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Zanetti, Alberto
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- PublicationOpen AccessThe petrogenesis of chemically zoned, phonolitic, Plinian and sub-Plinian eruptions of Somma-Vesuvius, Italy: Role of accessory phase removal, independently filled magma reservoirs with time, and transition from slightly to highly silica undersaturated magmatic series in an ultrapotassic stratovolcano(2022)
; ; ; ; ; ; ; ; ; A mineralogical, major, LA-ICP-MS trace element mineral chemistry and bulk-rock geochemical study of juvenile samples of the Mercato, Avellino, Pompeii and Pollena eruptions, collected in stratigraphically and volcano logically well-characterized sections of the Somma-Vesuvius stratovolcano (Roman Magmatic Province), along with reference data on the 1944 CE and the Pomici di Base eruptions, highlights the compositional variability of bulk-rock and glass from leucite phonotephrite to garnet-bearing phonolite. The latter products have extreme fractionation of trace elements (e.g., La/Ybn = 126, Zr/Y = 89, Zr/Hf =78, Nb/Ta = 40; Th/U = 2.3), very low Sc, V, Y, HREE and very high As, Tl, Cs, Pb, Th and U. The Pomici di Base products, older than the eruptions described above, range from leucite-bearing shoshonites to trachytes, are devoid of garnet and belong to an independent liquid-line-of-descent, having also different fractionation between trace elements (e.g., La/Ybn =15; Zr/Y = 12.4, Zr/Hf = 50, Nb/Ta = 15.6; Th/U = 3 in the Pomici di Base trachytes). A marked chemical variability of the observed phases is found. The geochemistry of garnet, amphibole, clinopyroxene and other phases shows wide variations of concentrations and elemental ratios (e.g., La/Ybn up to 520 in the sadanagaite coexisting with garnet). The magmatic evolution is dominated by low-pressure, oxidized, nearly closed-system fractional crystallization of clinopyroxene, plagioclase, leucite, ±magnetite, ±biotite, ±olivine and apatite in the transition tephrite-phonotephrite, and of potassic sanidine (±hyalophane), Fe-clinopyroxene, melanite garnet ±Fe-amphibole in the transition tephriphonolite-phonolite. Mineralogic and geochemical evidence and model ling points out the existence of independent, zoned magma batches throughout the activity of the stratovolcano, which possibly started to crystallize at similar depths. The Somma-Vesuvius magmas thus evolved in shallow independent reservoirs with respect to those of the neighbouring volcanic complexes (Campi Flegrei, Ischia) as shown, for instance, by the contrasting compositional trends of clinopyroxene and amphibole, and have very limited evidence of crustal contamination (and/or carbonate assimilation).68 2 - PublicationOpen AccessThe Variscan subduction inheritance in the Southern Alps Sub-Continental Lithospheric Mantle: Clues from the Middle Triassic shoshonitic magmatism of the Dolomites (NE Italy)Although often speculated, the link between theMiddle Triassic shoshonitic magmatismat the NE margin of the Adria plate and the subduction-related metasomatismof the Southern Alps Sub-Continental Lithospheric Mantle (SCLM) has never been constrained. In this paper, a detailed geochemical and petrological characterization of the lavas, dykes and ultramafic cumulates belonging to the shoshonitic magmatic event that shaped the Dolomites (Southern Alps) was used tomodel the composition and evolution of the underlying SCLMin the time comprised between the Variscan subduction and the opening of the Alpine Tethys. Geochemical models and numerical simulations enabled us to define that 5–7% partial melting of an amphibole + phlogopite-bearing spinel lherzolite, similar to the Finero phlogopite peridotite, can account for the composition of the primitive Mid-Triassic SiO2- saturated to -undersaturated melts with shoshonitic affinity (87Sr/86Sri = 0.7032–0.7058; 143Nd/144Ndi = 0.51219–0.51235; Mg # ~ 70; ~1.1 wt% H2O). By taking into account the H2O content documented in mineral phases from the Finero phlogopite peridotite, it is suggested that the Mid-Triassic SCLM source was able to preserve a significant enrichment and volatile content (600–800 ppm H2O) for more than 50 Ma, i.e. since the slab-related metasomatismconnected to the Variscan subduction. The partialmelting of a Finero-like SCLM represents the exhaustion of the subduction-related signature in the Southern Alps lithosphere that predated the Late Triassic-Early Jurassic asthenospheric upwelling related to the opening of the Alpine Tethys.
