CO2 emissions and heat flow through soil, fumaroles, and steam heated mud pools at the Reykjanes geothermal area, SW Iceland
Author(s)
Language
English
Status
Published
Peer review journal
Yes
Journal
Pages (printed)
(1551–1569)
Date Issued
2006
Subjects
Abstract
Carbon dioxide emissions and heat flow through soil, steam vents and fractures, and steam heated mud pools were
determined in the Reykjanes geothermal area, SW Iceland. Soil diffuse degassing of CO2 was quantified by soil flux measurements
on a 600 m by 375 m rectangular grid using a portable closed chamber soil flux meter and the resulting data were
analyzed by both a graphical statistical method and sequential Gaussian simulations. The soil temperature was measured
in each node of the grid and used to evaluate the heat flow. The heat flow data were also analyzed by sequential Gaussian
simulations. Heat flow from steam vents and fractures was determined by quantifying the amount of steam emitted from
the vents by direct measurements of steam flow rate. The heat loss from the steam heated mud pools was determined by
quantifying the rate of heat loss from the pools by evaporation, convection, and radiation. The steam flow rate into the
pools was calculated from the observed heat loss from the pools, assuming that steam flow was the only mechanism of heat
transport into the pool. The CO2 emissions from the steam vents and mud pools were determined by multiplying the steam
flow rate from the respective sources by the representative CO2 concentration of steam in the Reykjanes area. The observed
rates of CO2 emissions through soil, steam vents, and steam heated mud pools amounted to 13.5 ± 1.7, 0.23 ± 0.05, and
0.13 ± 0.03 tons per day, respectively. The heat flow through soil, steam vents, and mud pools was 16.9 ± 1.4, 2.2 ± 0.4,
and 1.2 ± 0.1 MW, respectively. Heat loss from the geothermal reservoir, inferred from the CO2 emissions through the soil
amounts to 130 ± 16 MW of thermal energy. The discrepancy between the observed heat loss and the heat loss inferred
from the CO2 emissions is attributed to steam condensation in the subsurface due to interactions with cold ground water.
These results demonstrate that soil diffuse degassing can be a more reliable proxy for heat loss from geothermal systems
than soil temperatures. The soil diffuse degassing at Reykjanes appears to be strongly controlled by the local tectonics. The
observed diffuse degassing defines 3–5 elongated N–S trending zones (000–020 ). The orientation of the diffuse degassing
structures at Reykjanes is consistent with reported trends of right lateral strike slip faults in the area. The natural CO2
emissions from Reykjanes under the current low-production conditions are about 16% of the expected emissions from
a 100 MWe power plant, which has recently been commissioned at Reykjanes.
determined in the Reykjanes geothermal area, SW Iceland. Soil diffuse degassing of CO2 was quantified by soil flux measurements
on a 600 m by 375 m rectangular grid using a portable closed chamber soil flux meter and the resulting data were
analyzed by both a graphical statistical method and sequential Gaussian simulations. The soil temperature was measured
in each node of the grid and used to evaluate the heat flow. The heat flow data were also analyzed by sequential Gaussian
simulations. Heat flow from steam vents and fractures was determined by quantifying the amount of steam emitted from
the vents by direct measurements of steam flow rate. The heat loss from the steam heated mud pools was determined by
quantifying the rate of heat loss from the pools by evaporation, convection, and radiation. The steam flow rate into the
pools was calculated from the observed heat loss from the pools, assuming that steam flow was the only mechanism of heat
transport into the pool. The CO2 emissions from the steam vents and mud pools were determined by multiplying the steam
flow rate from the respective sources by the representative CO2 concentration of steam in the Reykjanes area. The observed
rates of CO2 emissions through soil, steam vents, and steam heated mud pools amounted to 13.5 ± 1.7, 0.23 ± 0.05, and
0.13 ± 0.03 tons per day, respectively. The heat flow through soil, steam vents, and mud pools was 16.9 ± 1.4, 2.2 ± 0.4,
and 1.2 ± 0.1 MW, respectively. Heat loss from the geothermal reservoir, inferred from the CO2 emissions through the soil
amounts to 130 ± 16 MW of thermal energy. The discrepancy between the observed heat loss and the heat loss inferred
from the CO2 emissions is attributed to steam condensation in the subsurface due to interactions with cold ground water.
These results demonstrate that soil diffuse degassing can be a more reliable proxy for heat loss from geothermal systems
than soil temperatures. The soil diffuse degassing at Reykjanes appears to be strongly controlled by the local tectonics. The
observed diffuse degassing defines 3–5 elongated N–S trending zones (000–020 ). The orientation of the diffuse degassing
structures at Reykjanes is consistent with reported trends of right lateral strike slip faults in the area. The natural CO2
emissions from Reykjanes under the current low-production conditions are about 16% of the expected emissions from
a 100 MWe power plant, which has recently been commissioned at Reykjanes.
