McKay, Robert

We present a full characterization of a 20 cm-thick tephra layer found intercalated in the marine sediments recovered at Site U1524 during International Ocean Discovery Program (IODP) Expedition 374, in the Ross Sea, Antarctica. Tephra bedforms, mineral paragenesis, and major- and trace element composition on individual glass shards were investigated and the tephra age was constrained by 40Ar-39Ar on sanidine crystals. The 40Ar-39Ar data indicate that sanidine grains are variably contaminated by excess Ar, with the best age estimate of 1.282 ± 0.012 Ma, based on both single-grain total fusion analyses and step-heating experiments on multi-grain aliquots. The tephra is characterized by a very homogeneous rhyolitic composition and a peculiar mineral assemblage, dominated by sanidine, quartz, and minor aenigmatite and arfvedsonite-riebeckite amphiboles. The tephra from Site U1524 compositionally matches with a ca. 1.3 Ma, rhyolitic pumice fall deposit on the rim of the Chang Peak volcano summit caldera, in the Marie Byrd Land, located ca. 1,300 km from Site U1524. This contribution offers important volcanological data on the eruptive history of Chang Peak volcano and adds a new tephrochronologic marker for the dating, correlation, and synchronization of marine and continental early Pleistocene records of West Antarctica.

Water masses and depositional environments over the last 500 ka were reconstructed using absolute and relative abundances of lithogenous, biogenous and redox-sensitive elements in four sediment cores from two channel-levee systems of the Wilkes Land continental slope (East Antarctica). Sediments older than the Mid-Bruhnes event (MBE, 430 ka BP) show reduced glacial/interglacial variability in the abundance of elements associated to the terrigenous mineral phases (i.e. Al, Ti, Fe and partly Si). This suggests minor ice-sheet size changes occurred in the Antarctic margin during the pre-MBE “lukewarm” interval. Post-MBE sediments record instead a high variability between glacial and interglacial periods in the concentration of terrigenous and biogenous (i.e. Ca, Ba) elements suggesting larger amplitude changes in both ice-sheet size and ocean conditions toward the gradual establishment of last glacial cycle conditions. Moreover, a marked increase of Mn during the glacial to interglacial transitions, indicates a post-depositional migration of the redox front and re-oxidation of the surface sediment layers linked to major changes in bottom water oxygen conditions associated to Antarctic Bottom Water formation along the margin at the onset of deglaciations.

Deep sea geological records indicate that Antarctic ice-sheet growth and decay is strongly influenced by the Earth's astronomical variations (known as Milankovitch cycles), and that the frequency of the glacial-interglacial cycles changes through time. Here we examine the emergence of a strong obliquity (axial tilt) control on Antarctic ice-sheet evolution during the Miocene by correlating the Antarctic margin geological records from 34 to 5 million years ago with a measure of obliquity sensitivity that compares the variance in deep sea sediment core oxygen-isotope data at obliquity timescales with variance of the calculated obliquity forcing. Our analysis reveals distinct phases of ice-sheet evolution and suggests the sensitivity to obliquity forcing increases when ice-sheet margins extend into marine environments. We propose that this occurs because obliquity-driven changes in the meridional temperature gradient affect the position and strength of the circum-Antarctic easterly flow and enhance (or reduce) ocean heat transport across the Antarctic continental margin. The influence of obliquity-driven changes in ocean dynamics is amplified when marine ice sheets are extensive, and sea ice is limited. Our reconstruction of the Antarctic ice-sheet history suggests that if sea-ice cover decreases in the coming decades, ocean-driven melting at the ice-sheet margin will be amplified.

Geological records from the Antarctic margin offer direct evidence of environmental variability at high southern latitudes and provide insight regarding ice sheet sensitivity to past climate change. The early to mid-Miocene (23-14 Mya) is a compelling interval to study as global temperatures and atmospheric CO2 concentrations were similar to those projected for coming centuries. Importantly, this time interval includes the Miocene Climatic Optimum, a period of global warmth during which average surface temperatures were 3-4 °C higher than today. Miocene sediments in the ANDRILL-2A drill core from the Western Ross Sea, Antarctica, indicate that the Antarctic ice sheet (AIS) was highly variable through this key time interval. A multiproxy dataset derived from the core identifies four distinct environmental motifs based on changes in sedimentary facies, fossil assemblages, geochemistry, and paleotemperature. Four major disconformities in the drill core coincide with regional seismic discontinuities and reflect transient expansion of grounded ice across the Ross Sea. They correlate with major positive shifts in benthic oxygen isotope records and generally coincide with intervals when atmospheric CO2 concentrations were at or below preindustrial levels (∼280 ppm). Five intervals reflect ice sheet minima and air temperatures warm enough for substantial ice mass loss during episodes of high (∼500 ppm) atmospheric CO2 These new drill core data and associated ice sheet modeling experiments indicate that polar climate and the AIS were highly sensitive to relatively small changes in atmospheric CO2 during the early to mid-Miocene.

