Carbon dioxide diffuse emission from the soil: ten years of observations at Vesuvio and Campi Flegrei (Pozzuoli), and linkages with volcanic activity
Language
English
Obiettivo Specifico
1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
2.4. TTC - Laboratori di geochimica dei fluidi
4.5. Studi sul degassamento naturale e sui gas petroliferi
Status
Published
JCR Journal
JCR Journal
Peer review journal
Yes
Journal
Issue/vol(year)
/72(2010)
Publisher
Springer-Verlag
Pages (printed)
103-118
Date Issued
2010
Alternative Location
Abstract
Carbon dioxide flux from the soil is regularly
monitored in selected areas of Vesuvio and Solfatara
(Campi Flegrei, Pozzuoli) with the twofold aim of i)
monitoring spatial and temporal variations of the degassing
process and ii) investigating if the surface phenomena could
provide information about the processes occurring at depth.
At present, the surveyed areas include 15 fixed points
around the rim of Vesuvio and 71 fixed points in the floor
of Solfatara crater. Soil CO2 flux has been measured since
1998, at least once a month, in both areas. In addition, two
automatic permanent stations, located at Vesuvio and
Solfatara, measure the CO2 flux and some environmental
parameters that can potentially influence the CO2 diffuse
degassing. Series acquired by continuous stations are
characterized by an annual periodicity that is related to
the typical periodicities of some meteorological parameters.
Conversely, series of CO2 flux data arising from periodic
measurements over the arrays of Vesuvio and Solfatara are
less dependent on external factors such as meteorological
parameters, local soil properties (porosity, hydraulic conductivity)
and topographic effects (high or low ground).
Therefore we argue that the long-term trend of this signal
contains the “best” possible representation of the endogenous
signal related to the upflow of deep hydrothermal
fluids.
monitored in selected areas of Vesuvio and Solfatara
(Campi Flegrei, Pozzuoli) with the twofold aim of i)
monitoring spatial and temporal variations of the degassing
process and ii) investigating if the surface phenomena could
provide information about the processes occurring at depth.
At present, the surveyed areas include 15 fixed points
around the rim of Vesuvio and 71 fixed points in the floor
of Solfatara crater. Soil CO2 flux has been measured since
1998, at least once a month, in both areas. In addition, two
automatic permanent stations, located at Vesuvio and
Solfatara, measure the CO2 flux and some environmental
parameters that can potentially influence the CO2 diffuse
degassing. Series acquired by continuous stations are
characterized by an annual periodicity that is related to
the typical periodicities of some meteorological parameters.
Conversely, series of CO2 flux data arising from periodic
measurements over the arrays of Vesuvio and Solfatara are
less dependent on external factors such as meteorological
parameters, local soil properties (porosity, hydraulic conductivity)
and topographic effects (high or low ground).
Therefore we argue that the long-term trend of this signal
contains the “best” possible representation of the endogenous
signal related to the upflow of deep hydrothermal
fluids.
