Geochemistry of the Phlegraean Fields (Italy) proximal sources for major Mediterranean tephras: Implications for the dispersal of Plinian and co-ignimbritic components of explosive eruptions

Volcanic activity at Phlegraean Fields, Italy, produced several major marker tephras over a 50 ka period. The caldera
forming eruptions of the Campanian Ignimbrite (CI) and Neapolitan Yellow Tuff (NYT) are of particular importance for
tephrostratigraphy in Europe. Other key eruptions from this source include the Pomici Principali (PP) and the Tufi Biancastri
eruptions. We combine analyses of fresh glasses from proximal locations (i.e., juvenile clasts in proximal flow and fall deposits)
with data for key tephra layers from Lago Grande di Monticchio, 120 km to the east. The micron-beam major (EMPA)
and trace (LA-ICP-MS) element glass dataset allows us to: (a) distinguish between tephra units produced from the Phlegraean
Fields before and during the CI eruption (CI-series), and before and during the NYT and PP eruptions (NYT-series/PP); (b)
discriminate between the CI and the geochemically similar Pre-CI pyroclastic deposits; (c) separate the NYT from Pre-NYT
tephra units, although both major and trace elements do show significant overlap. The complex compositional overlap
between Pre-NYT tephras may present a problem for tephra correlations in the 14–39 ka time window and may have resulted
in incorrect proximal–distal and distal–distal correlations. The diagnostic chemical criteria detailed herein permits more accurate
matching of distal tephras with their proximal equivalents and hence will improve chronostratigraphy of distal settings
and give insight into tephra dispersal. We show that the dispersal of PP tephra was more limited than previously thought. The
surge/fall (Lower Member) and subsequent pyroclastic density current (Upper Member) phases of the NYT eruption can be
recognised in distal settings. Both the NYT Lower and Upper Members are found in distal localities to the east of the Phlegraean
Fields, however the Lower Member is found in the absence of the Upper Member in locations to the far north of Phlegraean
Fields. Chemical compositions of the Plinian and ignimbrite phases of the CI eruption overlap extensively, but can be
distinguished on a plot of Zr–Th.