The results revealed that, while the groundwater complied with Italian Drinking Water Directive 30/2001, it did not comply with the "good environmental state" criteria of Directive 30/2009 at two of the three sites investigated. Worrying results were revealed by the risk assessment at the investigated sites. Cancer and non-cancer risk indexes indicated a probable risk, mainly due to dermal exposure to groundwater. These results underline the importance of assessing the risk for all possible routes, evaluating not only ingestion but also dermal exposure, especially when organic pollutants are present. The results of this study show that human health risk has probably been underestimated in the past, as dermal exposure to organic pollutants has only rarely been evaluated in the literature.149 196 - PublicationRestrictedDistribution of volatile organic compounds in Sicilian groundwaters analysed by head space-solid phase micro extraction coupled with gas chromatography mass spectrometry (SPME/GC/MS)(2008-07-24)
; ; ; ; ; ; ; ; ;Pecoraino, G.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia ;Scalici, L.; Dipartimento di Chimica e Tecnologie Farmaceutiche, Università di Palermo ;Avellone, G.; Dipartimento di Chimica e Tecnologie Farmaceutiche, Università di Palermo ;Ceraulo, L.; Dipartimento di Chimica e Tecnologie Farmaceutiche, Università di Palermo ;Favara, R.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia ;Gagliano Candela, E.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia ;Provenzano, M. C.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia ;Scaletta, C.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia; ; ; ; ; ; ; This work presents the results of an assessment of the existence and concentration of 13 volatile organic compounds (VOCs) in groundwaters from 14 hydrological basins in Sicily (25,710 km2). On the basis of hydrological, hydrogeochemical and geological studies, 324 sampling points were selected. All groundwater sampled were collected twice, from October to December 2004 and from February to May 2005, and were analysed to determine the concentration and spatial distribution of the VOCs in the aquifers. The need to analyze a large number of samples in a short space of time so as to obtain quantitative analyses in trace concentration levels spurred us to create a new analytical method, both simple and sensitive, based on HS-SPME/GC/MS. The concentrations of VOCs measured in industrial and intensive agricultural unconfined aquifers were greater than those found in other aquifers. Tetrachloroethylene, chloroform, trichloroethylene and 1,2-dichloropropane were the most frequently detected VOCs. However, they exceeded the guideline values proposed by the EU in only three aquifers located near to industrial and intense agricultural areas.350 30 - PublicationOpen AccessUnderstanding Paleomagnetic Rotations in Sicily: Thrust Versus Strike-Slip Tectonics(2018)
; ; ; ; ; ; ; ; ; ; ; ; ;The paleomagnetic investigation of the western Sicily Maghrebian belt has revealed since the 1970s that large clockwise rotations up to 140° with respect to the Hyblean-African foreland occurred synchronous with Tertiary shortening of the chain. The observation that rotations decrease stepwise from internal to external tectono-stratigraphic units led in the 1990s to a widely accepted model postulating that rotational thrust-sheet emplaced during forward orogenic propagation. More recently, other authors suggested that clockwise rotations from Sicily are conversely the result of late orogenic dextral strike-slip tectonics. Here we report on a paleomagnetic investigation of 30 Jurassic-Eocene sedimentary sites sampled mainly across the WNW-ESE Mt. Kumeta and Rocca Busambra ridges (Trapanese Unit), both bounded to the north by high-angle reverse faults with dextral strike-slip components. We find rotations of 110°–120° at faults of northern ridge margins, which decrease to 80°–90° at ~200 m to the south and rise again moving further south. Thus, an excess rotation of 20°–40° due to dextral-strike-slip shear is annulled to the regional rotational background of the Trapanese Unit at only 200 m from fault traces, translating to paleomagnetically calculated strike-slip offsets not exceeding 600 m. Further north, seven sites sampled in the Imerese Unit, tectonically stacked above the Trapanese Unit, yield a ~130° rotation. Thus, our data confirm that CW rotations in Sicily are predominantly related to thrust-sheet emplacement. Strike-slip tectonics has very limited relevance and gives local rotations that fade out at only 200 m from fault planes.304 29 - PublicationRestrictedAssessment of a geological model by surface wave analysesA set of horizontal to vertical spectral ratio (HVSR) and multichannel