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Bajo, Petra
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- PublicationRestrictedStalagmite carbon isotopes and dead carbon proportion (DCP) in a near-closed-system situation: An interplay between sulphuric and carbonic acid dissolution(2017-08-01)
; ; ; ; ; ; ; ; ; ; ; ; ;; ;In this study, the ‘dead carbon proportion’ (DCP) calculated from combined U-Th and radiocarbon analyses was used to explore the carbon isotope systematics in Corchia Cave (Italy) speleothems, using the example of stalagmite CC26 which grew during the last ∼12 ka. The DCP values in CC26 are among the highest ever recorded in a stalagmite, spanning the range 44.8–68.8%. A combination of almost closed-system conditions and sulphuric acid dissolution (SAD) are proposed as major drivers in producing such a high DCP with minor contribution from old organic matter from the deep vadose zone. The long-term decrease in both DCP and δ13C most likely reflects post-glacial soil recovery above the cave, with a progressive increase of soil CO2 contribution to the total dissolved inorganic carbon (DIC). Pronounced millennial-scale shifts in DCP and relatively small coeval but antipathetic changes in δ13C are modulated by the effects of hydrological variability on open and closed-system dissolution, SAD and prior calcite precipitation. Hence, the DCP in Corchia Cave speleothems represents an additional proxy for rainfall amount.49 2 - PublicationRestrictedPrecise microsampling of poorly laminated speleothems for U-series dating(2012)
; ; ; ; ; ; ; ; ; ; ; ; ;Drysdale, R. N.; Department of Resource Management and Geography, University of Melbourne, Parkville 3010, Victoria, Australia ;Bence, T. P.; School of Earth Sciences, University of Melbourne, Parkville 3010, Victoria, Australia ;Hellstrom, J. C.; School of Earth Sciences, University of Melbourne, Parkville 3010, Victoria, Australia ;Couchoud, I.; Department of Resource Management and Geography, University of Melbourne, Parkville 3010, Victoria, Australia ;Greig, A.; School of Earth Sciences, University of Melbourne, Parkville 3010, Victoria, Australia ;Bajo, P.; Department of Resource Management and Geography, University of Melbourne, Parkville 3010, Victoria, Australia ;Zanchetta, G.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Pisa, Pisa, Italia ;Isola, I.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Pisa, Pisa, Italia ;Spötl, C.; Institut für Geologie und Paläontologie, Universität Innsbruck, 6020 Innsbruck, Austria ;Baneschi, I.; Istituto di Georisorse e Geoscienza-CNR, Pisa 56100, Italy ;Regattieri, E.; Department of Earth Sciences, University of Pisa, Pisa 56100, Italy ;Woodhead, J. D.; School of Earth Sciences, University of Melbourne, Parkville 3010, Victoria, Australia; ; ; ; ; ; ; ; ; ; ; One of the principal reasons why speleothems are recognised as important palaeoclimate archives is their suitability for accurate and precise uranium-series (U-series) age determination. Sampling speleothem sections for U-series dating is straightforward in most cases because visible growth layers are preserved. However, this is not always the case, and here we describe a sampling strategy whereby growth layers are resolved from trace-element images produced by laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). We apply this method to a section of an Italian subaqueous speleothem (CD3) that lacks persistent visible growth layering. Trace-element imaging revealed growth layers that are strongly non-planar in their geometry owing to the speleothem's pronounced euhedral crystal terminations. The most prominent trace-element layers were first digitized as x, y vector contours. We then interpolated these in the growth-axis direction to generate a series of contour lines at ∼250-μm increments. The coordinates of these contours were used to guide the sampling via a computerised micromilling lathe. This produced a total of 22 samples for U-series dating by multi-collector ICP-MS. The dating results returned ages in correct stratigraphic order within error. Close inspection of the U-series data and the derived depth–age model suggests that the main source of model-age uncertainty is unrelated to the contour sampling but instead more associated with how closely spaced the model ages are in time, i.e. the model age density. Comparisons between stable oxygen and carbon isotope profiles derived from aliquots of the dating samples and two other stable isotope profiles from CD3 spanning the same time period compare very favourably. Taken together, this suggests that our trace-element contouring method provides a reliable means for extracting samples for dating (and other geochemical analyses), and can be applied to similar speleothems lacking visible growth layering.289 18 - PublicationOpen AccessSpeleothem U/Th age constraints for the Last Glacial conditions in the Apuan Alps, northwestern Italy(2019)
; ; ; ; ; ; ; ; ; ; ; ;; ; ; ; ; ; ;During the Quaternary several glaciations occurred in the mountain regions around the Mediterranean and, in recent years, new ages have better constrained their timing. However, this is not the case for the Apuan Alps, a high-rainfall mountain chain adjacent to the Mediterranean Sea. Here, in spite of the widespread evidence for glaciers, the complete lack of geochronological information hinders our understanding of glaciation history. In this paper, we utilize speleothem ages to better constrain the timing of these glacial features. We re-examine 293 uranium‑thorium ages from 19 speleothems collected in five caves at different elevations. After a period of very low growth between 160 and 132 ka, the analysed speleothems grew almost continuously to ~75 ka, this period was followed by intermittent growth with lower deposition rate and presence of hiatuses until ~12.5/12 ka. This is consistent with an ice coverage persisting over the Apuan Alps, inhibiting or interrupting the growth of speleothems via the limited availability of groundwater and the scarcity/absence of soils. This interval is much greater than the time interval that has previously been attributed to the existence of glaciers on the Apuan Alps, which has been assumed to be restricted to Marine Isotope Stage (MIS) 2. Instead, ice cover probably also appeared in the Apuan Alps during MIS 4. The phase of restarting of growth, which may implies the definitive or substantial glacier melts seem to predate the Holocene201 98 - PublicationOpen AccessThe 4.2 ka event in the central Mediterranean: new data from a Corchia speleothem (Apuan Alps, central Italy)(2019)
