Please use this identifier to cite or link to this item: http://hdl.handle.net/2122/5190
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dc.contributor.authorallBagnato, E.; Dipartimento CFTA, Università di Palermo, Via Archirafi 36, 90123 Palermo, Italyen
dc.contributor.authorallAiuppa, A.; Dipartimento CFTA, Università di Palermo, Via Archirafi 36, 90123 Palermo, Italy; INGV, Sezione di Palermo, Via La malfa 153, Palermo, Italyen
dc.contributor.authorallParello, F.; Dipartimento CFTA, Università di Palermo, Via Archirafi 36, 90123 Palermo, Italyen
dc.contributor.authorallD'Alessandro, W.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italiaen
dc.contributor.authorallAllard, P.; Laboratoire Pierre Sue, CNRS-CEA, CE-Saclay, 91191 Gif/Yvette, Franceen
dc.contributor.authorallCalabrese, S.; Dipartimento CFTA, Università di Palermo, Via Archirafi 36, 90123 Palermo, Italyen
dc.date.accessioned2009-10-05T07:42:03Zen
dc.date.available2009-10-05T07:42:03Zen
dc.date.issued2009en
dc.identifier.urihttp://hdl.handle.net/2122/5190en
dc.description.abstractQuantifying the contribution of volcanism to global mercury (Hg) emissions is important to understand the pathways and the mechanisms of Hg cycling through the Earth's geochemical reservoirs and to assess its environmental impacts. While previous studies have suggested that degassing volcanoes might contribute importantly to the atmospheric budget of mercury, little is known about the amount and behaviour of Hg in volcanic aquifers. Here we report on detailed investigations of both the content and the speciation of mercury in aquifers of active volcanoes in Italy and Guadeloupe Island (Lesser Antilles). In the studied groundwaters, total Hg (THg) concentrations range from 10 to 500 ng/l and are lower than the 1000 ng/l threshold value for human health protection fixed by the World Health Organization [WHO (1993): WHO Guidelines for Drinking Water Quality- http://www.who.int/water_sanitation_health/GDWQ/index.htlm]. Positive co-variations of (THg) with sulphate indicate that Hg-SO4-rich acid groundwaters receive a direct input of magmatic/hydrothermal gases carrying mercury as Hg0 (gas). Increasing THg in a volcanic aquifer could thus be a sensitive tracer of magmatic gas input prior to an eruption. Since the complex behaviour and toxicity of mercury in waters depend on its chemical speciation, we carefully determined the different aqueous forms of this element in our samples.We find that dissolved elemental Hg0 (aq) and particulate-bound Hg (HgP) widely prevail in volcanic aquifers, in proportions that highlight the efficiency of Hg adsorption onto colloidal particles. Moreover, we observe that dissolved Hg0 aq and Hg(II) forms coexist in comparable amount in most of the waters, in stark contrast to the results of thermodynamic equilibrium modelling. Therefore, chemical equilibrium between dissolved mercury species in volcanic waters is either prevented by natural kinetic effects or not preserved in collected waters due to sampling/storage artefacts. Finally, we provide a first quantitative comparison of the relative intensity of aqueous transport and atmospheric emissions of mercury at Mount Etna, a very active basaltic volcano.en
dc.language.isoEnglishen
dc.publisher.nameElsevieren
dc.relation.ispartofJournal of Volcanology and Geothermal Researchen
dc.relation.ispartofseries/179(2009)en
dc.subjectspeciationen
dc.subjectvolcanic aquifersen
dc.subjecttotal and dissolved mercuryen
dc.subjectmercury cyclingen
dc.subjectvolatile budgeten
dc.titleMercury concentration, speciation and budget in volcanic aquifers: Italy and Guadeloupe (Lesser Antilles)en
dc.typearticleen
dc.description.statusPublisheden
dc.type.QualityControlPeer-revieweden
dc.description.pagenumber96-106en
dc.subject.INGV04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistryen
dc.identifier.doi10.1016/j.jvolgeores.2008.10.005en
