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An experimental study on the pressure dependence of viscosity in silicate melts
Language
English
Obiettivo Specifico
2.3. TTC - Laboratori di chimica e fisica delle rocce
Status
Published
JCR Journal
JCR Journal
Peer review journal
Yes
Title of the book
Issue/vol(year)
4/131(2009)
Publisher
American Institute of Physics
Pages (printed)
044504-14
Issued date
July 23, 2009
Alternative Location
Abstract
The effect of pressure on melt viscosity was investigated for five compositions along the join An(CaAl2Si2O8)–Di(CaMgSi2O6) and four alkali silicates containing lithium, sodium, and potassium in constant ratio of ∼ 1:1:1, but alkali-silica ratios are varying. The experiments were performed in an internally heated gas pressure vessel at pressures from 50 to 400 MPa in the viscosity range from 108 to 1011.5 Pa⋅s using parallel plate viscometry. The polymerized An composition shows a negative pressure dependence of viscosity while the other, more depolymerized compositions of the join An–Di have neutral to positive pressure coefficients. The alkali silicates display neutral to slightly positive pressure coefficients for melt viscosity. These findings in the high viscosity range of 108–1011 Pa⋅s, where pressure appears to be more efficient than in low viscous melts at high temperature, are consistent with previous results on the viscosity of polymerized to depolymerized melts in the system NaAlSi3O8–CaMgSi2O6 by Behrens and Schulze [ H. Behrens and F. Schulze, Am. Mineral. 88, 1351 (2003) ]. Thus we confirm that the sign of the pressure coefficient for viscosity is mainly related to the degree of melt polymerization in silicate and aluminosilicate melts.
Sponsors
DFG Grant n.°BE1720/9
References
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2 I. Avramov, J. of Non-Cryst. Sol. 351, 3163 (2005).
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8 F. Schulze, H. Behrens, and W. Hurckuck, Am. Min. 84, 1512 (1999).
9 D. Tinker, C. E. Lesher, G. M. Baxter, T. Uchida, and Y. Wang, Am. Min. 89, 1701 (2004).
10 P. K. Gupta, J. of Am. Ceram. Soc. 70, C-152 (1987).
11 Y. Bottinga, and P. Richet, Geoch. et Cosm. Acta 59, 2725 (1995).
12 J. W. P. Schmeler, E. D. Zanotto, and V. M. Fokin, The J. of Chem. Phy. 122, 074511 (2005).
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39 J. K. Russell, D. Giordano, and D. B. Dingwell, Am. Min. 88, 1390, (2003).
40 P. Tauber, and J. Arndt, Phys. of the Earth and Plan. Int. 43, 97, (1986).
41 H. Taniguchi, J. of Volc. and Geoth. Res. 66, 1, (1995).
42 M. J. Toplis, D. B. Dingwell, K. U. Hess, and T. Lenci, Am. Min. 82, 979, (1997).
43 D. Giordano, and D. B. Dingwell, J. of Phys.: Cond. Matter 15, S9454, (2003).
44 Q. Williams, and R. Jeanloz, Science, 239, 902, (1988).
45 S. K. Lee, G. D. Cody, Y. Fei, and B. O. Mysen, Geoc. et Cosm. Acta 68, 4189, (2004).
46 M. J. Toplis, and D. B. Dingwell, Geoc. et Cosm. Acta 68, 5169, (2004).
47 J. R. Allwardt, J. F. Stebbins, H. Terasaki, L.-S. Du, D. J. Frost, A. C. Withers, M. M. Hirschmann, A. Suzuki, E. Ohtani, Am. Min. 92, 1093, (2007).
48 D. Tinker, C. E. Lesher, I. D. Utcheon, Geoch. et Cosm. Acta 67, 133, (2003).
49 J. E. Reid, B. T. Poe, D. C. Rubie, N. Zotov, M. Wiedenbeck, Chem. Geol. 174, 77, (2001).
2 I. Avramov, J. of Non-Cryst. Sol. 351, 3163 (2005).
3 L. Wondraczek, S. Sen, H. Behrens, and R. E. Youngman, Phys. Rev. B 76, 014202 (2007).
4 P. W. Bridgeman, The physics of high pressure, p. 398. Bell, London (1931).
5 M. H. Cohen, and D. Turnbull, J. of Chem. Phys. 31, 1077 (1959).
6 I. Kushiro, J. Geophys. Res., 81(35), 6347 (1976).
7 C. M. Scarfe,B. O. Mysen, and D. Virgo, In B.O. Mysen, Ed., Special publication no.1, 59–67. The Geochemical Society, University Park, Pensylvania (1987).