; ; ; ; ; ; ; ; ; ; ; ; ; ; ;; ; ; ; ; ;We present new data on the 4.2 ka event in the central Mediterranean from Corchia Cave (Tuscany, central Italy) stalagmite CC27. The stalagmite was analyzed for stable isotopes (delta13C and delta18O) and trace elements (Mg, U, P, Y), with all proxies showing a coherent phase of reduced cave recharge between ca. 4.5 and 4.1 ka BP. Based on the current climatological data on cyclogenesis, the reduction in cave recharge is considered to be associated with the weakening of the cyclone center located in the Gulf of Genoa in response to reduced advection of air masses from the Atlantic during winter. These conditions, which closely resemble a positive North Atlantic Oscillation (NAO) type of configuration, are associated with cooler and wetter summers with reduced sea warming, which reduced the western Mediterranean evaporation during autumn–early winter, further reducing precipitation.402 209 - PublicationOpen AccessBeyond one-way determinism: San Frediano's miracle and climate change in Central and Northern Italy in late antiquity(2021)
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ;; ; ; ; ; ; ;Integrating palaeoclimatological proxies and historical records, which is necessary to achieve a more complete understanding of climate impacts on past societies, is a challenging task, often leading to unsatisfactory and even contradictory conclusions. This has until recently been the case for Italy, the heart of the Roman Empire, during the transition between Antiquity and the Middle Ages. In this paper, we present new high-resolution speleothem data from the Apuan Alps (Central Italy). The data document a period of very wet conditions in the sixth c. AD, probably related to synoptic atmospheric conditions similar to a negative phase of the North Atlantic Oscillation. For this century, there also exist a significant number of historical records of extreme hydroclimatic events, previously discarded as anecdotal. We show that this varied evidence reflects the increased frequency of floods and extreme rainfall events in Central and Northern Italy at the time. Moreover, we also show that these unusual hydroclimatic conditions overlapped with the increased presence of "water miracles" in Italian hagiographical accounts and social imagination. The miracles, performed by local Church leaders, strengthened the already growing authority of holy bishops and monks in Italian society during the crucial centuries that followed the "Fall of the Roman Empire". Thus, the combination of natural and historical data allows us to show the degree to which the impact of climate variability on historical societies is determined not by the nature of the climatic phenomena per se, but by the culture and the structure of the society that experienced it.147 11 - PublicationRestrictedA MIS 9/MIS 8 speleothem record of hydrological variability from Macedonia (F.Y.R.O.M.)(2018)
; ; ; ; ; ; ; ; ; ; ;; ; ; ; ; ; ; ;The period corresponding to Marine Isotope Stages 9 (MIS 9) offers the opportunity to study orbital and sub-orbital scale climate variability under boundary conditions different from those of better studied intervals such as the Holocene and the Last Interglacial. Yet, it is poorly represented in independently-dated continental archives around the Mediterranean Region. Here, we present a speleothem stable isotope record (δ18O and δ13C) from the Former Yugoslavian Republic of Macedonia (F.Y.R.O.M., southern Balkans), which consists of two periods of growth broadly covering the ca. 332 to 292 ka and the ca. 264 to 248 ka intervals (MIS 9e-b and late MIS 8). We interpret the speleothem δ18O as mostly related to regional hydrology, with variations that can be interpreted as due to changes in rainfall amount, with higher/lower values associated to drier/wetter condition. This interpretation is corroborated by a change in mineralogical composition between aragonite and calcite at ca. 328 ka, which marks increasing precipitation at the onset of MIS 9 and occurs within a trend of decreasing δ18O values. Also the comparison with the multiproxy climate record available from the nearby Lake Ohrid seems to support the proposed interpretation. The MIS 9e interglacial appears to be characterized by wettest conditions between ca. 326 and 321 ka, i.e. lasting ca. 5 kyr. Decreasing precipitation and enhanced millennial scale variability matches the glacial inception (MIS9 d to b), with drier events at ca. 319 ka (ca. 2 kyr long) and 310 ka (ca. 1 kyr long), and a major rainfall reduction between 306 and 298 ka. The latter is followed by a prominent wetter period between 298 and 295 ka, for which carbon data values suggest high infiltration rate. Rainfall decreases again after 295 ka, and remain low until the growth interruption at ca. 292 ka. Resumption of the growth and progressive soil development, expressed by the carbon isotope record, occurred during the late part of MIS 8. Despite the rather high temporal uncertainty (average 6 ka), the speleothem hydrological record complements the environmental information provided by the Lake Ohrid record and also fits well to the framework of regional and extra-regional variability, showing similarities with pollen records from southern and western Europe, both at orbital and at sub-orbital time137 7