Diffuse emission of CO2 and convective heat release at Nisyros caldera (Greece)

The diffuse emission of CO2 from the south east sector of Nisyros caldera (Lakki plain) has beenmeasured during
a detailed survey (~1400 soil CO2 flux measurements) performed in October 2018. The gas emissions are fed by
hydrothermal sources and, inminor part, by the soil biogenic activity whosemean CO2 flux (4 gm−2 d−1) is here
estimated for the first time. The total amount of hydrothermal CO2 reaches 92 ± 8 t/d, a value that is slightly
higher than that estimated with the same method between 1999 and 2001 (74 ± 7 t/d). The gas is emitted by
different diffuse degassing structures (DDSs), including volcanic-hydrothermal structures (craters and domes)
and NE-SWand NW-SE-trending tectonic lineaments.
Even if the total CO2 emission is not particularly high at Nisyros (close to themedian of CO2 emissionsmeasured
in volcanoesworldwide), the process is very energetic. The thermal energy associated with the shallow condensation
of the steam in the DDSs reaches ~60MW, whilewe estimate at 134–270MWthe total amount of thermal
energy involved in the convective rising of the deep geothermal liquids that transport the gas from the depth toward
the surface. This large flux of energy could dramatically increase during future earthquakes by addition of
heat and mass from a deep hydrothermal reservoir, potentially triggering hydrothermal explosions, as it happened
several times in the past few centuries.