43 32 - PublicationOpen AccessCrystal-mush reactivation by magma recharge: Evidence from the Campanian Ignimbrite activity, Campi Flegrei volcanic field, Italy(2020)
; ; ; ; ; ; ; ; ; ; ; Processes of crystal-mush remobilization bymaficmagma recharges are often related to the outpouring of large volumes of silicic melt during caldera-forming eruptions. This occurred for the Campanian Ignimbrite (CI) eruption (Campi Flegrei, Italy), which produced a voluminous trachy-phonolitic ignimbrite in southern-central Italy about 40 ka ago.We focussed on the proximal-CI deposits at San Martino that are composed of a main sequence of early-erupted, crystal-poor units and a late-erupted (post-caldera collapse) crystal-rich Upper Pumice Flow Unit (UPFU). Detailed micro-analytical geochemical data were performed on glasses and crystals of pyroclasts from these deposits and coupledwith Sr-Nd isotopic measurements on glasses. Results show that the CI eruption was fed by two distinctmelts for the early-erupted units and the late UPFU, respectively. The glasses of the early erupted units have negative Eu anomalies and show more evolved compositions and higher Nd isotope ratios than those of the UPFU, which have positive Eu/Eu*. The magmas of the early units formed the main volume of eruptiblemelt of the CI reservoir, and are interpreted as having been extracted from cumulate crystal-mush without a vertical geochemical gradient within the magma reservoir. The data indicate that the generation of the distinctive UPFU melts involved the injection of a new batch of mafic magma into the base of the CI reservoir. The mafic magma allowed heating and reactivation of the CI crystal-mush by melting of low-Or sanidines (+/− low-An plagioclases), leaving high-An plagioclases and high-Mg# clinopyroxenes as residual phases and a crystal-mush melt, made of 20% of the initial mush interstitial melt (with a composition similar to the early erupted units) and 80% of sanidine melt. When the mush crystallinity was sufficiently reduced, the mafic magma was able to penetrate into the reactivated crystal-mush, mixing with variable proportions of crystalmush melt and generating cooler hybrid melts, which underwent further crystallization of high-Or sanidine at variable degrees (10–25%). Finally, possibly a short time before the eruption, the UPFU magmas were able to mix and mingle with the crystal-poor eruptible melts still persisting in the CI reservoir at the time of UPFU emission. We suggest that the complex mechanisms described for themagma evolution feeding the CI eruption may occur whenever a crystal-mush is reactivated by new mafic magma inputs .91 10 - PublicationRestrictedConstraining the recent plumbing system of Vulcano (Aeolian Arc, Italy) by textural, petrological and fractal analysis: The 1739 AD Pietre Cotte Lava Flow(2009)
; ; ; ; ; ; ;Piochi, M; Istituto Nazionale di Geofisica e Vulcanologia, Sezione OV, Napoli, Italia ;De Astis, G.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Roma1, Roma, Italia ;Petrelli, M.; Universita' di Perugia ;Ventura, G.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Roma1, Roma, Italia ;Sulpizio, R.; Universita' di Bari ;Zanetti, A.; CNR, IGG Pavia; ; ; ; ; The 1739 A.D. Pietre Cotte lava flow is part of a sequence of low-explosive to weak effusion events occurred at La Fossa Cone, the active vent on Vulcano Island (Aeolian Arc, Italy). This lava is rhyolitic, texturally heterogeneous, and contains lati-trachytic enclaves. These compositions are recurrent in the La Fossa volcanic products and are representative of the recent Vulcano plumbing system. The host lava is vesicular, relatively phenocryst-free, and locally contains microlites and millimeter-sized spherulites. The enclaves are up to 10 cm in size, display angular to spherical shapes, and can form the core of spherulites. Enclaves mostly consist of plagioclase and augitic phenocrysts set in a weakly vesicular groundmass characterized by variable abundance of glass and feldspar microlites. Field, textural, and fractal data allow us to constrain the rheological features of the rhyolitic and lati-trachytic magmas. In situ major, trace, and volatile element analyses provide evidence for heterogeneities in the glassy matrix and zoning of phenocrysts. Processes of magma evolution have been quantitatively constrained by using the apparent distribution ratios of trace elements measured between mineral phases and glassy matrices. The collected data in combination with petrological and fluid inclusion data from the literature provides evidence for (1) a genetic relationship between the two magmas through assimilation fractional crystallization process; (2) a mingling mechanism between an uprising rhyolitic magma and a shallower partly crystallized lati-trachytic magma plug; (3) the desegregation (enclaves) at variable scales of the lati-trachyte within the rhyolite; and (4) the possible eruptive scenarios consequent to a future magmatic unrest.218 31 - PublicationRestrictedTexture and composition of pumices and scoriae from the Campi Flegrei caldera (Italy): implications on the dynamics of explosive eruptions(2008-03-19)
