Please use this identifier to cite or link to this item: http://hdl.handle.net/2122/6288
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dc.contributor.authorallLa Spina, A.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Catania, Catania, Italiaen
dc.contributor.authorallBurton, M.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Pisa, Pisa, Italiaen
dc.contributor.authorallSalerno, G. G.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Catania, Catania, Italiaen
dc.date.accessioned2010-12-06T15:04:01Zen
dc.date.available2010-12-06T15:04:01Zen
dc.date.issued2010en
dc.identifier.urihttp://hdl.handle.net/2122/6288en
dc.description.abstractWe measured volcanic gas emissions from the northeast crater (NEC) and central crater (CC) of Mount Etna on 21st July 2008, and 3rd and 31st August 2009, using a novel, lightweight open-path Fourier transform infrared spectrometry (OP-FTIR) in active mode with a portable infrared lamp. Contemporaneously we measured the SO2 flux of the total gas emission released by the combined summit craters 14 km downwind and the SO2 flux emitted by the NEC measured at the summit. Combining these data we determined the flux of the major volcanic components H2O, CO2, SO2, HCl and HF emitted individually from CC and NEC craters. The results reveal similar SO2/HCl ratios but distinct CO2/SO2 ratios (1.3 and 10.9 for NEC and CC, respectively) and an order of magnitude greater CO2 flux from the CC compared with the NEC. A simple model in which the NEC branches from a central feeding conduit at a depth of ~2 km can reproduce these observations. We highlight that in such a system short-term variations in CO2/SO2 ratios at each crater can occur due to minor variations in the magma/gas flux entering each conduit at the branch, without an overall change in magma supply. CO2/ SO2 variations measured at individual craters may therefore be unrepresentative of the volcanic system and require cautious interpretation. Monitoring of the total CO2 and SO2 fluxes emitted from each crater is, on the contrary, an optimal monitoring strategy and can be achieved using a combination of CO2/SO2 instruments and SO2 imaging camerasen
dc.description.sponsorshipINGV-DPC “Sicilia” Project (Gas plumeTask).en
dc.language.isoEnglishen
dc.publisher.nameElsevieren
dc.relation.ispartofJournal of Volcanology and Geothermal Researchen
dc.relation.ispartofseries3-4/198 (2010)en
dc.subjectmagma degassing, OP-FTIR, Mt. Etnaen
dc.titleUnravelling the processes controlling gas emissions from the central and northeast craters of Mt. Etnaen
dc.typearticleen
dc.description.statusPublisheden
dc.type.QualityControlPeer-revieweden
dc.description.pagenumber368-376en
dc.subject.INGV04. Solid Earth::04.08. Volcanology::04.08.01. Gasesen
dc.identifier.doi10.1016/j.jvolgeores.2010.09.018en
dc.relation.referencesAiuppa, A., Inguaggiato, S., McGonigle, A.J.S., O'Dwyer, M., Oppenheimer, C., Padgett, M.J., Rouwet, D., Valenza, M., 2005.H2S fluxes fromMt. Etna, Stromboli, and Vulcano (Italy) and implications for the sulphur budget at volcanoes. Geochim. Cosmochim. Acta 69, 1861–1871. Aiuppa, A., Federico, C., Giudice, G., Guerrieri, S., Liuzzo, M., Shinohara, H., Favara, R., Valenza, M., 2006. Rates of carbon dioxide plume degassing from Mount Etna volcano. J. Geophys. Res. 111, B09207. doi:10.1029/2006JB004307. Aiuppa, A., Giudice, G., Guerrieri, S., Liuzzo,M., Burton,M., Caltabiano, T., McGonigle, A.J.S., Salerno, G., Shinohara, H., Valenza, M., 2008. The total volatile flux from Mount Etna and implications for the geochemicalmonitoring of basaltic volcanoes. Geophys. Res. Lett. 35, L24302. doi:10.1029/2008GL035871. Allard, P., 1997. Endogenous magma degassing and storage at Mount Etna. Geophys. Res. Lett. 24 (17), 2219–2222. Allard, P., Burton, M., Mure, F., 2005. Spectroscopic evidence for a lava fountain driven by previously accumulated magmatic gas. Nature 433, 407–410. Behncke, B., Neri, M., Pecora, E., Zanon, V., 2006. The exceptional activity and growth of the Southeast Crater, Mount Etna (Italy), between 1996 and 2001. Bull. Volcanol. 