References
´
gu´stsdo´ ttir, A.M., Brantley, S.L., 1994. Volatile fluxes integrated
over 4 decades at Grı´msvo¨tn volcano, Iceland. J.
Geophys. Res. 99 B5, 9505–9522.
Aiuppa, A., Caleca, A., Federico, C., Gurrieri, S., Valenza, M.,
2004. Diffuse degassing of carbon dioxide at Somma–Vesuvius
volcanic complex (Southern Italy) and its relation with
regional tectonics. J. Volcanol. Geotherm. Res. 133, 55–79.
Allard, P., Carbonelle, J., Dajlevic, D., Le Bronec, J., Morel, P.,
Robe, M.C., Maurenas, J.M., Faivre-Pierret, R., Martin, D.,
Sabroux, J.C., Zettwoog, P., 1991. Eruptive and diffuse
emissions of CO2 from Mount Etna. Nature 351, 387–391.
A ´
rmannsson, H., 1991 Geothermal energy and the environment.
In: Geoscience Society of Iceland. Conf. Geology and
Environmental Matters. Prog. and Abstr., pp. 16–17 (In
Icelandic).
A ´
rmannsson, H., Benjamı´nsson, J., Jeffrey, A., 1989. Gas
changes in the Krafla geothermal system, Iceland. Chem.
Geol. 76, 175–196.
A ´
rmannsson, H., Fridriksson, Th., Kristja´nsson, B.R., 2005. CO2
emissions from geothermal power plants and natural geothermal
activity in Iceland. Geothermics 34, 286–296.
Arno´rsson, S., 1991. Estimate of natural CO2 and H2S flow from
Icelandic high-temperature geothermal areas. In: Conf. Geology
and Environmental Matters. Prog. and Abstr., pp. 18–19
(In Icelandic).
Arno´rsson, S., Gı´slason, S.R., 1994. CO2 from magmatic sources
in Iceland. Miner. Mag. 58A, 27–28.
Arno´rsson, S., Gunnlaugsson, E., 1985. New gas geothermometers
for geothermal exploration – calibration and application.
Geochim. Cosmochim. Acta 49, 1307–1325.
Arno´rsson, S., Fridriksson, Th., Gunnarsson, I., 1998. Gas
chemistry of the Krafla Geothermal field, Iceland. In: Arehart
G.B., Hulston J.R. (Eds)., Proceedings of the 9th International
Symposium Water–Rock Interaction, WRI-9, pp. 613–
616.
Arno´rsson, S, Sigurdsson, S., Svavarsson, H., 1982. The chemistry
of geothermal waters in Iceland 1. Calculation of
aqueous speciation from 0 C to 370 C. Geochim. Cosmochim.
Acta 46, 1513–1532.
Ba´rdarson, G.G., 1931. The warm sea water pool at Reykjanes.
Na´ttu´rufreadingurinn 1, 78–80 (in Icelandic).
Baubron, J.C., Allard, P., Toutain, J.P., 1991. Diffuse volcanic
emissions of carbon dioxide from Vulcano Island, Italy.
Nature 344, 51–53.
Bjo¨rnsson, S., O´ lafsdo´ ttir B., To´masson J., Jo´nsson J., Arno´ rsson,
S., Sigurmundsson, S.G., 1971. Reykjanes. Final report
on investigations in the geothermal area. National Energy
Authority report (in Icelandic).
Bjo¨rnsson, G., O´ lafsson, M., Jo´nasson, H., Magnu´sson, Th. M.,
2004. Production studies of wells RN-9, RN-10, RN-11 and
RN-12 in Reykjanes (2002–2004). Iceland GeoSurvey report
I´
SOR-2004/019 (in Icelandic).
Brombach, T., Hunziker, J.C, Chiodini, G., Cardellini, C.,
Marini, L., 2001. Soil diffuse degassing and thermal energy
fluxes from the southern Lakki plain, Nisyros (Greece).
Geophys. Res. Lett. 28, 67–72.
Cardellini, C., Chiodini, G., Frondini, F., 2003. Application of
stochastic simulations to CO2 flux from soil: mapping and
quantifying gas release. J. Geophys. Res. 108, 2425.
doi:10.1029/2002JB002165.
Chiodini, G., Cioni, R., Guidi, M., Raco, B., Marini, L., 1998.
Soil CO2 flux measurements in volcanic and geothermal areas.
Appl. Geochem. 13, 543–552.
Chiodini, G., Frondini, F., Cardellini, C., Granieri, D., Marini,
L., Ventura, G., 2001. CO2 degassing and energy release at
Solfatara volcano, Campi Flegrei, Italy. J. Geophys. Res. 106
B8, 16213–16221.