analysis of surface waves (MASW) measurements, carried out in the Altavilla Milicia (Sicily) area, is analyzed to test a geological model of the area. Statistical techniques have been used in different stages of the data analysis, to optimize the reliability of the information extracted from geophysical measurements. In particular, cluster analysis algorithms have been implemented to select the time windows of the microseismic signal to be used for calculating the spectral ratio H/V and to identify sets of spectral ratio peaks likely caused by the same underground structures. Using results of reflection seismic lines, typical values of P-wave and S-wave velocity were estimated for each geological formation present in the area. These were used to narrow down the research space of parameters for the HVSR interpretation. MASW profiles have been carried out close to each HVSR measuring point, provided the parameters of the shallower layers for the HVSR models. MASW inversion has been constrained by extrapolating thicknesses from a known stratigraphic sequence. Preliminary 1D seismic models were obtained by adding deeper layers to models that resulted from MASW inversion. These justify the peaks of the HVSR curves due to layers deeper than MASW investigation depth. Furthermore, much deeper layers were included in the HVSR model, as suggested by geological setting and stratigraphic sequence. This choice was made considering that these latter layers do not generate other HVSR peaks and do not significantly affect the misfit. The starting models have been used to limit the starting research space for a more accurate interpretation, made considering the noise as a superposition of Rayleigh and Love waves. Results allowed to recognize four main seismic layers and to associate them to the main stratigraphic successions. The lateral correlation of seismic velocity models, joined with tectonic evidences, allowed to plot two geological sections, showing the main pattern of geological formations and tectonic structures. © 2016 Sinopec Geophysical Research Institute.
175 4 - PublicationOpen AccessGeology of the lower Belice River valley, epicentral area of the M > 5 1968 seismic sequence (south-western Sicily, Italy)(2023-08-08)
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; We present a new 1:25,000-scale geological map of the lower Belice River valley, the area struck by the M > 5.0 devastating 1968 seismic sequence, whose seismic source and seismotectonic framework are still controversial. The map, utilizing dating methods and traditional field survey approaches integrated by high-resolution topography, provides an unprecedented detail and precision on the spatial distribution and on the compressional growth geometries of the prominent sedimentary sequence. This map, supported by the first recognition of an on-shore Chibanian-Calabrian deposition and by identifying a flight of marine terraces, offers new insights on the long-lasting syn-depositional tectonic forces up to late-Pleistocene-Holocene times. Such tectonic forces may take part in the regional ongoing deformational phase, prompting detailed studies on the potential seismic sources affecting the area.77 10 - PublicationRestrictedEffect of solid waste landfill organic pollutants on groundwater in three areas of Sicily (Italy) characterized by different vulnerability(2017-06-01)
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ;; ; ; ;; ; ; ; ; ; ; ; ;The aim of this study was to obtain information on the presence and levels of hazardous organic pollutants in groundwater located close to solid waste landfills. Eighty-two environmental contaminants, including 16 polycyclic aromatic hydrocarbons (PAHs), 20 volatile organic compounds (VOCs), 29 polychlorinated biphenyls (PCBs), 7 dioxins (polychlorinated dibenzo-p-dioxins, PCDDs) and 10 furans (polychlorinated dibenzofurans, PCDFs) were monitored in areas characterised by different geological environments surrounding three municipal solid waste landfills (Palermo, Siculiana and Ragusa) in Sicily (Italy) in three sampling campaigns. The total concentrations of the 16 PAHs were always below the legal threshold. Overall, the Fl/Fl + Py diagnostic ratio revealed that PAHs had a petrogenic origin. VOC levels, except for two notable exceptions near Palermo landfill, were always below the legal limit. As concerns PCB levels, several samples were found positive with levels exceeding the legal limits. It is worth noting that the % PCB distribution differs from that of commercial compositions. In parallel, some samples of groundwater containing PCDDs and PCDFs exceeding the legal threshold were also found. Among the 17 congeners monitored, the most abundant were the highest molecular weight ones.794 9