69 (2), 149–173. doi:10.1007/s00445-006-0061-x. Branca, S., Ferrara, V., 2001. An example of river pattern evolution produced during the lateral growth of a central polygenic volcano: the case of the Alcantara river system, Mt. Etna (Italy). Catena 45 (2), 85–102. Burton, M. (2009), FTIR_FIT: Software for analysis of FTIR absorption spectra for volcanological applications, J. Volcan. Geotherm. Res., submitted. Burton, M.R., Oppenheimer, C., Horrocks, L.A., Francis, P.W., 2000. Remote sensing of CO2 and H2O emissions rates fromMasaya Volcano, Nicaragua. Geology 28 (10), 915–918. Burton, M., Allard, P., Murè, F., Oppenheimer, C., 2003. FTIR remote sensing of fractional magma degassing at Mount Etna, Sicily. Volcanic Degassing: Geol. Soc. Spec. Pub.,213, pp. 281–293. Burton, M., Allard, P., Murè, F., La Spina, A., 2007. Magmatic gas composition reveals the source depth of slug-driven Strombolian explosive activity. Science 317. Caltabiano, T., Romano, R., Budetta, G., 1994. SO2 flux measurements at Mount Etna, Sicily. J. Geophys. Res. 99 (D6), 12809–12819. Clocchiatti, R., Metrich, N., 1984. Témoignages de la contamination dans les produits des eruptions explosives des Mts. Silvestri (1892) et Mts. Rossi (1669), Mt. Etna. Bull. Volcanol. 47/2, 909–928. Collins, S.J., Pyle, D.M.,Maclennan, J., 2009.Melt inclusions track pre-eruption storage and dehydration of magmas at Etna. Geology 37 (6), 571–574. doi:10.1130/G30040A.1. Corsaro, R.M., Pompilio, M., 2004. Magma dymanics in the shallow plumbing system of Mt. Etna as recorded by compositional variations in volcanics of recent summit activity (1995–1999). J. Volcan. Geotherm. Res. 137, 55–71. Cristofolini, R., Lentini, F., Patanè, G., Rasà, R., 1979. Integrazione dei dati geologici, geofisici e petrologici per la stesura di un profilo crostale in corrispondenza dell'Etna. Boll. Soc. Geol. It. 98, 239–247. Di Grazia, G., Cannata, A., Montalto, P., Patané, D., Privitera, E., Zuccarello, L., 2009. A multiparameter approach to volcano monitoring based on 4D analyses of seismovolcanic and acoustic signals: the 2008 Mt. Etna eruption. Geophys. Res. Lett. 36, L18307. doi:10.1029/2009GL039567. Edmonds, M., Gerlach, T.M., 2007. Vapor segregation and loss in basaltic melts. Geology 35 (8), 751–754. doi:10.1130/G23464A.1. Edmonds, M., Pyle, D., Oppenheimer, C., 2002. HCl emissions at Soufriere Hills Volcano, Monserrat, West Indies, during a second phase of dome building: November 1999 to October 2000. Bull. Volcanol. 64, 21–30. Ferrara, V., 1991. Modificazioni indotte dallo sfruttamento delle acque sotterranee sull'equilibrio idrodinamico e idrochimico dell'acquifero vulcanico dell'Etna. Mem. Soc. Geol. It. 47, 619–630. Francis, P., Chaffin, C., Maciejewski, A., Oppenheimer, C., 1996a. Remote determination of SiF4 in volcanic plumes: a new tool for volcano monitoring. Geophys. Res. Lett. 23 (3), 249–252. Francis, P., Maciejewski, A., Oppenheimer, C., Chaffin, C., 1996b. New methods make volcanology research less hazardous. EOS Trans. AGU 77 (393), 396–397. Francis, P., Burton, M.R., Oppenheimer, C., 1998. Remote measurement of volcanic gas compositions by solar occultation spectroscopy. Nature 396, 567–570. La Delfa, S., Patane, G., Clocchiatti, R., Joronb, J.L., Tanguy, J.C., 2001. Activity of Mount Etna preceding the February 1999 fissure eruption: inferred mechanism from seismological and geochemical data. J. Volcanol. Geotherm. Res 105, 121–139. Lentini, F., 1982. The geology of the Mt Etna basement. In: Romano, R. (Ed.), Mt. Etna Volcano: Mem. Soc. Geol. It., 23, pp. 7–26. Martin, R.S., Mather, T.A., Pyle, D.M., Power, M., Allen, A.G., Aiuppa, A., Horwell, C.J., Ward, E.P., 2008. Composition-resolved size distributions of volcanic aerosols in the Mt. Etna plumes. J. Geophys. Res. 113, D17211. McGonigle, A.J.S., Oppenheimer, C., Galle, B., Mather, T.A., Pyle, D.M., 2002. Walking traverse and scanning DOAS measurements of volcanic gas emission rates. Geophys. Res. Lett. 29, 20. Menand, T., Phillips, J.C., 2007. Gas segregation in dykes and sills. J. Volcanol. Geotherm. Res. 159, 393–408. doi:10.1016/j.jvolgeores.2006.08.003. Métrich, N., Clocchiatti, R., Mosbah, M., Chaussidon, M., 1993. The 1989–1990 activity of Etna magma mingling and ascent of H2O–Cl–S-rich basaltic magma. Evidence from melt inclusions. J. Volcanol. Geotherm. Res. 59, 131–144. Métrich, N., Allard, P., Spilliaert, N., Andronico, D., Burton, M., 2004. 