Chiodini, G., Frondini, F., Raco, B., 1996. Diffuse emission of
CO2 from the Fossa crater, Vulcano Island (Italy). Bull. Volc.
58, 41–50.
Chiodini, G., Granieri, D., Avino, R., Caliro, S., Costa, A.,
Werner, C., submitted for publication. Carbon dioxide diffuse
degassing: implications on the energetic state of volcanic/
hydrothermal systems. J. Geophys. Res.
Clifton, A.E., Schlische, R.W., 2003. Fracture populations on the
Reykjanes Peninsula, Iceland: comparison with experimental
clay models of oblique rifting. J. Geophys. Res. 108 B2, 2074.
D’Amore, F., Truesdell, A.H., 1985. Calculations of geothermal
reservoir temperatures and steam fractions from gas compositions.
GRC Trans. 9, 305–310.
David, M., 1977. Geostatistical Ore Reserve Estimations. Elsevier,
New York.
Dawson, G.B., 1964. The nature and assessment of heat flow
from hydrothermal areas. N.Z. J. Geol. Geophys. 7, 155–171.
Deutsch, C.V., Journel, A.G., 1998. GSLIB: Geostatistical
Software Library and Users Guide. Oxford University Press,
New York.
Elmarsdo´ ttir, A ´ ., Ingimarsdo´ ttir, M., Hansen, I´., O´ lafsson, J.S.,
Magnu´sson, S., 2003. Vegetation and invertebrates in six
high-temperature geothermal areas in Iceland. Icelandic
Museum of Natural History and University of Iceland
Institute of Biology report (in Icelandic).
Favara, R., Giammanco, S., Inguaggiato, S., Pecoraino, G.,
2001. Preliminary estimate of CO2 output from Pantelleria
Island volcano (Sicily, Italy): evidence of active mantle
degassing. Appl. Geochem. 16, 883–894.
Franz, G., Libscher, A., 2004. Physical and chemical properties
of the epidote minerals – an introduction. In: Libscher, A.,
Franz, G. (Eds.), Reviews in Mineralogy and Geochemistry,
vol. 56. Mineralogical Society of America and Geochemical
Society, pp. 1–80.
Franzson H., 2004. Reykjanes high-temperature geothermal
system. Geological and geothermal model. Iceland GeoSurvey
report I´SOR-2004/012 (in Icelandic).
Franzson H., Thordarson S., Bjo¨rnsson G., Gudlaugsson S.Th.,
Richter B., Fridleifsson G.O´ ., Tho´rhallsson S., 2002. Reykjanes
high-temperature field SW-Iceland. Geology and hydrothermal
alteration of well RN-10. In: Proceedings of the 27th
Workshop Geothermal Reservoir Engineering, Stanford
University.
Gerlach, T.M., McGee, K.A., Elias, T., Sutton, A.J., Doukas,
M.P., 2002. Carbon dioxide emission rate of Kilauea
Volcano: implications for primary magma and the summit
reservoir. J. Geophys. Res. 107 B9, 2189.
Gı´slason, S.R., 2000. Carbon dioxide from Eyjafjallajo¨ kull and
chemical composition of spring water and river water in the
Eyjafjalljo¨kull – My´rdalsjo¨kull region. Science Institute,
University of Iceland, Report RH-06-2000.
Granieri, D., Chiodini, G., Marzocchi, W., Avino, R., 2003.
Continuous monitoring of CO2 soil diffuse degassing at
Phlegraean Fields (Italy): influence of environmental and
volcanic parameters. Earth Plan. Sci. Lett. 212, 167–179.
Gudmundsdo´ ttir, A.L., 1988. Natural heat flow through surface
in geothermal areas in the Nesjavellir area. University of
Iceland 4th year honors thesis.
Herna´ndez, P.A., Notsu, K., Salazar, J.M., Mori, T., Natale, G.,
Okada, H., Virgili, G., Shimoike, Y., Sato, M., Pe´rez, N.M.,
2001a. Carbon dioxide degassing by advective flow from Usu
volcano, Japan. Science 292, 83–86.
Herna´ndez, P.A., Perez, N.M., Salazar, J.M., Nakai, S., Notsu,
K., Wakita, H., 1998. Diffuse emissions of carbon dioxide,
methane, and helium-3 from Teide volcano, Tenerife, Canary
Islands. Geophys. Res. Lett. 25, 3311–3314.
Herna´ndez, P.A., Salazar, J.M., Shimoike, Y., Mori, T., Notsu,
K., Pe´rez, N.M., 2001b. Diffuse emissios of CO2 from
Miyakejima volcano, Japan. Chem. Geol. 177, 175–185.
