Please use this identifier to cite or link to this item:
http://hdl.handle.net/2122/12154
Authors: | Fedele, Alessandro* Pedone, Maria* Moretti, Roberto* Wiersberg, Thomas* Somma, Renato* Troise, Claudia* De Natale, Giuseppe* |
Title: | Real-time quadrupole mass spectrometry of hydrothermal gases from the unstable Pisciarelli fumaroles (Campi Flegrei): Trends, challenges and processes | Journal: | International Journal of Mass Spectrometry | Series/Report no.: | /415 (2017) | Issue Date: | 2017 | DOI: | 10.1016/j.ijms.2017.02.006 | Abstract: | Volcanic gas sampling and post-collection chemical determination in a laboratory may preclude anyreal-time continuous monitoring of volcanic activity. We describe the development, and show the advan-tages, of a system used for the continuous monitoring of fumarolic gases discharged from the Pisciarellisite (Campi Flegrei, Southern Italy) based on a commercial quadrupole mass spectrometer (QMS-301OmnistarTM). Although numerous technical problems were addressed due to the ephemeral nature ofthe emission point and the harsh environment, we also report measurements of the chemical composi-tion of the major gas species emitted from the fumarole for two different periods (in 2009 and 2012). TheCO2/H2S, H2S/H2, He/CO2and CH4/CO2molar ratios were investigated in order to detect magmatic and/orhydrothermal components in the system, while the N2/O2ratio was adopted to infer other non-volcanicprocesses, such as air contamination and mixing with polluted surface waters. The presented method-ology allows continuous gas sampling and provides the first evidence of short-term gas variations notavailable by direct sampling, which is often impractical and hazardous. Compared to the current tech-niques that are used worldwide for the full characterization of gaseous emissions, i.e. chemical analysis oftraditional soda-filled under-vacuum bottles and MultiGAS surveys (laboratory-based and in situ, respec-tively), QMS-based monitoring is complementary and, in prospect, an alternative. With our method, thegeochemical monitoring benefits of the real-time analysis for high sampling rates that can be made com-parable to the continuous measurements of geophysical networks. This allows a better understandingof hydrothermal features, particularly of chemical fluctuations occurring on the very short-term, whichis fundamental for the evaluation of the evolution of unrest episodes at Campi Flegrei, one of the mosthazardous volcanic areas in the world. |
Appears in Collections: | Article published / in press |
Files in This Item:
File | Description | Size | Format | Existing users please Login |
---|---|---|---|---|
Real-time quadrupole mass spectrometry of hydrothermal gases fromthe unstable Pisciarelli fumaroles (Campi Flegrei) Trends challengesand processes.pdf | 2.6 MB | Adobe PDF |
WEB OF SCIENCETM
Citations
50
6
checked on Feb 10, 2021
Page view(s)
233
checked on Apr 17, 2024
Download(s)
1
checked on Apr 17, 2024