Please use this identifier to cite or link to this item:
http://hdl.handle.net/2122/8969| DC Field | Value | Language |
|---|---|---|
| dc.contributor.authorall | van Geldern, R.; GeoZentrum Nordbayern, Applied Geosciences, Friedrich-Alexander-University Erlangen-Nuremberg, Schlossgarten 5, 91054 Erlangen, Germany | en |
| dc.contributor.authorall | Verma, M. P.; Geotermia, Instituto de Investigaciones Eléctricas, Reforma 113, Col. Palmira, Cuernavaca, Mor. C.P. 62490, Mexico | en |
| dc.contributor.authorall | Carvalho, M. C.; Centre for Coastal Biogeochemistry Research, Southern Cross University, Lismore 2480, NSW, Australia | en |
| dc.contributor.authorall | Grassa, F.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia | en |
| dc.contributor.authorall | Delgado-Huertas, A.; Laboratorio de Biogeoquímica de Isótopos Estables, Instituto Andaluz de Ciencias de la Tierra IACT(CSIC-UGR), Avda. de las Palmeras 4, 18100 Armilla, Granada, Spain | en |
| dc.contributor.authorall | Monvoisin, G.; Laboratoire Interactions et Dynamiques des Environnements de Surface, Bâtiment 504, Université Paris Sud, 91405 Orsay, France | en |
| dc.contributor.authorall | Barth, J. A. C.; GeoZentrum Nordbayern, Applied Geosciences, Friedrich-Alexander-University Erlangen-Nuremberg, Schlossgarten 5, 91054 Erlangen, Germany | en |
| dc.date.accessioned | 2014-03-17T08:04:37Z | en |
| dc.date.available | 2014-03-17T08:04:37Z | en |
| dc.date.issued | 2013-06-21 | en |
| dc.identifier.uri | http://hdl.handle.net/2122/8969 | en |
| dc.description.abstract | RATIONALE: Stable carbon isotope ratios of dissolved inorganic (DIC) and organic carbon (DOC) are of particular interest in aquatic geochemistry. The precision for this type of analysis is typically reported in the range of 0.1‰ to 0.5‰. However, there is no published attempt that compares !13C measurements of DIC and DOC among different laboratories for natural water samples. METHODS: Five natural water samples (lake water, seawater, two geothermal waters, and petroleum well water) were analyzed for !13CDIC and !13CDOC values by !ve laboratories with isotope ratio mass spectrometry (IRMS) in an international pro!ciency test. RESULTS: The reported !13CDIC values for lake water and seawater showed fairly good agreement within a range of about 1‰, whereas geothermal and petroleum waters were characterized by much larger differences (up to 6.6‰ between laboratories). !13CDOC values were only comparable for seawater and showed differences of 10 to 21‰for other samples. CONCLUSIONS: This study indicates that scatter in !13CDIC isotope data can be in the range of several per mil for samples from extreme environments (geothermal waters) and may not yield reliable information with respect to dissolved carbon (petroleum wells). The analyses of lake water and seawater also revealed a larger than expected difference and researchers from various disciplines should be aware of this. Evaluation of analytical procedures of the participating laboratories indicated that the differences cannot be explained by analytical errors or different data normalization procedures and must be related to speci!c sample characteristics or secondary effects during sample storage and handling. Our results reveal the need for further research on sources of error and on method standardization. | en |
| dc.language.iso | English | en |
| dc.publisher.name | Wiley Online Library | en |
| dc.relation.ispartof | Rapid Communication in Mass Spectrometry | en |
| dc.relation.ispartofseries | /27 (2013) | en |
| dc.subject | proficiency test | en |
| dc.subject | isotopes | en |
| dc.subject | DIC | en |
| dc.subject | DOC | en |
| dc.title | Stable carbon isotope analysis of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC) in natural waters – Results from a worldwide pro!ciency test | en |
| dc.type | article | en |
| dc.description.status | Published | en |
| dc.type.QualityControl | Peer-reviewed | en |
| dc.description.pagenumber | 2099-2107 | en |
| dc.subject.INGV | 05. General::05.04. Instrumentation and techniques of general interest::05.04.99. General or miscellaneous | en |
| dc.identifier.doi | 10.1002/rcm.6665 | en |