Jakobsson, S.P., Jo´nsson, J., Shido, F., 1978. Petrology of the
Western Reykjanes Peninsula, Iceland. J. Petrol. 19, 669–705.
Johnson, J.W., Oelkers, E.H., Helgeson, H.C., 1992. SUPCRT92
– a software package for calculating the standard molal
thermodynamic properties of minerals, gases, aqueous species,
and reactions from 1 bar to 5000 bar and 0 C to
1000 C. Comput. Geosci. 18, 899–947.
Jo´nsson, J., 1968. Changes in the geothermal area at Reykjanes in
1967. National Energy Authority Report 10421 OST 5 (in
Icelandic).
Jo´nsson, J., 1983. Historic eruptions on the Reykjanes Peninsula.
Na´ttu´rufraedingurinn 52, 127–139 (in Icelandic).
Karlsdo´ ttir, R., 2005. TEM-measurements at Reykjanes 2004.
Iceland GeoSurvey Report I´SOR-2005/002 (in Icelandic).
Kerrick, D.M., 2001. Present and past nonanthropogenic CO2
degassing from the solid Earth. Rev. Geophys. 39, 564–
585.
Lewicki, J.L., Connor, C., St-Amand, K., Stix, J., Spinner, W.,
2003. Self-potential, soil CO2 flux and temperature on
Masaya volcano, Nicaragua. Geophys. Res. Lett. 30, 1817.
Lonker, S.W., Franzson, H., Kristmannsdo´ ttir, H., 1993. Mineral–
fluid interactions in the Reykjanes and Svartsengi
geothermal systems, Iceland. Am. J. Sci. 293, 605–670.
Marty, B., Tolstikhin, I.N., 1998. CO2 fluxes from mid-ocean
ridges, arcs and plumes. Chem. Geol. 145, 233–248.
Mo¨ rner, N.A., Etiope, G., 2002. Carbon degassing of the
lithosphere. Global Planet. Change 33, 185–203.
Nehring, N.L., D’Amore, F., 1984. Gas chemistry of the Cerro
Prieto, Mexico. Geothermics 13, 75–89.
Notsu, K., Sugiyama, K., Hosoe, M., Uemura, A., Shimoike, Y.,
Tsunomori, F., Sumino, H., Yamamoto, J., Mori, T.,
He´rnandez, P.A., 2005. Diffuse CO2 efflux from Iwojima
volcano, Izu-Ogasawara arc, Japan. J. Volc. Geoth. Res. 139,
147–161.
O´
skarsson, N., 1996. Carbon dioxide from large volcanic
eruptions. Short term effects. In: Biological Society of Iceland.
The carbon budget of Iceland Conference, Reykjavı´k 22–23
November 1966. Prog. and Abstr., p. 17 (In Icelandic).
Pa´lmason, G., Saemundsson, K., 1974. Iceland in relation
to Mid-Atlantic Ridge. Ann. Rev. Earth Plan. Sci. 2,
25–50.
Pa´lmason, G., Johnsen, G.V., Torfason, H., Sæmundsson, K,
Ragnars, K, Haraldsson, G.I., Halldo´rsson, G.K., 1985.
Assessment of geothermal energy in Iceland. Orkustofnun
OS-85076/JHD-10.
Saemundsson, K., Jo´hannesson, H., 2004. Geothermal map of
Iceland. Iceland GeoSurvey and Icelandic Energy Authority.
Saemundsson, K., Tho´rhallsson, S., Bjo¨rnsson, G., Karlsdo´ ttir,
R., Franzson, H., 2004. Siting of drillholes RN-17 to RN-21
at Reykjanes. Iceland GeoSurvey report I´ SOR-04088 (in
Icelandic).
Salazar, J.M.L., Herna´ndes, P.A., Pe´rez, N.M., Melia´n, G.,
A ´
lvarez, J., Segura, F., Notsu, K., 2001. Diffuse emission of
carbon dioxide from Cerro Negro volcano, Nicaragua,
Central America. Geophys. Res. Lett. 28, 4275–4278.
Sapper, K., 1908. On some Icelandic volcanic fissures and crater
rows. Neu. Jahrb. Min. Geol. Pala¨ontol., 26 (in German).
Schmidt, E., Grigull, U., 1979. Properties of Water and Steam in
SI-units: 0–800 C, 0–1000 bar. Springer-Verlag, Berlin Heidelberg,
R. Oldebourg, Mu¨nchen.
Sigurgeirsson, M.A´ ., 1995. The younger Stampar eruption at
Reykjanes. Na´ttu´rufraedingurinn 64, 211–230 (in Icelandic).
Sigurgeirsson, M.A´ ., 2004. A chapter in the eruption history of
Reykjanes: eruption episode two thousand years ago.