dc.relation.referencesAiuppa, A., Dongarrà, G., Capasso, G., Allard, P., 2000a. Trace element in the thermal groundwaters of Vulcano Island (Sicily). J. Volcanol. Geotherm. Res. 98, 189–207. Aiuppa, A., Allard, P., D'Alessandro, W., Michel, A., Parello, F., Treuil, M., Valenza, M., 2000b. Mobility and fluxes major, minor and trace metals during basalt weathering and groundwater transport at Mt. Etna volcano (Sicily). Geochim. Cosmochim. Acta 64, 1827–1841. Aiuppa, A., Allard, P., D'Alessandro, W., Giammanco, S., Parello, F., Valenza, M., 2004. Magmatic gas leakage at Mount Etna (Sicily, Italy): relationships with the volcanotectonic structures, the hydrological pattern and the eruptive activity. Mt. Etna: Volcano Laboratory. A.G.U. Geophysical Monograph Series, vol. 143, pp. 129–145. doi:10.1029/143GM09. Aiuppa, A., Avino, R., Brusca, L., Caliro, S., Chiodini, G., D'Alessandro, W., Favara, R., Federico, C., Ginevra,W., Inguaggiato, S., Longo, M., Pecoraino, G., Valenza, M., 2006. Mineral control of arsenic content in thermal waters from volcano-hosted hydrothermal systems: insights from island of Ischia and Phlegrean Fields (Campanian Volcanic Province, Italy). Chem. Geol. 229, 313–330. Allard, P.,1983. The origin of hydrogen, carbon, sulfur, nitrogen and rare gases in volcanic exhalations: evidence from isotope geochemistry. In: Tazieff, H., Sabroux, J.C. (Eds.), Forecasting volcanic events. Elsevier, Amsterdam , pp. 337–386. Chap. 25. Allard, P., Carbonnelle, J., Dajlevic, D., Le Bronec, J., Morel, P., Maurenas, J.M., Robe, M.C., Faivre-Pierret, R., Sabroux, J.C., Zettwoog, P., 1991. Eruptive and diffuse emissions of carbon dioxide from Etna volcano. Nature 351, 387–391. Allard, P., Carbonnelle, J., Métrich, N., Loyer, H., Zettwoog, P., 1994. Sulfur output and magma degassing budget of Stromboli volcano. Nature 368, 326–330. Allard, P., Jean-Baptiste, P., D'Alessandro, W., Parello, F., Parisi, B., Fleoch, C., 1997. Mantle-derived helium and carbon in groundwaters and gases of Mount Etna, Italy. Earth Planet. Sci. Lett. 148, 501–516. Allard, P., Aiuppa, A., Loyer, H., Carrot, F., Gaudry, A., Pinte, G., Michel, A., Dongarrà, G., 2000. Acid gas and metal emission rates during long-lived basalt degassing at Stromboli Volcano. Geophys. Res. Lett. 27 (8), 1207–1210. Allard, P., Behncke, B., D'Amico, S., Neri, M., Gambino, S., 2006. Mount Etna 1993–2005: anatomy of an evolving eruptive cycle. Earth-Sci. Rev. 78, 85–114. Anderson, A., 1979. Mercury in Soils. In: Nriagu, J.O. (Ed.), The Biogeochemistry of Mercury in the Environment. Elsevier, Amsterdam, pp. 79–112. Appelo, C.A.J., 1988. WATEQP Program. Institute voor Aard-wetenshappen. Vrije Universiteit, Amsterdam. Aureli, A., 1973. Idrogeologia del fianco occidentale etneo. Proceedings of the Second International Symposium on Groundwaters Palermo 28 April–2 May, pp. 425–487. Bagnato, E., Aiuppa, A., Parello, F., Calabrese, S., D'Alessandro, W., Mather, T.A., McGonigle, A.J.S., Pyle, D.M., Wängberg, I., 2007. Degassing of gaseous (elemental and reactive) and particulate mercury from Mount Etna volcano (Southern Italy). Atmos. Environ. 41, 7377–7388. Barberi, F., Neri, G., Valenza, M., Villari, L., 1991. 1987–1990 unrest at Vulcano. Acta Vulcanol. 1, 95–106. Barnes, H.L., Seaward, T.M., 1997. Geothermal systems and mercury deposits. Geochemistry of Hydrothermal Ore Deposits. John Wiley & Sons, New York. Bernard, M.L., Molinié, J., Petit, R.H., Beaducel, F., Hammouya, G., Marion, G., 2006. Remote and in situ plume measurements of acid gas release from La Soufrière volcano, Guadeloupe. J. Volcanol. Geotherm. Res. 150, 395–409. Bloom, N.S., Fitzgerald, W.F., 1988. Determination of volatile mercury species at the picogram level by low-temperature gas chromatography with cold vapour atomic fluorescence detection. Anal. Chim. Acta 209, 151–161. Boichu, M., Villemant, B., Boudon, G., 2008. A model for episodic degassing of an andesitic magma intrusion. J. Geophys. Res.113, B07202. doi:10.1029/2007JB005130. Bolognesi, L., D'Amore, F., 