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Anthropogenically enhanced "uxes of water and carbon from the Mississippi River. Nature 2008, 451, 449. [6] P. Schulte, R. van Geldern, H. Freitag, A. Karim, P. Négrel, E. Petelet-Giraud, A. Probst, J. L. Probst, K. Telmer, J. Veizer, J. A. C. Barth. Applications of stable water and carbon isotopes in watershed research: Weathering, carbon cycling, and water balances. Earth-Sci. Rev. 2011, 109, 20. [7] D. H. Doctor, C. Kendall, S. D. Sebestyen, J. B. Shanley, N.Ohte, E.W. Boyer.Carbon isotope fractionation of dissolved inorganic carbon (DIC) due to outgassing of carbon dioxide from a headwater stream. Hydrol. Processes 2008, 22, 2410. [8] R. van Geldern, T. Hayashi, M. E. Böttcher, M. J. Mottl, J. A. C. Barth, S. Stadler. Stable isotope geochemistry of pore waters and marine sediments from the New Jersey shelf: Methane formation and "uid origin. Geosphere 2013, 9, 96. [9] A. Myrttinen, V. Becker, R. van Geldern, H. Würdemann, D. Morozova, M. Zimmer, H. Taubald, P. Blum, J. A. C. Barth. Carbon and oxygen isotope indications for CO2 behaviour after injection: First results from the Ketzin site (Germany). Int. J. Greenhouse Gas Control 2010, 4, 1000. [10] J.-F. Hélie, C. Hillaire-Marcel. Sources of particulate and dissolved organic carbon in the St Lawrence River: isotopic approach. Hydrol. Processes 2006, 20, 1945. [11] A. Stögbauer, H. Strauss, J. Arndt, V. Marek, F. Einsiedl, R. van Geldern. Rivers of North-Rhine Westphalia revisited: Tracing changes in river chemistry. Appl. Geochem. 2008, 23, 3290. [12] J. Barth, J. Veizer. Three-component water balance to enable protection of ecologically important ecosystems: an example from the St. Lawrence River. Appl. Geochem. 2004, 19, 1637. [13] Final Report on Fourth Interlaboratory Comparison Exercise for !2H and !18O Analysis of Water Samples (WICO2011), (Eds: M. Ahmad, P. Aggarwal, M. van Duren, L. Poltenstein, L. Araguas, T. Kurttas, L. I. Wassenaar). International Atomic Energy Agency, Vienna, Austria, 2012, p. 67. [14] Available: http://isogeochem.wikispaces.com/. [15] N. Assayag, K. Rivé, M. Ader, D. Jézéquel, P. Agrinier. Improved method for isotopic and quantitative analysis of dissolved inorganic carbon in natural water samples. Rapid Commun. Mass Spectrom. 2006, 20, 2243. [16] G. St-Jean. Automated quantitative and isotopic (13C) analysis of dissolved inorganic carbon and dissolved organic carbon in continuous-"ow using a total organic carbon analyser. Rapid Commun. Mass Spectrom. 2003, 17, 419. [17] C. Spötl. A robust and fast method of sampling and analysis of !13 C of dissolved inorganic carbon in ground waters. Isot. Environ. Health Stud. 2005, 41, 217. [18] Available: http://nucleus.iaea.org/rpst/. [19] Available: http://www.nist.gov/srm/. [20] G. Capasso, R. Favara, F. Grassa, S. Inguaggiato, M. Longo. On-line technique for preparing and measuring stable carbon isotope of total dissolved inorganic carbon in water samples (!13CTDIC). Ann. Geophys. 2005, 48, 159. [21] G. G. Salata, L. A. Roelke, L. A. Cifuentes. A rapid and precise method for measuring stable carbon isotope ratios of dissolved inorganic carbon. Mar. Chem. 2000, 69, 153. [22] D. Paul, G. Skrzypek, I. Fórizs. Normalization of measured stable isotopic compositions to isotope reference scales – A review. Rapid Commun. Mass Spectrom. 2007, 21, 3006. [23] S. Emerson, J. Hedges. Chemical Oceanography and the Marine Carbon Cycle. Cambridge University Press, Cambridge, 2008. [24] M. P. Verma. A revised analytical method for HCO3 and CO32– determinations in geothermal waters: An assessment of IAGC and IAEA interlaboratory comparisons. Geostandards Geoanal. Res. 2004, 28, 391. [25] M. P. Verma. Determination of carbonic species in ground, surface, geothermal, ocean and petroleum waters: Theoretical aspects of CO2 chemistry in acid-base titration. J. Anal. Chem. 2013, submitted. [26] M. P. Verma, P. Brikle, D. Sánchez, in Proceedings World Geothermal Congress 2010, Bali, Indonesia, 25–29 April, 2010. [27] I. Clark, P. Fritz. Environmental Isotopes in Hydrology. Lewis, Boca Raton, 1997. [28] J. E. Spangenberg. Caution on the storage of waters and aqueous solutions in plastic containers for hydrogen and oxygen stable isotope analysis. Rapid Commun. Mass Spectrom. 