Degassing regime of Hekla volcano 2012–2013
Author(s)
Language
English
Obiettivo Specifico
6V. Pericolosità vulcanica e contributi alla stima del rischio
Status
Published
JCR Journal
JCR Journal
Peer review journal
Yes
Journal
Issue/vol(year)
/159 (2015)
ISSN
0016-7037
Publisher
Elsevier
Pages (printed)
80-99
Date Issued
2015
Alternative Location
Subjects
Abstract
Hekla is a frequently active volcano with an infamously short pre-eruptive warning period. Our project contributes to the ongoing work on improving Hekla’s monitoring and early warning systems. In 2012 we began monitoring gas release at Hekla. The dataset comprises semi-permanent near-real time measurements with a MultiGAS system, quantification of diffuse gas flux, and direct samples analysed for composition and isotopes (δ13C, δD and δ18O). In addition, we used reaction path modelling to derive information on the origin and reaction pathways of the gas emissions.
Hekla’s quiescent gas composition was CO2-dominated (0.8 mol fraction) and the δ13C signature was consistent with published values for Icelandic magmas. The gas is poor in H2O and S compared to hydrothermal manifestations and syn-eruptive emissions from other active volcanic systems in Iceland. The total CO2 flux from Hekla central volcano (diffuse soil emissions) is at least 44 T d−1, thereof 14 T d−1 are sourced from a small area at the volcano’s summit. There was no detectable gas flux at other craters, even though some of them had higher ground temperatures and had erupted more recently.
Our measurements are consistent with a magma reservoir at depth coupled with a shallow dike beneath the summit. In the current quiescent state, the composition of the exsolved gas is substantially modified along its pathway to the surface through cooling and interaction with wall-rock and groundwater. The modification involves both significant H2O condensation and scrubbing of S-bearing species, leading to a CO2-dominated gas emitted at the summit. We conclude that a compositional shift towards more S- and H2O-rich gas compositions if measured in the future by the permanent MultiGAS station should be viewed as sign of imminent volcanic unrest on Hekla.
Hekla’s quiescent gas composition was CO2-dominated (0.8 mol fraction) and the δ13C signature was consistent with published values for Icelandic magmas. The gas is poor in H2O and S compared to hydrothermal manifestations and syn-eruptive emissions from other active volcanic systems in Iceland. The total CO2 flux from Hekla central volcano (diffuse soil emissions) is at least 44 T d−1, thereof 14 T d−1 are sourced from a small area at the volcano’s summit. There was no detectable gas flux at other craters, even though some of them had higher ground temperatures and had erupted more recently.
Our measurements are consistent with a magma reservoir at depth coupled with a shallow dike beneath the summit. In the current quiescent state, the composition of the exsolved gas is substantially modified along its pathway to the surface through cooling and interaction with wall-rock and groundwater. The modification involves both significant H2O condensation and scrubbing of S-bearing species, leading to a CO2-dominated gas emitted at the summit. We conclude that a compositional shift towards more S- and H2O-rich gas compositions if measured in the future by the permanent MultiGAS station should be viewed as sign of imminent volcanic unrest on Hekla.
Sponsors
The research leading to these results has received funding from
the Icelandic Centre for Research (RANNIS, grant number
110002-0031); the European Community’s Seventh Framework
Programme under Grant Agreement No. 308377 (Project
FUTUREVOLC); and the International Civil Aviation
Organization.
the Icelandic Centre for Research (RANNIS, grant number
110002-0031); the European Community’s Seventh Framework
Programme under Grant Agreement No. 308377 (Project
FUTUREVOLC); and the International Civil Aviation
Organization.
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293–316.
Flaathen T., Gislason S. R., Oelkers E. and Sveinbjornsdottir A.
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a natural analogue for CO2 sequestration in basaltic
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Fridriksson T., Kristjansson B. R., Armannsson H.,
Margretardottir E., Olafsdottir S. and Chiodini G. (2006)
CO2 emissions and heat flow through soil, fumaroles, and
steam heated mud pools at the Reykjanes geothermal area, SW
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Hreinsdo´ ttir S. and Bennett R. (2012) Volcano deformation
at active plate boundaries: deep magma accumulation at Hekla
volcano and plate boundary deformation in south Iceland. J.
Geophys. Res. Solid Earth 117, B11409.
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Surtsey volcano, Iceland 1964–1967. J. Volcanol. Geoth. Res. 8,
191–198.
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of Na–K–Mg–Ca geoindicators. Geochim. Cosmochim. Acta 52,
2749–2765.
Gislason S. R. and Eugster H. P. (1987) Meteoric water-basalt
interactions. II: A field study in N.E Iceland. Geochim.
Cosmochim. Acta 51, 2841–2855.
Gislason S. R. and Oelkers E. (2003) Mechanism, rates, and
consequences of basaltic glass dissolution: II. An experimental
study of the dissolution rates of basaltic glass as a
function of pH and temperature. Geochim. Cosmochim. Acta
67, 3817–3832.
Gislason S. R., Andre´sdo´ ttir A., Sveinbjo¨rnsdo´ ttir A ´ ., Oskarsson
N., Thordarson T., Torssander P., Novaˆk M. and Zaˆk K.
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from Hekla, southern Iceland. Water–Rock Interact.
Rotterdam, Balkema 1, 477–481.
Granieri D., Chiodini G., Marzocchi W. and Avino R. (2003)
Continuous monitoring of CO2 soil diffuse degassing at
Phlegraean Fields (Italy): influence of environmental and
volcanic parameters. Earth Planet. Sci. Lett. 212, 167–179.
Gronvold K., Larsen G., Einarsson P., Thorarinsson S. and
Saemundsson K. (1983) The Hekla eruption 1980–1981. Bull.
Volcanologique 46, 349–363.
Gudmundsson A., Oskarsson N., Gronvold K., Saemundsson K.,
Sigurdsson O., Stefansson R., Gislason S. R., Einarsson P.,
Brandsdottir B., Larsen G., Johannesson H. and Thordarson T.
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238–246.
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the formation of hydrothermal ore deposits. Nature 370, 519–
527.
Helgeson H. C. (1968) Evaluation of irreversible reactions in
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