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Authors: Schito, Andrea* 
Corrado, Sveva* 
Trolese, Matteo* 
Aldega, Luca* 
Caricchi, Chiara* 
Cirilli, Simonetta* 
Grigo, Domenico* 
Guedes, Alexandra* 
Romano, Claudia* 
Spina, Amalia* 
Valentim, Bruno* 
Title: Assessment of thermal evolution of Paleozoic successions of the Holy Cross Mountains (Poland)
Issue Date: 2017
Series/Report no.: /80(2017)
DOI: 10.1016/j.marpetgeo.2016.11.016
Keywords: Paleozoic source rocks
Thermal maturity
Vitrinite and organoclast reflectance
Clay mineralogy
Raman spectroscopy
Palynomorph darkness index
Holy Cross Mountains
Subject Classification04.04. Geology 
Basin analysis
Thermal evolution
Abstract: Poland is considered the most prospective country for shale gas production in Europe. Hydrocarbon generation/expulsion scenarios, drawn in the latest intensive exploration phases, tend to overestimate maturation levels when compared with brand new data acquired after recent drillings. We tested an integrated workflow to correlate published and original thermal maturity datasets for the Paleozoic to Jurassic successions cropping out in the Holy Cross Mountains. These successions, when preserved in subsurface, host the major source rocks in the area. The application of the workflow allowed us to highlight the burial and thermal evolutionary scenarios of the two tectono-stratigraphic blocks of the Holy Cross Mountains (Łysog ory and Kielce blocks) and to propose this approach as a tool for reducing levels of uncertainty in thermal maturity assessment of Paleozoic successions worldwide. In particular, published datasets including colour alteration indexes of Paleozoic microfossils (conodont, acritarchs) and vitrinite and graptolite reflectance data, show differences in levels of thermal maturity for the Łysog ory (mid mature to overmature) and Kielce (immature to late mature) blocks. Original data, derived from optical analysis, pyrolysis, and Raman spectroscopy on kerogen, and X-Ray diffraction on finegrained sediments, mostly confirm and integrate published data distribution. 1D thermal models, constrained by these data, show burial and exhumation events of different magnitude, during the Late Cretaceous, for the Łysog ory (maximum burial depths of 9 km) and Kielce (burial depths of 6 km) blocks that have been related to the Holy Cross Fault polyphase activity. In the end, Palynomorph Darkness Index and Raman spectroscopy on kerogen, for Llandoverian and Cambrian rocks, turned out to be promising tools for assessing thermal maturity of Paleozoic organic facies devoid of vitrinite macerals.
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