References
Acocella V, Salvini F, Funiciello R, Faccenna C (1999) The role of
transfer structures on volcanic activity at Campi Flegrei (Southern
Italy). J Volcanol Geotherm Res 62:123–139
Allard P, Maiorani A, Tedesco D, Cortecci G, Turi B (1991) Isotopic
study of the origin of sulfur and carbon in Solfatara fumaroles,
Campi Flegrei caldera. J Volcanol Geotherm Res 48:139–159
Andronico D, Calderoni G, Cioni R, Sbrana A, Sulpizio R, Santacroce
R (1995) Geological map of Somma-Vesuvius volcano. Per
Mineral 64:77–78
Barberi F, Corrado G, Innocenti F, Luongo G (1984) Phlegrean fields
1982–1984: brief chronicle of a volcano emergency in a densely
populated area. Bull Volcanol 47:175–185
Barberi F, CarapezzaM, Innocenti F, Luongo G, Santacroce R (1989) The
problem of volcanic unrest: the Phlegraean fields case history. Atti
convegno Accademia Nazionale dei Lincei 80:387–405
Baubron JC, Allard P, Toutain JP (1990) Diffuse volcanic emissions of
carbon dioxide from Vulcano Island, Italy. Nature 344:51–53
Bianco F, Del Pezzo E, Saccorotti G, Ventura G (2004) The role of
hydrothermal fluids in triggering the July–August 2000 seismic
swarm at Campi Flegrei, Italy: evidence from seismological and
mesostructural data. J Volcanol Geotherm Res 133:229–246
Brombach T, Hunziker JC, Chiodini G, Cardellini C, Marini L (2001)
Soil diffuse degassing and thermal energy fluxes from the
southern Lakki plain, Nisyros (Greece). Geophys Res Lett
28:69–72
Carapezza ML, Granieri D (2004) CO2 soil flux at Vulcano (Italy):
comparison of active and passive methods. Appl Geochem
19:73–88
Cardellini C, Chiodini G, Frondini F (2003) Application of stochastic
simulation to CO2 flux from soil: mapping and quantification
of gas release. J Geophys Res 108:2425. doi:10.1029/
2002JB002165
Chiodini G, Frondini F, Raco B (1996) Diffuse emission of CO2 from
the Fossa crater, Vulcano Island (Italy). Bull Volcanol 58:41–50
Chiodini G, Cioni R, Guidi M, Marini L, Raco B (1998) Soil CO2
measurements in volcanic and geothermal areas. Appl Geochem
13:543–552
Chiodini G, Frondini F, Cardellini C, Granieri D, Marini L, Ventura G
(2001a) CO2 degassing and energy release at Solfatara Volcano,
Campi Flegrei, Italy. J Geophys Res 106:16213–16221
Chiodini G, Marini L, Russo M (2001b) Geochemical evidences of
high temperature hydrothermal brines at Vesuvio volcano (Italy).
Geochim Cosmochim Acta 65:2129–2147
Chiodini G, Todesco M, Caliro S, Del Gaudio C, Macedonio G, Russo
M (2003) Magma degassing as a trigger of bradyseismic events:
the case of Phlegrean Fields (Italy). Geophys Res Lett 30:1434.
doi:10.1029/2002GL016790
Chiodini G, Granieri D, Avino R, Caliro S, Costa A, Werner C (2005)
Carbon dioxide diffuse degassing and estimation of heat release
from volcanic and hydrothermal systems. J Geophys Res 110:
B08204. doi:10.1029/2004JB003542
Chiodini G, Caliro S, Cardellini C, Avino R, Granieri D, Schmidt A
(2008) Carbon isotopic composition of soil CO2 efflux, a
powerful method to discriminate different sources feeding soil
CO2 degassing in volcanic-hydrothermal areas. Earth Planet Sci
Lett 274:372–379
Cioni R, Santacroce R, Sbrana A (1999) Pyroclastic deposits as a
guide for reconstructing the multi-stage evolution of the Somma-
Vesuvius caldera. Bull Volcanol 61:207–222
De Natale G, Troise C, Pingue F, Mastrolorenzo G, Pappalardo L,