Stratigraphic drilling from the McMurdo Ice Shelf in the 2006/2007 austral summer recovered a 1284.87 m sedimentary succession from beneath the sea floor. Key age data for the core include magnetic polarity stratigraphy for the entire succession, diatom biostratigraphy for the upper 600 m and 40Ar/39Ar ages for in-situ volcanic deposits as well as reworked volcanic clasts. A vertical seismic profile for the drill hole allows correlation between the drill hole and a regional seismic network and inference of age constraint by correlation with well‐dated regional volcanic events through direct recognition of interlayered volcanic deposits as well as by inference from flexural loading of pre‐existing strata. The combined age model implies relatively rapid (1 m/2–5 ky) accumulation of sediment punctuated by hiatuses, which account for approximately 50% of the record. Three of the longer hiatuses coincide with basin‐wide seismic reflectors and, along with two thick volcanic intervals, they subdivide the succession into seven chronostratigraphic intervals with characteristic facies: 1. The base of the cored succession (1275–1220 mbsf) comprises middle Miocene volcaniclastic sandstone dated at approx 13.5 Ma by several reworked volcanic clasts; 2. A late-Miocene sub-polar orbitally controlled glacial–interglacial succession (1220–760 mbsf) bounded by two unconformities correlated with basin‐wide reflectors associated with early development of the terror rift; 3. A late Miocene volcanigenic succession (760–596 mbsf) terminating with a ~1 my hiatus at 596.35 mbsf which spans the Miocene–Pliocene boundary and is not recognised in regional seismic data; 4. An early Pliocene obliquity-controlled alternating diamictite and diatomite glacial–interglacial succession(590–440 mbsf), separated from; 5. A late Pliocene obliquity-controlled alternating diamictite and diatomite glacial–interglacial succession (440–150 mbsf) by a 750 ky unconformity interpreted to represent a major sequence boundary at other locations; 6. An early Pleistocene interbedded volcanic, diamictite and diatomite succession (150–80 mbsf), and; 7. A late Pleistocene glacigene succession (80–0 mbsf) comprising diamictite dominated sedimentary cycles deposited in a polar environment.

Thirty years after oxygen isotope records frommicrofossils deposited in ocean sediments confirmed the hypothesis that variations in the Earth’s orbital geometry control the ice ages1, fundamental questions remain over the response of the Antarctic ice sheets to orbital cycles2. Furthermore, an understanding of the behaviour of the marine-based West Antarctic ice sheet (WAIS) during the ‘warmer-than- present’ early-Pliocene epoch (̃5–3Myr ago) is needed to better constrain the possible range of ice-sheet behaviour in the context of future global warming3. Here we present a marine glacial record from the upper 600 m of theAND-1B sediment core recovered from beneath the northwest part of the Ross ice shelf by the ANDRILL programme and demonstrate well-dated, ̃40-kyr cyclic variations in ice-sheet extent linked to cycles in insolation influenced by changes in the Earth’s axial tilt (obliquity) during the Pliocene. Our data provide direct evidence for orbitally induced oscillations in the WAIS, which periodically collapsed, resulting in a switch from grounded ice, or ice shelves, to open waters in the Ross embayment when planetary temperatures were up to ̃3 C warmer than today4 and atmospheric CO2 concentration was as high as ̃400 p.p.m.v. (refs 5, 6). The evidence is consistent with a new ice-sheet/ice-shelf model7 that simulates fluctuations in Antarctic ice volume of up to + 7 m in equivalent sea level associated with the loss of the WAIS and up to +3 m in equivalent sea level from the EastAntarctic ice sheet, in response to ocean-induced melting paced by obliquity.During interglacial times, diatomaceous sediments indicate high surface-water productivity, minimal summer sea ice and air temperatures above freezing, suggesting an additional influence of surface melt8 under conditions of elevated CO2.

This section reports preliminary data and results on petrology and geochemistry of AND-1B core

Chronostratigraphic data available for the preliminary age model for the upper 700 m for the AND-1B drill core include diatom biostratigraphy, magnetostratigraphy, 40Ar/39Ar ages on volcanic material, 87Sr/86Sr ages on calcareous fossil material, and surfaces of erosion identified from physical appearance and facies relationships recognised in the AND-1B drill core. The available age data allow a relatively well-constrained age model to be constructed for the upper 700 m of the drill core. Available diatom biostratigraphic constraints and 40Ar/39Ar ages allow a unique correlation of ~70% of the AND-1B magnetic polarity stratigraphy with the Geomagnetic Polar Time Scale (GPTS). Unique correlation is not possible in several coarse diamictite intervals with closely spaced glacial surfaces of erosion and sparse microflora. However, the age model indicates relatively rapid (up to 1 m/k.y.) and continuous accumulation of intervening finer grained diatomaceous intervals punctuated by several half- to million-years hiatuses representing more than half of the last 7 m.y. in the AND-1B record. The mid- to late Pleistocene is represented by superimposed diamictite units separated from upper Pliocene alternating diamictites/diatomites by a ~1 m.y. hiatus co-incident with a regionally correlated seismic reflection surface. A c. 100 m-thick diatomite represents a significant portion of the early Pliocene record in the AND-1B drill core. Strata below ~620 m are late Miocene in age; however, biostratigraphic constraints are absent below 586 m and correlation with the GPTS is relatively unconstrained. At the the of writing, the only chronostratigraphic data available below 700 mbsf include three 40Ar/39Ar ages on volcanic clasts from near 1280 mbsf affording a maximum depositional age of 13.57 Ma for the base of the AND-1B drill core.