Geology and petrochemistry of the recent (<25 ka) silicic volcanism at Pantelleria Island

Pantelleritic pumice fall on the northern slopes of M. Grande have built a complex sequence of interfingered deposits emitted by closely spaced eruptive vents which are frequently associated with dome-building phases and pantelleritic lavas flows. Field relationships allowed us to recognize eight eruptive units, all lying above the Montagna Grande trachytes.
As a whole, petrochemical characteristics of the erupted products indicate an evolutionary trend in which Na-clinopyroxene was the liquidus phase, followed by alkali feldspar. Amphibole and quartz are late-crystallizing, whereas aenigmatite is both early- and late-crystallizing as well. Aenigmatite and Na-clinopyroxene crystallization buffers efficiently the increase of agpaicity, induced by feldspar crystallization, to values of agpaitic index <2.0.
Some eruptions are characterized by distinctive mineral assemblages: the couple amphibole + aegirine occurs in the Fastuca tephra, whilst the fayalite + ilmenite + quartz association characterizes the Randazzo tephra. The Fastuca eruption, the most powerful among those studied, tapped a reservoir characterized by lower temperature and highly reducing conditions in comparison with the other eruptions. The frequent coexistence of Na-rich and Na-poor pyroxenes, may result from syn-eruptive mixing among variably evolved pantelleritic magmas. The occurrence of late-precipitated halite witnesses the exsolution of a Cl-rich brine during magma ascent.