Battaglia M, Boschi E (2006) The Campi Flegrei caldera: Unrest
mechanisms and hazards. In: Troise C, De Natale G, Kilburn CRJ
(eds) Mechanisms of activity and unrest at large calderas. Geol
Soc London Spec Pub 269:25–45
De Vivo B, Rolandi G, Gans PB, Calvert A, Bohrson WA, Spera FJ,
Belkin HE (2001) New constraints on the pyroclastic eruptive
history of the Campanian Volcanic Plain (Italy). Mineral Petrol
73:47–65
Deino AL, Orsi G, De Vita S, Piochi M (2004) The age of the
Neapolitan Yellow Tuff caldera forming eruption (Campi Flegrei
caldera Italy) assessed by 40Ar/39Ar dating method. J Volcanol
Geotherm Res 133:157–170
Deutsch CV, Journel AG (1998) GSLIB: geostatistical software library
and users guide. Oxford Univ Press, New York
Di Renzo V, Di Vito MA, Arienzo I, Civetta L, D’Antonio M, Giordano
F, Orsi G, Tonarini S (2007) Magmatic history of Somma-
Vesuvius on the basis of new geochemical and isotopic data from
a deep borehole (Camaldoli della Torre). J Petrol 48:753–784
Di Vito MA, Lirer L, Mastrolorenzo G, Rolandi G (1987) The 1538
Monte Nuovo eruption (Campi Flegrei, Italy). Bull Volcanol
49:608–615
Frondini F, Chiodini G, Caliro S, Cardellini C, Granieri D, Ventura G
(2004) Diffuse CO2 degassing at Vesuvio, Italy. Bull Volcanol
66:642–651. doi:10.1007/s00445-004-0346-x
Garside MJ (1971) Best subset search. Appl Stat 20:112–115
Gilbert RO (1987) Statistical methods for environmental pollution
monitoring. Van Nostrand-Reinhold, New York
Granieri D, Chiodini G, Marzocchi W, Avino R (2003) Continuous
monitoring of CO2 soil diffuse degassing at Phlegraean Fields
(Italy): influence of environmental and volcanic parameters.
Earth Planet Sci Lett 212:167–179
Orsi G, Di Vito MA, de Vita S (1996) The restless, resurgent Campi
Flegrei Nested Caldera (Italy): constraints on its evolution and
configuration. J Volcanol Geotherm Res 74:179–214
Rogie JD, Kerrick DM, Sorey ML, Chiodini G, Galloway DL (2001)
Dynamic of carbon dioxide emission at Mammoth Mountain,
California. Earth Planet Sci Lett 188:535–541
Rosi M, Sbrana A (eds) (1987) Phlegraean fields. Quaderni de “La
Ricerca Scientifica” 114(9) CNR, Roma
Saccorotti G, Bianco F, Castellano M, Del Pezzo E (2001) The July-
August 2000 seismic swarms at Campi Flegrei volcanic complex,
Italy. Geophys Res Lett 28:2525–2528
Salazar JML, Hernandez PA, Perez NM, Melian G, Alvarez J, Notsu K
(2001) Diffuse emission of carbon dioxide from Cerro Negro volcano,
Nicaragua, Central America. Geophys Res Lett 28:4275–4278
Santacroce R (ed) (1987) Somma-Vesuvius. Quaderni de “La Ricerca
Scientifica” 114(8) CNR, Roma
Santacroce R, Cioni R, Marianelli P, Sbrana A (2005) Understanding
Vesuvius and preparing for its next eruption. In: Balmuth MS,
Chester DK, Johnston PA (eds) Cultural responses to the volcanic
landscape; the Mediterranean and beyond. Archaeological Institute
of America, pp 27–55
Todesco M, Chiodini G, Macedonio G (2003) Monitoring and
modelling hydrothermal fluid emission at La Solfatara (Phlegrean
Fields, Italy). An interdisciplinary approach to the study of
diffuse degassing. J Volcanol Geotherm Res 125:57–79
Troise C, De Natale G, Pingue F, Obrizzo F, De Martino P, Tammaro
U, Boschi E (2007) Renewed ground uplift at Campi Flegrei
caldera (Italy): new insight on magmatic processes and forecast.