Na´ttu´rufraedingurinn 72, 21–28 (in Icelandic).
Sinclair, A.J., 1974. Selection of threshold values in geochemical
data using probability graphs. J. Geochem. Explor. 3, 129–
149.
Sorey, M.L., Colvard, E.M., 1994. Measurements of heat and
mass flow from thermal areas in Lassen Volcanic National
Park, California, 1984–1993. U.S.G.S. Water Resour. Invest.
Rep., 94–4180-A.
Stefa´nsson, A., Arno´ rsson, S., 2002. Gas pressures and redox
reactions in geothermal fluids in Iceland. Chem. Geol. 190,
251–271.
Sutton, O.G., 1953. Micrometeorology. McGraw-Hill, New
York.
Sveinbjo¨rnsdo´ ttir, A.E., 1991. composition of geothermal minerals
from saline and dilute fluids – Krafla and Reykjanes,
Iceland. Lithos 27, 301–315.
Thorkelsson, Th., 1928. On thermal activity in Reykjanes. Rit
Vı´sindafe´lags I´slendinga, 3.
Werner, C., Brantley, S., 2003. CO2 emissions from the Yellowstone
volcanic system. Geochem. Geophys. Geosyst. 4, 1061.
Werner, C., Brantley, S.L., Boomer, K., 2000. CO2 emissions
related to the Yellowstone volcanic system 2. Statistical
sampling, total degassing, and transport mechnanisms. J.
Geophys. Res. 105, 10831–10846.
Werner, C., Christenson, B.J., Scott, K., Britten, K., Kilgour, G.,
2004. Monitoring CO2 emissions at White Island volcano,
New Zealand: evidence for total decrease in magmatic mass
and heat output. In: Wanty R.B., Seal II R.R. (Eds.),
Proceedings of the 11th International Symposium Water–
Rock Interaction, WRI-11, pp. 223–226.
Wolfe, C.J., Bjarnason, I.Th., VanDecar, J.C., Solomon, S.C.,
1997. Seismic structure of the Iceland mantle plume. Nature
385, 245–247.
Zhao, Ping, A ´ rmannsson, H., 1996. Gas geothermometry in
selected Icelandic geothermal fields with comparative examples
from Kenya. Geothermics 25, 307–347.
Th. Fridriksson et al. / Applied Geochemistry 21 (2006) 1551–1569 1569
gu´stsdo´ ttir, A.M., Brantley, S.L., 1994. Volatile fluxes integrated
over 4 decades at Grı´msvo¨tn volcano, Iceland. J.
Geophys. Res. 99 B5, 9505–9522.
Aiuppa, A., Caleca, A., Federico, C., Gurrieri, S., Valenza, M.,
2004. Diffuse degassing of carbon dioxide at Somma–Vesuvius
volcanic complex (Southern Italy) and its relation with
regional tectonics. J. Volcanol. Geotherm. Res. 133, 55–79.
Allard, P., Carbonelle, J., Dajlevic, D., Le Bronec, J., Morel, P.,
Robe, M.C., Maurenas, J.M., Faivre-Pierret, R., Martin, D.,
Sabroux, J.C., Zettwoog, P., 1991. Eruptive and diffuse
emissions of CO2 from Mount Etna. Nature 351, 387–391.
A ´
rmannsson, H., 1991 Geothermal energy and the environment.
In: Geoscience Society of Iceland. Conf. Geology and
Environmental Matters. Prog. and Abstr., pp. 16–17 (In
Icelandic).
A ´
rmannsson, H., Benjamı´nsson, J., Jeffrey, A., 1989. Gas
changes in the Krafla geothermal system, Iceland. Chem.
Geol. 76, 175–196.
A ´
rmannsson, H., Fridriksson, Th., Kristja´nsson, B.R., 2005. CO2
emissions from geothermal power plants and natural geothermal
activity in Iceland. Geothermics 34, 286–296.
Arno´rsson, S., 1991. Estimate of natural CO2 and H2S flow from
Icelandic high-temperature geothermal areas. In: Conf. Geology
and Environmental Matters. Prog. and Abstr., pp. 18–19
(In Icelandic).
Arno´rsson, S., Gı´slason, S.R., 1994. CO2 from magmatic sources
in Iceland. Miner. Mag. 58A, 27–28.
Arno´rsson, S., Gunnlaugsson, E., 1985. New gas geothermometers
for geothermal exploration – calibration and application.
Geochim. Cosmochim. Acta 49, 1307–1325.
Arno´rsson, S., Fridriksson, Th., Gunnarsson, I., 1998. Gas
chemistry of the Krafla Geothermal field, Iceland. In: Arehart
G.B., Hulston J.R. (Eds)., Proceedings of the 9th International
Symposium Water–Rock Interaction, WRI-9, pp. 613–
616.