1993. Isotopic variation of the hydrothermal system on Vulcano Island, Italy. Geochim. Cosmochim. Acta 57, 209–2082. Boudon, G., Semet, M., Vincent, P.M., 1989. The evolution of la Grande Decouverte (la Soufriere) volcano, Guadeloupe. F.W.I. In: Latter, J. (Ed.), Volcano Hazards: Assessment and Monitoring. IAVCEI Proceedings in Volcanology, vol. 1. Springer- Verlag, pp. 86–109. Bouysse, P., 1988. Opening of the Grenada back-arc basin and evolution of the Caribbean Plate during the Mesozoic and early Paleogene. Tectonophysiscs 149, 121–143. Caliro, S., Panichi, C., Stanzione, D., 1999. Variation in the total dissolved carbon isotope composition of thermal waters of the Island of Ischia (Italy) and its implications for volcanic surveillance. J. Volcanol. Geotherm. Res. 90, 219–240. Caltabiano, T., Burton, M., Giammanco, S., Allard, P., Bruno, N., Murè, F., Romano, R., 2004. Volcanic gas emissions from the summit craters and flanks of Mt. Etna, 1987– 2000. In: Bonaccorso, A., Calvari, S., Coltelli, M., Del Negro, C., Falsaperla, S. (Eds.), Etna Volcano Laboratory. AGU Geophysical Monography Series, vol. 143, pp. 111–128. Capasso, G., D'Alessandro, W., Favara, R., Inguaggiato, S., Parello, F., 2001. Interaction between the deep fluids and the shallow groundwaters on Vulcano Island (Italy). J. Volcanol. Geotherm. Res. 108 (1), 187–198 (12). Carapezza, M.L., Federico, C., 2000. The contribution of fluid geochemistry to the volcano monitoring of Stromboli. J. Volcanol. Geotherm. Res. 95, 227–245. Chiodini, G., Allard, P., Caliro, S., Parello, F., 2000. 18O exchange between steam and carbon dioxide in volcanic and hydrothermal gases: implications for the origin of water. Geochim. Cosmochim. Acta 64 (14), 2479–2488. Christenson, B.W., Mroczek, E.K., 2003. Potential reaction pathways of hg in some New Zealand hydrothermal environments. Soc. Econom. Geol. 10, 111–132. Civetta, L., Cornette, Y., Crisci, G., Gillot, P.Y., Orsi, G., Requejo, C.S., 1984. Geology, geochronology and chemical evolution of the island of Pantelleria. Geol. Mag. 121 (6), 541–562. D'Alessandro, W., Federico, C., Longo, M., Parello, F., 2004. Oxygen isotope composition of natural waters in the Mt Etna area. J. Hydrol. 296 (1–4), 282–299. D'Alessandro, W., Dongarrà, G., Guerrieri, S., Parello, F., Valenza, M., 1994. Geochemical characterization of naturally occurring fluids on Island of Pantelleria (Italy). Mineral. Petrogr. Acta 37, 91–102. Ferrara, V., 1975. Idrogeologia del versante orientale dell'Etna. Proc. of the 3rd Intern. Conf. on Groundwaters, pp. 91–144. Fitzgerald,W.F.,1986. Cycling of mercury between the atmosphere and oceans. In: Buat- Menard, P. (Ed.), The Role of Air–Sea Exchange in Geochemical Cycling, NATO Advanced Institute Series. Reidel, Dordrecht, The Netherlands, pp. 363–408. Fitzgerald, W.F., Lamborg, C.H., 2003. Geochemistry of mercury in the environment. In: Sherwood Lollar, B. (Ed.), Treatise on Geochemistry, vol. 9, pp. 107–148. Fleischer, M., 1970. Procedures of the International Mineralogical Association Commission on New Minerals and Mineral Names. Am. Mineral. 55, 1016–1017. Fulignati, G., Malfitano, A., Sbrana, A., 1997. The Pantelleria caldera geothermal system: data from the hydrothermal minerals. J. Volcanol. Geotherm. Res. 75, 251–270. Gauthier, P.J., Le Cloarec, M.F., 1998. Variability of alkali and heavy metal fluxes released by Mt. Etna volcano, Sicily, between 1991 and 1995. J. Volcanol. Geotherm. Res. 81, 311–326. Giggenbach, W.F., 1988. Geothermal solute equilibria. Derivation of Na–K–Mg–Ca geoindicators. Geochim. Cosmochim. Acta 52, 2749–2763. Herdianita, N.R., Priadi, B., 2008. Arsenic and mercury concentrations at several geothermal systems in West Java, Indonesia. J. Sci. 40 (1), 1–14. Hornig-Kjarsgaard, I., Keller, J., Koberski, U., Stadlbauer, E., Francalanci, L., Lenhart, R., 1993. Geology, stratigraphy and volcanological evolution of the island of Stromboli, Aeolian arc, Italy. Acta Vulcanol. 