Geophys Res Lett 34:L03301. doi:10.1029/2006GL028545
transfer structures on volcanic activity at Campi Flegrei (Southern
Italy). J Volcanol Geotherm Res 62:123–139
Allard P, Maiorani A, Tedesco D, Cortecci G, Turi B (1991) Isotopic
study of the origin of sulfur and carbon in Solfatara fumaroles,
Campi Flegrei caldera. J Volcanol Geotherm Res 48:139–159
Andronico D, Calderoni G, Cioni R, Sbrana A, Sulpizio R, Santacroce
R (1995) Geological map of Somma-Vesuvius volcano. Per
Mineral 64:77–78
Barberi F, Corrado G, Innocenti F, Luongo G (1984) Phlegrean fields
1982–1984: brief chronicle of a volcano emergency in a densely
populated area. Bull Volcanol 47:175–185
Barberi F, CarapezzaM, Innocenti F, Luongo G, Santacroce R (1989) The
problem of volcanic unrest: the Phlegraean fields case history. Atti
convegno Accademia Nazionale dei Lincei 80:387–405
Baubron JC, Allard P, Toutain JP (1990) Diffuse volcanic emissions of
carbon dioxide from Vulcano Island, Italy. Nature 344:51–53
Bianco F, Del Pezzo E, Saccorotti G, Ventura G (2004) The role of
hydrothermal fluids in triggering the July–August 2000 seismic
swarm at Campi Flegrei, Italy: evidence from seismological and
mesostructural data. J Volcanol Geotherm Res 133:229–246
Brombach T, Hunziker JC, Chiodini G, Cardellini C, Marini L (2001)
Soil diffuse degassing and thermal energy fluxes from the
southern Lakki plain, Nisyros (Greece). Geophys Res Lett
28:69–72
Carapezza ML, Granieri D (2004) CO2 soil flux at Vulcano (Italy):
comparison of active and passive methods. Appl Geochem
19:73–88
Cardellini C, Chiodini G, Frondini F (2003) Application of stochastic
simulation to CO2 flux from soil: mapping and quantification
of gas release. J Geophys Res 108:2425. doi:10.1029/
2002JB002165
Chiodini G, Frondini F, Raco B (1996) Diffuse emission of CO2 from
the Fossa crater, Vulcano Island (Italy). Bull Volcanol 58:41–50
Chiodini G, Cioni R, Guidi M, Marini L, Raco B (1998) Soil CO2
measurements in volcanic and geothermal areas. Appl Geochem
13:543–552
Chiodini G, Frondini F, Cardellini C, Granieri D, Marini L, Ventura G
(2001a) CO2 degassing and energy release at Solfatara Volcano,
Campi Flegrei, Italy. J Geophys Res 106:16213–16221
Chiodini G, Marini L, Russo M (2001b) Geochemical evidences of
high temperature hydrothermal brines at Vesuvio volcano (Italy).
Geochim Cosmochim Acta 65:2129–2147
Chiodini G, Todesco M, Caliro S, Del Gaudio C, Macedonio G, Russo
M (2003) Magma degassing as a trigger of bradyseismic events:
the case of Phlegrean Fields (Italy). Geophys Res Lett 30:1434.
doi:10.1029/2002GL016790
Chiodini G, Granieri D, Avino R, Caliro S, Costa A, Werner C (2005)
Carbon dioxide diffuse degassing and estimation of heat release
from volcanic and hydrothermal systems. J Geophys Res 110:
B08204. doi:10.1029/2004JB003542
Chiodini G, Caliro S, Cardellini C, Avino R, Granieri D, Schmidt A
(2008) Carbon isotopic composition of soil CO2 efflux, a
powerful method to discriminate different sources feeding soil
CO2 degassing in volcanic-hydrothermal areas. Earth Planet Sci
Lett 274:372–379
Cioni R, Santacroce R, Sbrana A (1999) Pyroclastic deposits as a
guide for reconstructing the multi-stage evolution of the Somma-
Vesuvius caldera. Bull Volcanol 61:207–222
De Natale G, Troise C, Pingue F, Mastrolorenzo G, Pappalardo L,
Battaglia M, Boschi E (2006) The Campi Flegrei caldera: Unrest