Arno´rsson, S, Sigurdsson, S., Svavarsson, H., 1982. The chemistry
of geothermal waters in Iceland 1. Calculation of
aqueous speciation from 0 C to 370 C. Geochim. Cosmochim.
Acta 46, 1513–1532.
Ba´rdarson, G.G., 1931. The warm sea water pool at Reykjanes.
Na´ttu´rufreadingurinn 1, 78–80 (in Icelandic).
Baubron, J.C., Allard, P., Toutain, J.P., 1991. Diffuse volcanic
emissions of carbon dioxide from Vulcano Island, Italy.
Nature 344, 51–53.
Bjo¨rnsson, S., O´ lafsdo´ ttir B., To´masson J., Jo´nsson J., Arno´ rsson,
S., Sigurmundsson, S.G., 1971. Reykjanes. Final report
on investigations in the geothermal area. National Energy
Authority report (in Icelandic).
Bjo¨rnsson, G., O´ lafsson, M., Jo´nasson, H., Magnu´sson, Th. M.,
2004. Production studies of wells RN-9, RN-10, RN-11 and
RN-12 in Reykjanes (2002–2004). Iceland GeoSurvey report
I´
SOR-2004/019 (in Icelandic).
Brombach, T., Hunziker, J.C, Chiodini, G., Cardellini, C.,
Marini, L., 2001. Soil diffuse degassing and thermal energy
fluxes from the southern Lakki plain, Nisyros (Greece).
Geophys. Res. Lett. 28, 67–72.
Cardellini, C., Chiodini, G., Frondini, F., 2003. Application of
stochastic simulations to CO2 flux from soil: mapping and
quantifying gas release. J. Geophys. Res. 108, 2425.
doi:10.1029/2002JB002165.
Chiodini, G., Cioni, R., Guidi, M., Raco, B., Marini, L., 1998.
Soil CO2 flux measurements in volcanic and geothermal areas.
Appl. Geochem. 13, 543–552.
Chiodini, G., Frondini, F., Cardellini, C., Granieri, D., Marini,
L., Ventura, G., 2001. CO2 degassing and energy release at
Solfatara volcano, Campi Flegrei, Italy. J. Geophys. Res. 106
B8, 16213–16221.
Chiodini, G., Frondini, F., Raco, B., 1996. Diffuse emission of
CO2 from the Fossa crater, Vulcano Island (Italy). Bull. Volc.
58, 41–50.
Chiodini, G., Granieri, D., Avino, R., Caliro, S., Costa, A.,
Werner, C., submitted for publication. Carbon dioxide diffuse
degassing: implications on the energetic state of volcanic/
hydrothermal systems. J. Geophys. Res.
Clifton, A.E., Schlische, R.W., 2003. Fracture populations on the
Reykjanes Peninsula, Iceland: comparison with experimental
clay models of oblique rifting. J. Geophys. Res. 108 B2, 2074.
D’Amore, F., Truesdell, A.H., 1985. Calculations of geothermal
reservoir temperatures and steam fractions from gas compositions.
GRC Trans. 9, 305–310.
David, M., 1977. Geostatistical Ore Reserve Estimations. Elsevier,
New York.
Dawson, G.B., 1964. The nature and assessment of heat flow
from hydrothermal areas. N.Z. J. Geol. Geophys. 7, 155–171.
Deutsch, C.V., Journel, A.G., 1998. GSLIB: Geostatistical
Software Library and Users Guide. Oxford University Press,
New York.
Elmarsdo´ ttir, A ´ ., Ingimarsdo´ ttir, M., Hansen, I´., O´ lafsson, J.S.,
Magnu´sson, S., 2003. Vegetation and invertebrates in six
high-temperature geothermal areas in Iceland. Icelandic
Museum of Natural History and University of Iceland
Institute of Biology report (in Icelandic).
Favara, R., Giammanco, S., Inguaggiato, S., Pecoraino, G.,
2001. Preliminary estimate of CO2 output from Pantelleria
Island volcano (Sicily, Italy): evidence of active mantle
degassing. Appl. Geochem. 16, 883–894.
Franz, G., Libscher, A., 2004. Physical and chemical properties
of the epidote minerals – an introduction. In: Libscher, A.,
Franz, G. (Eds.), Reviews in Mineralogy and Geochemistry,
vol. 56. Mineralogical Society of America and Geochemical
Society, pp. 1–80.
Franzson H., 2004. Reykjanes high-temperature geothermal
system. Geological and geothermal model. Iceland GeoSurvey
report I´SOR-2004/012 (in Icelandic).
