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  5. Apparent magnetic polarity reversals due to remagnetization resulting from late diagenetic growth of greigite from siderite
 
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Apparent magnetic polarity reversals due to remagnetization resulting from late diagenetic growth of greigite from siderite

Author(s)
Sagnotti, L.  
Istituto Nazionale di Geofisica e Vulcanologia, Sezione Roma2, Roma, Italia  
Roberts, A. P.
School of Ocean and Earth Science, University of Southampton, Southampton Oceanography Centre, European Way, Southampton SO14 3ZH, UK
Weaver, R.
School of Ocean and Earth Science, University of Southampton, Southampton Oceanography Centre, European Way, Southampton SO14 3ZH, UK
Verosub, K. L.
Department of Geology, University of California, Davis, CA 95616, USA
Florindo, F.  
Istituto Nazionale di Geofisica e Vulcanologia, Sezione Roma2, Roma, Italia  
Pike, C. R.
3Department of Geology, University of California, Davis, CA 95616, USA
Clayton, T.
School of Ocean and Earth Science, University of Southampton, Southampton Oceanography Centre, European Way, Southampton SO14 3ZH, UK
Wilson, G. S.
Department of Geology, University of Otago, Dunedin, New Zealand
Language
English
Obiettivo Specifico
2.2. Laboratorio di paleomagnetismo
Status
Published
JCR Journal
JCR Journal
Peer review journal
Yes
Journal
Geophysical Journal International  
Issue/vol(year)
1 / 160 (2005)
Publisher
Blackwell Publishing
Pages (printed)
89-100
Date Issued
January 2005
DOI
10.1111/j.1365-246X.2005.02485.x
URI
https://www.earth-prints.org/handle/2122/3992
Subjects
04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism  
04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism  
Subjects

Antarctica

diagenesis

greigite

iron carbonate

iron sulphide

remagnetization

siderite

Abstract
A mixed-polarity zone, representing alternations between remagnetized and non-remagnetized strata, has been documented within the lower few metres of the CRP-1 core (Ross Sea, Antarctica). Detailed rock magnetic investigation of this interval indicates that the normal polarity
remagnetization is carried by magnetostatically interacting single-domain particles of a ferrimagnetic iron sulphide mineral, while the reversed-polarity magnetization of non-remagnetized
strata is carried by magnetite with a broad range of grain sizes and negligible magnetostatic interactions. Scanning electron microscope observations of polished sections indicate that the ferrimagnetic iron sulphide mineral is greigite (Fe3S4). Based on microtextural relationships, it is not possible to determine the relative timing of formation for much of the greigite. However,
a significant proportion of the greigite has grown on the surface of authigenic siderite (FeCO3) grains that occur as microconcretions and as cement surrounding detrital matrix grains. In such cases, microtextural relationships indicate that siderite post-dates early diagenetic pyrite and that greigite post-dates the siderite. Siderite usually forms in environments with abundant
dissolved iron and carbonate, but without dissolved pore water H2S. This set of geochemical conditions occurs in methanic settings below the sulphate reduction zone (in which early diagenetic pyrite forms).We interpret the observed remagnetization of the lower part of the CRP-1 core as due to a late diagenetic pore water migration event where abundant iron on the surface of siderite grains reacted with fluids containing limited dissolved sulphide, thereby causing
precipitation of greigite. The distribution of siderite (and associated greigite) in the lower part of the CRP-1 core is patchy, which accounts for the apparent alternation of polarities. This study is part of a growing catalogue of remagnetizations involving greigite, which suggests that occurrences of greigite should be treated with caution in palaeomagnetic and environmental magnetic studies.
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