mechanisms and hazards. In: Troise C, De Natale G, Kilburn CRJ
(eds) Mechanisms of activity and unrest at large calderas. Geol
Soc London Spec Pub 269:25–45
De Vivo B, Rolandi G, Gans PB, Calvert A, Bohrson WA, Spera FJ,
Belkin HE (2001) New constraints on the pyroclastic eruptive
history of the Campanian Volcanic Plain (Italy). Mineral Petrol
73:47–65
Deino AL, Orsi G, De Vita S, Piochi M (2004) The age of the
Neapolitan Yellow Tuff caldera forming eruption (Campi Flegrei
caldera Italy) assessed by 40Ar/39Ar dating method. J Volcanol
Geotherm Res 133:157–170
Deutsch CV, Journel AG (1998) GSLIB: geostatistical software library
and users guide. Oxford Univ Press, New York
Di Renzo V, Di Vito MA, Arienzo I, Civetta L, D’Antonio M, Giordano
F, Orsi G, Tonarini S (2007) Magmatic history of Somma-
Vesuvius on the basis of new geochemical and isotopic data from
a deep borehole (Camaldoli della Torre). J Petrol 48:753–784
Di Vito MA, Lirer L, Mastrolorenzo G, Rolandi G (1987) The 1538
Monte Nuovo eruption (Campi Flegrei, Italy). Bull Volcanol
49:608–615
Frondini F, Chiodini G, Caliro S, Cardellini C, Granieri D, Ventura G
(2004) Diffuse CO2 degassing at Vesuvio, Italy. Bull Volcanol
66:642–651. doi:10.1007/s00445-004-0346-x
Garside MJ (1971) Best subset search. Appl Stat 20:112–115
Gilbert RO (1987) Statistical methods for environmental pollution
monitoring. Van Nostrand-Reinhold, New York
Granieri D, Chiodini G, Marzocchi W, Avino R (2003) Continuous
monitoring of CO2 soil diffuse degassing at Phlegraean Fields
(Italy): influence of environmental and volcanic parameters.
Earth Planet Sci Lett 212:167–179
Orsi G, Di Vito MA, de Vita S (1996) The restless, resurgent Campi
Flegrei Nested Caldera (Italy): constraints on its evolution and
configuration. J Volcanol Geotherm Res 74:179–214
Rogie JD, Kerrick DM, Sorey ML, Chiodini G, Galloway DL (2001)
Dynamic of carbon dioxide emission at Mammoth Mountain,
California. Earth Planet Sci Lett 188:535–541
Rosi M, Sbrana A (eds) (1987) Phlegraean fields. Quaderni de “La
Ricerca Scientifica” 114(9) CNR, Roma
Saccorotti G, Bianco F, Castellano M, Del Pezzo E (2001) The July-
August 2000 seismic swarms at Campi Flegrei volcanic complex,
Italy. Geophys Res Lett 28:2525–2528
Salazar JML, Hernandez PA, Perez NM, Melian G, Alvarez J, Notsu K
(2001) Diffuse emission of carbon dioxide from Cerro Negro volcano,
Nicaragua, Central America. Geophys Res Lett 28:4275–4278
Santacroce R (ed) (1987) Somma-Vesuvius. Quaderni de “La Ricerca
Scientifica” 114(8) CNR, Roma
Santacroce R, Cioni R, Marianelli P, Sbrana A (2005) Understanding
Vesuvius and preparing for its next eruption. In: Balmuth MS,
Chester DK, Johnston PA (eds) Cultural responses to the volcanic
landscape; the Mediterranean and beyond. Archaeological Institute
of America, pp 27–55
Todesco M, Chiodini G, Macedonio G (2003) Monitoring and
modelling hydrothermal fluid emission at La Solfatara (Phlegrean
Fields, Italy). An interdisciplinary approach to the study of
diffuse degassing. J Volcanol Geotherm Res 125:57–79
Troise C, De Natale G, Pingue F, Obrizzo F, De Martino P, Tammaro
U, Boschi E (2007) Renewed ground uplift at Campi Flegrei
caldera (Italy): new insight on magmatic processes and forecast.
Geophys Res Lett 34:L03301. doi:10.1029/2006GL028545
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