3, 21–68. Horvat, M., Kotnik, J., Logar, M., Fajon, V., Zvonaric, T., Pirrone, N., 2003. Speciation of mercury in surface and deep-sea waters in the Mediterranean Sea. Atmos. Environ. 37 (Supplement No. 1), S93–S108. HSC 1999, HSC chemistry for Windows, Version 4, Outokumpu Research Oy, pori, Finland. Ikingura, J.R., Akagi, H., 1999. Methylmercury production and distribution in aquatic systems. Sci. Total Environ. 234, 109–118. Inguaggiato, S., Rizzo, A., 2004. Dissolved helium isotope ratios in groundwaters: a new technique based on gas–water re-equilibration and its application to Stromboli volcanic system. Appl. Geochem. 19, 665–673. Jenne, E.A., 1970. Atmospheric and fluvial transport of mercury. Mercury in the Environment. Geological Survey profession, vol. 713, pp. 40–45. Khodakovskii, I.L., Shikina, N.D., 1981. The role of carbonate complexes in mercury transport in hydrothermal solutions (experimental studies and thermodynamic analysis). Geochem. Int. 18, 32–43. Komorowski, J.C., Boudon, G., Antenor-Habazac, C., Hammouya, G., Semet, M., David, J., Beauducel, Cheminée, J.L., Feuillard, M., 2001. L'activité éruptive et non-éruptive de la Soufrière de Guadeloupe: problèmes et implications de la phénoménologie et des signaux actuellement enregistrés. INSU Lesser Antilles Volcanic HazardWorkshop, Paris, pp. 18–21. abstract volume. Lee, Y.H., Iverfeldt, A., 1991. Measurement of methylmercury and mercury in run-off, lake and rain waters. Water Air Soil Pollut. 56, 405–414. Lin, C.-J., Pehkonen, S.O., 1999a. The chemistry of atmospheric mercury: a review. Atmos. Environ. 33, 2067–2079. Lin, C.-J., Pehkonen, S.O., 1999b. Aqueous phase reactions of mercury with free radicals and chlorine: implications for atmospheric mercury chemistry. Chemosphere 38 (6), 1253–1263. Lindqvist, O., Rodhe, H., 1985. Atmospheric mercury — a review. Tellus 27B, 136–159. Mason, R.P., Fitzgerald, W.F., Morel, F.M.M., 1994. The biogeochemical cycling of elemental mercury: anthropogenic influences. Geochim. Cosmochim. Acta 58 (15), 3191–3198. Nriagu, J., Becker, C., 2003. Volcanic emissions of mercury to the atmosphere: global and regional inventories. Sci. Total Environ. 304, 3–12. Ogniben, L., 1966. Lineamenti idrogeologici dell'Etna. Riv. Min. Sicil. 100–102, 1–24. Paonita, A., Favara, R., Nuccio, P.M., Sortino, F., 2002. Genesis of fumarolic emissions as inferred by isotope mass balances: CO2 and water at Vulcano Island, Italy. Geochim. Cosmochim. Acta 66, 759–772. Parello, F., Allard, P., D'Alessandro, W., Federico, C., Jean-Baptiste, P., Catani, O., 2000. Isotope geochemistry of Pantelleria volcanic fluids, Sicily Channel rift: a mantle volatile end-member for volcanism in southern Europe. Earth Planet. Sci. Lett. 180, 325–339. Parker, J.L., Bloom, N.S., 2005. Preservation and storage techniques for low-level aqueous mercury speciation. Sci. Total Environ. 337, 253–263. Parkhurst, D.L., 1995. User's guide to PHEEQC—a computer program for speciation, reaction-path, advective-transport, and inverse geochemical calculations. U.S. Geological Survey Water-Resources Investigations report, vol. 143, pp. 95–4227. Pyle, D.M., M ather, A.M., 2003. The importance of volcanic emissions for the global atmospheric mercury cycle. Atmos. Environ. 37, 5115–5124. Sarkar, D., Essington, M.E., Mistra, K.C., 2000. Adsorption of mercury (II) by kaolinite. Soil Sci. Soc. Am. J. 64, 1968–1975. Siegel, S.M., Siegel, B.Z.,1984. First estimate of annual mercury flux at Kilauea main vent. Nature 309, 146–147. Slemr, F., Schuster, G., Seiler, W., 1985. Distribution, speciation and budget of atmospheric mercury. Atmos. Environ. 3, 407–434. Stumm,W., Morgan, J.J. (Eds.), 1996. Aquatic Chemistry— Chemical Equilibria and Rates in Natural Waters, 3rd Edition. Wiley Interscience, New York. TEKRAN, 1998. Model 2600.