2012, 26, 2627. [29] J. E. Spangenberg, T. W. Vennemann. The stable hydrogen and oxygen isotope variation of water stored in polyethylene terephthalate (PET) bottles. Rapid Commun. Mass Spectrom. 2008, 22, 672. [30] S. J. Taipale, E. Sonninen. The in"uence of preservationmethod and time on the !13C value of dissolved inorganic carbon in water samples. Rapid Commun. Mass Spectrom. 2009, 23, 2507. [31] B. M. Van Breukelen,W. F. M. Röling, J. Groen, J. Grif!oen, H. W. Van Verseveld. Biogeochemistry and isotope geochemistry of a land!ll leachate plume. J. Contam. Hydrol. 2003, 65, 245. [32] P. P. Videla, A. J. Farwell, B. J. Butler, D. G. Dixon. Examining the microbial degradation of naphthenic acids using stable isotope analysis of carbon and nitrogen. Water Air Soil Pollut. 2009, 197, 107. [33] W. A. Brand, in Handbook of Stable Isotope Analytical Techniques, vol. I, (Ed: P. A. De Groot), Elsevier, Amsterdam, 2004. | en |
| dc.description.obiettivoSpecifico | 2IT. Laboratori sperimentali e analitici | en |
| dc.description.journalType | JCR Journal | en |
| dc.description.fulltext | restricted | en |
| dc.contributor.author | van Geldern, R. | en |
| dc.contributor.author | Verma, M. P. | en |
| dc.contributor.author | Carvalho, M. C. | en |
| dc.contributor.author | Grassa, F. | en |
| dc.contributor.author | Delgado-Huertas, A. | en |
| dc.contributor.author | Monvoisin, G. | en |
| dc.contributor.author | Barth, J. A. C. | en |
| dc.contributor.department | GeoZentrum Nordbayern, Applied Geosciences, Friedrich-Alexander-University Erlangen-Nuremberg, Schlossgarten 5, 91054 Erlangen, Germany | en |
| dc.contributor.department | Geotermia, Instituto de Investigaciones Eléctricas, Reforma 113, Col. Palmira, Cuernavaca, Mor. C.P. 62490, Mexico | en |
| dc.contributor.department | Centre for Coastal Biogeochemistry Research, Southern Cross University, Lismore 2480, NSW, Australia | en |
| dc.contributor.department | Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia | en |
| dc.contributor.department | Laboratorio de Biogeoquímica de Isótopos Estables, Instituto Andaluz de Ciencias de la Tierra IACT(CSIC-UGR), Avda. de las Palmeras 4, 18100 Armilla, Granada, Spain | en |
| dc.contributor.department | Laboratoire Interactions et Dynamiques des Environnements de Surface, Bâtiment 504, Université Paris Sud, 91405 Orsay, France | en |
| dc.contributor.department | GeoZentrum Nordbayern, Applied Geosciences, Friedrich-Alexander-University Erlangen-Nuremberg, Schlossgarten 5, 91054 Erlangen, Germany | en |
| item.openairetype | article | - |
| item.cerifentitytype | Publications | - |
| item.languageiso639-1 | en | - |
| item.grantfulltext | restricted | - |
| item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
| item.fulltext | With Fulltext | - |
| crisitem.author.dept | GeoZentrum Nordbayern, Applied Geosciences, Friedrich-Alexander-University Erlangen-Nuremberg, Schlossgarten 5, 91054 Erlangen, Germany | - |
| crisitem.author.dept | Geotermia, Instituto de Investigaciones Eléctricas, Reforma 113, Col. Palmira, Cuernavaca, Mor. C.P. 62490, Mexico | - |
| crisitem.author.dept | Centre for Coastal Biogeochemistry Research, Southern Cross University, Lismore 2480, NSW, Australia | - |
| crisitem.author.dept | Istituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Palermo, Palermo, Italia | - |
| crisitem.author.dept | Laboratoire Interactions et Dynamiques des Environnements de Surface, Bâtiment 504, Université Paris Sud, 91405 Orsay, France | - |
| crisitem.author.dept | GeoZentrum Nordbayern, Applied Geosciences, Friedrich-Alexander-University Erlangen-Nuremberg, Schlossgarten 5, 91054 Erlangen, Germany | - |
| crisitem.author.orcid | 0000-0002-4360-9911 | - |
| crisitem.author.orcid | 0000-0001-5043-792X | - |
| crisitem.author.orcid | 0000-0002-7240-1570 | - |
| crisitem.author.parentorg | Istituto Nazionale di Geofisica e Vulcanologia | - |
| crisitem.classification.parent | 05. General | - |
| crisitem.department.parentorg | Istituto Nazionale di Geofisica e Vulcanologia | - |
| Appears in Collections: | Article published / in press | |
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| vanGeldern et al 2013.pdf | Main article | 463.61 kB | Adobe PDF |
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