8 F. Schulze, H. Behrens, and W. Hurckuck, Am. Min. 84, 1512 (1999).
9 D. Tinker, C. E. Lesher, G. M. Baxter, T. Uchida, and Y. Wang, Am. Min. 89, 1701 (2004).
10 P. K. Gupta, J. of Am. Ceram. Soc. 70, C-152 (1987).
11 Y. Bottinga, and P. Richet, Geoch. et Cosm. Acta 59, 2725 (1995).
12 J. W. P. Schmeler, E. D. Zanotto, and V. M. Fokin, The J. of Chem. Phy. 122, 074511 (2005).
13 I. Avramov,J. of Volc. and Geoth. Research 160, 165 (2007).
14 I. Kushiro, Earth and Plan. Sci. Let. 41, 87 (1978).
15 C. M. Scarfe, B. O.Mysen, and D. Virgo, Carn. Instit. Wash. Yearb. 78, 547 (1979).
16 M. Brearley, J. E. Dickinson, and C. M. Scarfe, Geoch. et Cosm. Acta 50, 2563 (1986).
17 M. Brearley, and A. Montana, Geoch. et Cosm. Acta 53, 2609 (1989).
8 S. Mori, E. Ojami, and A. Suzuki, Earth and Plan. Sci. Let. 175, 87 (2000).
19 K. Funakoshi, M. Kanzaki, A. Yasuda, A. Suzuki, H. Terasaki, and S. Yamashita, Sci. And Tech. Of High Pres., 1023, (2000).
20 A. Suzuki, E. Ohtani, K. Funakoshi, H. Terasaki, and T. Kubo, Phys. Chem. Min. 29, 159, (2002).
21 J. E. Reid, A. Suzuki, K. Funakoshi, H. Terasaki, B. T. Poe, D. C. Rubie, and E. Ohtani, Phys. Earth Planet. Inter. 139, 45 (2003).
22 A. Suzuki, E. Ohtani, H. Terasaki, and K. Funakoshi, Phys. Chem. Min. 32, 140, (2005).
23 B. T. Poe, C. Romano, C. Liebske, D. C. Rubie, H. Terasaki, A. Suzuki, and K. Funakoshi, Chem. Geol. 229, 2 (2006).
24 N. I. Khitarov, Y. B. Lebedev, A. M. Slutsky, A. M. Dorfman, I. A. Soldatov, and N. I. Revin, Trans. From Geokhimiya 10, 1489, (1976).
25 I. Kushiro, J. Geophys. Res., 91(B9), 9343, (1986).
26 C. Liebske, B. Schmickler, H. Terasaki, B. T. Poe, A. Suzuki, K. Funakoshi, R. Ando, and D. C. Rubie, Earth Planet. Sci. Lett. 240, 589 (2005).
27 P. Ardia, D. Giordano, and M. W. Schmidt, Geoch. et Cosm. Acta 72, 6103, (2008).
28 C. Liebske, H. Behrens, F. Holtz, and R. Lange, Geoch. et Cosm. Acta 67, 473, (2003).
29 P. Del Gaudio, H. Behrens, and J. Deubener, J. of Non-Cryst. Sol. 353, 223, (2007).
30 H. Hui, Y. Zhang, Z. Xu, P. Del Gaudio, and H. Behrens, Geoch. et Cosm. Acta (Accepted).
31 B. O. Mysen, Eur. J. Mineral. 7, 745, (1995).
32 H. Scholze, Glastechn. Ber. 32, 81-88 (in German), (1959).
33 N. Zotov, and H. Keppler, Amer. Mineral. 83, 823, (1998).
34 H. Behrens, and A. Stuke, Glass sci. Technol. 76, 176, (2003).
35 E. M. Stolper, Contrib. Mineral. Petrol. 81, 1, (1982).
36 D. Neuville, and P. Richet, Geoch. et Cosm. Acta 55, 1011, (1991).
37 J. Lees, and B. H. J. Williamson, Nature, 208, 278, (1965).
38 J. D. Dudley, and H. T. Hall, Reprinted from The Physical Review, 118, n°5, 1211 (1960).
39 J. K. Russell, D. Giordano, and D. B. Dingwell, Am. Min. 88, 1390, (2003).
40 P. Tauber, and J. Arndt, Phys. of the Earth and Plan. Int. 43, 97, (1986).
41 H. Taniguchi, J. of Volc. and Geoth. Res. 66, 1, (1995).
42 M. J. Toplis, D. B. Dingwell, K. U. Hess, and T. Lenci, Am. Min. 82, 979, (1997).
43 D. Giordano, and D. B. Dingwell, J. of Phys.: Cond. Matter 15, S9454, (2003).
44 Q. Williams, and R. Jeanloz, Science, 239, 902, (1988).
45 S. K. Lee, G. D. Cody, Y. Fei, and B. O. Mysen, Geoc. et Cosm. Acta 68, 4189, (2004).
46 M. J. Toplis, and D. B. Dingwell, Geoc. et Cosm. Acta 68, 5169, (2004).
47 J. R. Allwardt, J. F. Stebbins, H. Terasaki, L.-S. Du, D. J. Frost, A. C. Withers, M. M. Hirschmann, A. Suzuki, E. Ohtani, Am. Min. 92, 1093, (2007).
48 D. Tinker, C. E. Lesher, I. D. Utcheon, Geoch. et Cosm. Acta 67, 133, (2003).
49 J. E. Reid, B. T. Poe, D. C. Rubie, N. Zotov, M. Wiedenbeck, Chem. Geol. 174, 77, (2001).
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