—Principles of Operations. http://tekran.com. U.S. E.P.A, 1999. Method 1631: Mercury inWater by Oxidation, Purge and Trap, and Cold Vapour Atomic Fluorescence Spectrometry. Office of Water, Engineering, Washington (DC). Varekamp, J.C., Buseck, P.R., 1984. The speciation of mercury in hydrothermal systems, with applications for ore deposition. Geochim. Cosmochim. Acta 48, 177–186. Varekamp, J.C., Buseck, P.R., 1986. Global mercury flux from volcanic and geothermal sources. Appl. Geochem. 1, 65–73. Villemant, B., Boudon, G., 1999. H2O and halogens (F, Cl, Br) behaviour during shallow magma degassing processes. Earth Planet. Sci. Lett. 168 (3–4), 271–286. Villemant, B., Hammouya, G., Michel, A., Semet, M.P., Komorowski, J.C., Boudon, G., Cheminee, J.L., 2005. The memory of volcanic waters: shallow magma degassing revealed by halogen monitoring in thermal springs of La Soufriere volcano (Guadeloupe, Lesser Antilles). Earth Planet. Sci. Lett. doi:10.1016/j.epsl.2005.05.013. Washington, H.S.,1909. The submarine eruptions of 1831 and 1891 near Pantelleria. Am. J. Sci. 27, 131–150. Watras, C.J., Bloom, N.S., Hudson, R.J.M., Gherini, S., Munson, R., Claas, S.A., Morrison, K.A., Hurley, J.,Wiener, J.G., Fitzgerald,W.F.,Mason, R., Vandal, G., Powell, D., Rada, R., Rislov, L., Winfrey, M., Elder, J., Krabbenhoft, D., Andren, A.W., Babiarz, C., Porcella, D.B., Huckabee, J.W., 1994. Sources and fates of mercury and methylmercury inWisconsin lakes. In:Watras, C., Huckabee, J. (Eds.),Mercury Pollution: Integration and Synthesis. Lewis Publishers, Ann Arbor, MI, pp. 153–177. chapter I.12. WHO, 1993. WHO Guidelines for Drinking Water Quality. http://www.who.int/ water_sanitation_health/GDWQ/index.htlmen
dc.description.obiettivoSpecifico4.5. Studi sul degassamento naturale e sui gas petroliferien
dc.description.journalTypeJCR Journalen
dc.description.fulltextreserveden
dc.contributor.authorBagnato, E.en
dc.contributor.authorAiuppa, A.en
dc.contributor.authorParello, F.en
dc.contributor.authorD'Alessandro, W.en
dc.contributor.authorAllard, P.en
dc.contributor.authorCalabrese, S.en
dc.contributor.departmentDipartimento CFTA, Università di Palermo, Via Archirafi 36, 90123 Palermo, Italyen
dc.contributor.departmentDipartimento CFTA, Università di Palermo, Via Archirafi 36, 90123 Palermo, Italy; INGV, Sezione di Palermo, Via La malfa 153, Palermo, Italyen
dc.contributor.departmentIstituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italiaen
dc.contributor.departmentLaboratoire Pierre Sue, CNRS-CEA, CE-Saclay, 91191 Gif/Yvette, Franceen
dc.contributor.departmentDipartimento CFTA, Università di Palermo, Via Archirafi 36, 90123 Palermo, Italyen
item.grantfulltextrestricted-
item.languageiso639-1en-
item.fulltextWith Fulltext-
item.openairetypearticle-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
crisitem.classification.parent04. Solid Earth-
crisitem.author.deptIstituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione OV, Napoli, Italia-
crisitem.author.deptIstituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Palermo, Palermo, Italia-
crisitem.author.deptUniversità di Palermo, DiSTeM, Italy-
crisitem.author.deptIstituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Palermo, Palermo, Italia-
crisitem.author.deptIstituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione OE, Catania, Italia-
crisitem.author.deptDipartimento C.F.T.A., Palermo University, Palermo/Italy-
crisitem.author.orcid0000-0003-2285-0842-
crisitem.author.orcid0000-0002-0254-6539-
crisitem.author.orcid0000-0003-1724-0388-
crisitem.author.orcid0000-0001-7836-3117-
crisitem.author.orcid0000-0003-0249-6663-
crisitem.author.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
crisitem.author.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
crisitem.author.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
crisitem.author.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
crisitem.department.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
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