; ; ; ; ; ; ; ;Piochi, M.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione OV, Napoli, Italia ;Polacci, M.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Catania, Catania, Italia ;De Astis, G.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione OV, Napoli, Italia ;Zanetti, A.; CNR ;Mangiacapra, A.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Bologna, Bologna, Italia ;Vannucci, R.; CNR ;Giordano, D.; Università Roma Tre; ; ; ; ; ; The Campi Flegrei (CF) caldera is one of the most dangerous quiescent volcanic systems in the world. Its activity mostly resulted in low magnitude explosive eruptions, such as that of the Monte Nuovo tuff cone that represents the last eruptive event within the caldera (AD 1538). However, there have been more energetic Plinian events, i.e., the Agnano Monte Spina eruption (4.1 ky), and very highly-explosive, caldera-forming eruptions, i.e., the Campanian Ignimbrite eruption (39 ky). Here, we integrate new and literature data on the groundmass texture and composition of pyroclastic products from the three above eruptions with the aim of unraveling how volatiles content, degassing mechanisms and crystallization processes influence magma explosivity and eruption dynamics at CF. Previous studies indicate that the investigated rocks share similar major element bulk and phenocryst chemistry; also similar is the water content of their trapped melt inclusions. These observations suggest that the magmas feeding these eruptions had comparable physico-chemical properties during storage in the shallow crust. However, our investigations indicate that the studied rocks differ in texture and composition of the groundmass and viscosity of the related magmas. We ascribe such differences to the variable style of volatile exsolution and outgassing from the melt, primarily in response to changes of the rate of magma ascent to the surface. We conclude that the magma ascent rate was the key-parameter in driving explosive eruptions at CF and we suggest that this parameter may be influenced by magma/water interaction and/or magma chamber geometry and replenishment.185 26 - PublicationRestrictedEvidence for an intra-oceanic affinity of the serpentinized peridotites from the Mt. Pollino ophiolites (Southern Ligurian Tethys): Insights into the peculiar tectonic evolution of the Southern ApenninesA detailed petrochemical investigation of the peridotites from the Mt. Pollino area (Basilicata, Southern Italy) allowed to provide the first comprehensive reconstruction of the evolution and geodynamic setting of ophiolitic mantle from the Southern Apennines. These mantle peridotites firstly acquired strongly-refractory modal and chemical compositions consistent with large degrees of partial melting (≥ 23%). This process was presumably assisted by concomitant injection of melt increments rising from deeper levels of the mantle column, as suggested by relatively large Al and Fe contents of Ol, Opx and Sp. The porous flow ascent of melt increments produced by deeper near-fractional melting continued after the end of the partial melting, as recorded by precipitation of disseminated clinopyroxene out of thermal and chemical equilibrium with the other rock-forming minerals. The Pollino mantle sequence locally experienced reheating associated to a new episode of porous flow migration of melts with REE composition approaching that of N-MORB. The petrological evolution recorded by the peridotites of Mt. Pollino, their high equilibrium T (up to 1100 °C) and the absence of pyroxenites show remarkable analogies with modern abyssal peridotites, pointing to an intra-oceanic setting of the Jurassic Ligurian Tethys for this mantle sequence. According to the present knowledge about the Southern Apennines, the abyssal-like peridotites with the associated terrigenous sediments and continental crustal rocks were incorporated in the Ligurian Accretionary Complex and reached HP/LT conditions during a subduction event starting in Upper Oligocene, to be later exhumed in the Tortonian. The results of this study strongly support the existence of significant differences in terms of geodynamic evolution between Southern and Northern Apennines.