Franzson H., Thordarson S., Bjo¨rnsson G., Gudlaugsson S.Th.,
Richter B., Fridleifsson G.O´ ., Tho´rhallsson S., 2002. Reykjanes
high-temperature field SW-Iceland. Geology and hydrothermal
alteration of well RN-10. In: Proceedings of the 27th
Workshop Geothermal Reservoir Engineering, Stanford
University.
Gerlach, T.M., McGee, K.A., Elias, T., Sutton, A.J., Doukas,
M.P., 2002. Carbon dioxide emission rate of Kilauea
Volcano: implications for primary magma and the summit
reservoir. J. Geophys. Res. 107 B9, 2189.
Gı´slason, S.R., 2000. Carbon dioxide from Eyjafjallajo¨ kull and
chemical composition of spring water and river water in the
Eyjafjalljo¨kull – My´rdalsjo¨kull region. Science Institute,
University of Iceland, Report RH-06-2000.
Granieri, D., Chiodini, G., Marzocchi, W., Avino, R., 2003.
Continuous monitoring of CO2 soil diffuse degassing at
Phlegraean Fields (Italy): influence of environmental and
volcanic parameters. Earth Plan. Sci. Lett. 212, 167–179.
Gudmundsdo´ ttir, A.L., 1988. Natural heat flow through surface
in geothermal areas in the Nesjavellir area. University of
Iceland 4th year honors thesis.
Herna´ndez, P.A., Notsu, K., Salazar, J.M., Mori, T., Natale, G.,
Okada, H., Virgili, G., Shimoike, Y., Sato, M., Pe´rez, N.M.,
2001a. Carbon dioxide degassing by advective flow from Usu
volcano, Japan. Science 292, 83–86.
Herna´ndez, P.A., Perez, N.M., Salazar, J.M., Nakai, S., Notsu,
K., Wakita, H., 1998. Diffuse emissions of carbon dioxide,
methane, and helium-3 from Teide volcano, Tenerife, Canary
Islands. Geophys. Res. Lett. 25, 3311–3314.
Herna´ndez, P.A., Salazar, J.M., Shimoike, Y., Mori, T., Notsu,
K., Pe´rez, N.M., 2001b. Diffuse emissios of CO2 from
Miyakejima volcano, Japan. Chem. Geol. 177, 175–185.
Jakobsson, S.P., Jo´nsson, J., Shido, F., 1978. Petrology of the
Western Reykjanes Peninsula, Iceland. J. Petrol. 19, 669–705.
Johnson, J.W., Oelkers, E.H., Helgeson, H.C., 1992. SUPCRT92
– a software package for calculating the standard molal
thermodynamic properties of minerals, gases, aqueous species,
and reactions from 1 bar to 5000 bar and 0 C to
1000 C. Comput. Geosci. 18, 899–947.
Jo´nsson, J., 1968. Changes in the geothermal area at Reykjanes in
1967. National Energy Authority Report 10421 OST 5 (in
Icelandic).
Jo´nsson, J., 1983. Historic eruptions on the Reykjanes Peninsula.
Na´ttu´rufraedingurinn 52, 127–139 (in Icelandic).
Karlsdo´ ttir, R., 2005. TEM-measurements at Reykjanes 2004.
Iceland GeoSurvey Report I´SOR-2005/002 (in Icelandic).
Kerrick, D.M., 2001. Present and past nonanthropogenic CO2
degassing from the solid Earth. Rev. Geophys. 39, 564–
585.
Lewicki, J.L., Connor, C., St-Amand, K., Stix, J., Spinner, W.,
2003. Self-potential, soil CO2 flux and temperature on
Masaya volcano, Nicaragua. Geophys. Res. Lett. 30, 1817.
Lonker, S.W., Franzson, H., Kristmannsdo´ ttir, H., 1993. Mineral–
fluid interactions in the Reykjanes and Svartsengi
geothermal systems, Iceland. Am. J. Sci. 293, 605–670.
Marty, B., Tolstikhin, I.N., 1998. CO2 fluxes from mid-ocean
ridges, arcs and plumes. Chem. Geol. 145, 233–248.
Mo¨ rner, N.A., Etiope, G., 2002. Carbon degassing of the
lithosphere. Global Planet. Change 33, 185–203.
Nehring, N.L., D’Amore, F., 1984. Gas chemistry of the Cerro
Prieto, Mexico. Geothermics 13, 75–89.
Notsu, K., Sugiyama, K., Hosoe, M., Uemura, A., Shimoike, Y.,
Tsunomori, F., Sumino, H., Yamamoto, J., Mori, T.,
He´rnandez, P.A., 2005. Diffuse CO2 efflux from Iwojima
volcano, Izu-Ogasawara arc, Japan. J. Volc. Geoth. Res. 139,
147–161.
O´
skarsson, N., 1996. Carbon dioxide from large volcanic
eruptions. Short term effects. In: Biological Society of Iceland.