2001 flank eruption of the alkali- and volatile-rich primitive basalt responsible for Mount Etna's evolution in the last three decades, Earth Planet. Sci. Lett. 228, 1–17. Moretti, R. (2001), Volatiles solubilitywith particular regardto sulphur species: theoretical aspects and application to Etnean volcanics, PhD Thesis, Univ. of Pisa, Italy. Mori, T., Burton, M., 2006. The SO2 camera: a simple, fast and cheap method for groundbased imaging of SO2 in volcanic plumes. Geophys. Res. Lett. 33, L24804. doi:10.1029/ 2006GL027916. Neri, M. and M. Rossi (2002), Geometria e volume dell'apparato vulcanico etneo: il contributo offerto dall'uso di mappe digitali. INGV, Quaderni di Geofisica, 20. Newman, S., Lowenstern, J.B., 2002. VolatileCalc: a silicate melt–H2O–CO2 solution model written in Visual Basic for Excel. Comput. Geosci. 28 (5), 597–604. Patané, D., Di Grazia, G., Cannata, A., Montalto, P., Boschi, E., 2008. Shallow magma pathway geometry at Mt. Etna Volcano. Geochem. Geophys. Geosyst. 9, Q12021. doi:10.1029/2008GC002131. Salerno, G.G., Burton, M.R., Oppenheimer, C., Caltabiano, T., Tsanev, V., Bruno, N., 2009. Novel retrieval of volcanic SO2 abundance from ultraviolet spectra. J. Volcanol. Geotherm. Res. 181, 141–153. doi:10.1016/j.jvolgeores.2009.01.009. Shinohara, H., Aiuppa, A., Giudice, G., Gurrieri, S., Liuzzo,M., 2008. Variation of H2O/CO2 and CO2/SO2 ratios of volcanic gases discharged by continuous degassing of Mount Etna volcano, Italy. J. Geophys. Res. 113, B09203. doi:10.1029/2007JB005185. Spilliaert, N., Allard, P., Métrich, N., Sobolev, A.V., 2006a. Melt inclusion record of the conditions of ascent, degassing and extrusion of volatile-rich alkali basalt during the powerful 2002 flank eruption of Mount Etna (Italy). J. Geophys. Res. 111, B04203. doi:10.1029/2005/JB003934. Spilliaert, N., Métrich, N., Allard, P., 2006b. S–Cl–F degassing pattern of water-rich alkali basalt: modelling and relationship with eruption styles on Mount Etna volcano. Earth Planet. Sci. Lett. 248, 772–786. Symonds, R.B., Gerlach, T.M., Reed, M.H., 2001. Magmatic gas scrubbing: implication for volcano monitoring. J. Volcanol. Geotherm. Res. 108, 303–341.en
dc.description.obiettivoSpecifico1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attiveen
dc.description.journalTypeJCR Journalen
dc.description.fulltextreserveden
dc.contributor.authorLa Spina, A.en
dc.contributor.authorBurton, M.en
dc.contributor.authorSalerno, G. G.en
dc.contributor.departmentIstituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione OE, Catania, Italiaen
dc.contributor.departmentIstituto Nazionale di Geofisica e Vulcanologia, Sezione Pisa, Pisa, Italiaen
dc.contributor.departmentIstituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione OE, Catania, Italiaen
item.openairetypearticle-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.grantfulltextrestricted-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
crisitem.author.deptIstituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione OE, Catania, Italia-
crisitem.author.deptIstituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Roma1, Roma, Italia-
crisitem.author.deptIstituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione OE, Catania, Italia-
crisitem.author.orcid0000-0002-5007-613X-
crisitem.author.orcid0000-0001-6588-7560-
crisitem.author.orcid0000-0002-9336-107X-
crisitem.author.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
crisitem.author.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
crisitem.author.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
crisitem.classification.parent04. Solid Earth-
crisitem.department.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
crisitem.department.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
crisitem.department.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
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