223 3 - PublicationOpen AccessUltra-depleted melt refertilization of mantle peridotites in a large intra-transform domain (Doldrums Fracture Zone; 7–8°N, Mid Atlantic Ridge)(2020)
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; The Doldrums transform system offsets the Equatorial Mid Atlantic Ridge by ~630 km at 7–8° N. This transform system consists of four intra-transform spreading centers (ITRs) bounded by five transform faults. The northernmost ITR is linked to the MAR axis by a ~ 180 km-long transform. Here, during two R/V A. N. Strakhov expeditions (S06 and S09), mantle peridotites were dredged along the transverse and median ridge of the transform, across the western flank of the ITR valley. Residual harzburgites were mainly sampled along the northern Doldrums transform valley, whereas plagioclase-bearing peridotites showing evidence for melt-rock interaction characterize the ITR domain. Petrological and geochemical observations reinforced by geochemical modelling are used to define the behaviour of trace elements during melt extraction and melt-rock reaction in our rocks. Results suggest that residual peridotites derive from mantle rocks that have undergone a degree of partial melting up to 12%, with melting likely starting at the transition of garnet-spinel stability fields, whereas peridotites which suffered melt-rock reactions have been divided into two types: (i) pl-impregnated peridotites, formed by migration of melts at high porosity and high melt-rock ratio; and (ii) refertilized peridotites, generated at reduced porosity, when small fractions of the same percolating melt crystallized clinopyroxene and minor plagioclase. We suggest that the refertilizing agent was a melt highly depleted in incompatible trace elements, in turn produced by an ultra-depleted mantle source. This mantle experienced previous degrees of melt extraction at the ridge axis, before being transposed laterally along the transform where it melted a second time during the opening of the intra-transform spreading segment.128 13 - PublicationRestrictedFrom the Middle Triassic Cima Pape complex (Dolomites; Southern Alps) to the feeding systems beneath active volcanoes: Clues from clinopyroxene textural and compositional zoningCrystal zoning plays a fundamental role in modern volcanology as a key to unravel the geometry and the dynamics of plumbing systems. In this study, a detailed textural and compositional study of clinopyroxene crystals entrained in intrusive, hypabyssal and effusive products from Cima Pape (Dolomites) is coupled with thermobarometric-hygrometricmodels to reconstruct the geometry and evolution of the feeding systembeneath Middle Triassic volcanic edifices. Whole-rock major, trace element distribution and Sr-Nd isotopic signature (87Sr/86Sri = 0.7045–0.7050; 143Nd/144Ndi = 0.51223–0.51228) show that the rocks from Cima Pape are SiO2- saturated and have shoshonitic affinity, and likely belong to the acme of the Mid-Triassic magmatismthat shaped the Southern Alps between 239 and 237.6Ma. Highly porphyritic trachybasaltic to basaltic trachyandesitic volcanic rocks contain a large number of concentric-zoned clinopyroxene crystals. Here, high-Mg# and -Cr2O3, REEdepleted bands (Mg# 80–91; Cr2O3 up to 1.2 wt%) with variable thickness grew between relatively low-Mg# and -Cr2O3 (Mg# 70–77; Cr2O3 < 0.1 wt%) augitic cores and rims. In contrast, the gabbroic to monzodioritic 50- to 300-m-thick sill cropping out belowthe volcanic sequences, though to represent a relic of the shallowest portion of the plumbing system, is mostly made up of unzoned clinopyroxene crystals. Thermobarometric and hygrometric models allowed us to define that a small “mush-type” batchwas located beneath the Cima Pape volcano at depths between 7 and 14 km. Here, augitic clinopyroxene formed in equilibrium with a slightly evolved (basaltic trachyandesitic), H2O-rich melt (Mg# = 43–45; T = 1035–1075 °C; H2O = 2.6–3.8 wt%). Periodic replenishments of the magma batch by primitive (Mg# = 65–70), hotter and relatively H2O-poor (T = 1130–1150 °C; H2O = 2.1–2.8 wt%) basaltic magmas led to the formation of diopsidic bands mantling the already formed augitic cores. Later on, re-equilibration of clinopyroxene with the mixed melt resulted in the formation of low-Mg#, LILE- and LREE-enriched rims. The most Mg-poor micro-phenocrystic clinopyroxene in the volcanic rocks and in the sill records the ultimate and shallowest conditions of crystallization, occurring at T of 975–1010 °C and P comprised between 50 and 150 MPa. Based on the presence of similar zoning in clinopyroxene phenocrysts, a comparison between the Mid-Triassic Cima Pape and active volcanoes was put forward to highlight the potential of studying ancient, entirely exposed volcanic systems for interpreting the feeding systemprocesses acting beneath active volcanoes. At a regional scale, this approach represents a new, powerful tool for investigating the evolution of the Mid-Triassic magmatism in the Southern Alps and shedding light on the interactions between mantle-derived melts and differentiated batches ponding in the crust.
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