The carbon budget of Iceland Conference, Reykjavı´k 22–23
November 1966. Prog. and Abstr., p. 17 (In Icelandic).
Pa´lmason, G., Saemundsson, K., 1974. Iceland in relation
to Mid-Atlantic Ridge. Ann. Rev. Earth Plan. Sci. 2,
25–50.
Pa´lmason, G., Johnsen, G.V., Torfason, H., Sæmundsson, K,
Ragnars, K, Haraldsson, G.I., Halldo´rsson, G.K., 1985.
Assessment of geothermal energy in Iceland. Orkustofnun
OS-85076/JHD-10.
Saemundsson, K., Jo´hannesson, H., 2004. Geothermal map of
Iceland. Iceland GeoSurvey and Icelandic Energy Authority.
Saemundsson, K., Tho´rhallsson, S., Bjo¨rnsson, G., Karlsdo´ ttir,
R., Franzson, H., 2004. Siting of drillholes RN-17 to RN-21
at Reykjanes. Iceland GeoSurvey report I´ SOR-04088 (in
Icelandic).
Salazar, J.M.L., Herna´ndes, P.A., Pe´rez, N.M., Melia´n, G.,
A ´
lvarez, J., Segura, F., Notsu, K., 2001. Diffuse emission of
carbon dioxide from Cerro Negro volcano, Nicaragua,
Central America. Geophys. Res. Lett. 28, 4275–4278.
Sapper, K., 1908. On some Icelandic volcanic fissures and crater
rows. Neu. Jahrb. Min. Geol. Pala¨ontol., 26 (in German).
Schmidt, E., Grigull, U., 1979. Properties of Water and Steam in
SI-units: 0–800 C, 0–1000 bar. Springer-Verlag, Berlin Heidelberg,
R. Oldebourg, Mu¨nchen.
Sigurgeirsson, M.A´ ., 1995. The younger Stampar eruption at
Reykjanes. Na´ttu´rufraedingurinn 64, 211–230 (in Icelandic).
Sigurgeirsson, M.A´ ., 2004. A chapter in the eruption history of
Reykjanes: eruption episode two thousand years ago.
Na´ttu´rufraedingurinn 72, 21–28 (in Icelandic).
Sinclair, A.J., 1974. Selection of threshold values in geochemical
data using probability graphs. J. Geochem. Explor. 3, 129–
149.
Sorey, M.L., Colvard, E.M., 1994. Measurements of heat and
mass flow from thermal areas in Lassen Volcanic National
Park, California, 1984–1993. U.S.G.S. Water Resour. Invest.
Rep., 94–4180-A.
Stefa´nsson, A., Arno´ rsson, S., 2002. Gas pressures and redox
reactions in geothermal fluids in Iceland. Chem. Geol. 190,
251–271.
Sutton, O.G., 1953. Micrometeorology. McGraw-Hill, New
York.
Sveinbjo¨rnsdo´ ttir, A.E., 1991. composition of geothermal minerals
from saline and dilute fluids – Krafla and Reykjanes,
Iceland. Lithos 27, 301–315.
Thorkelsson, Th., 1928. On thermal activity in Reykjanes. Rit
Vı´sindafe´lags I´slendinga, 3.
Werner, C., Brantley, S., 2003. CO2 emissions from the Yellowstone
volcanic system. Geochem. Geophys. Geosyst. 4, 1061.
Werner, C., Brantley, S.L., Boomer, K., 2000. CO2 emissions
related to the Yellowstone volcanic system 2. Statistical
sampling, total degassing, and transport mechnanisms. J.
Geophys. Res. 105, 10831–10846.
Werner, C., Christenson, B.J., Scott, K., Britten, K., Kilgour, G.,
2004. Monitoring CO2 emissions at White Island volcano,
New Zealand: evidence for total decrease in magmatic mass
and heat output. In: Wanty R.B., Seal II R.R. (Eds.),
Proceedings of the 11th International Symposium Water–
Rock Interaction, WRI-11, pp. 223–226.
Wolfe, C.J., Bjarnason, I.Th., VanDecar, J.C., Solomon, S.C.,
1997. Seismic structure of the Iceland mantle plume. Nature
385, 245–247.
Zhao, Ping, A ´ rmannsson, H., 1996. Gas geothermometry in
selected Icelandic geothermal fields with comparative examples
from Kenya. Geothermics 25, 307–347.
Th. Fridriksson et al. / Applied Geochemistry 21 (2006) 1551–1569 1569
Type
article
File(s)![Thumbnail Image]()
Loading...
Name
1456.pdf
Size
3.18 MB
Format
Adobe PDF
Checksum (MD5)
a9f34c7dd0a6526b5b7c793810d74554
