Sincrotrone Trieste S.C.p.A., Basovizza, Trieste, Italy

In the texture analysis of volcanic rocks, the preferred orientation of the constituents can provide useful information for the interpretation of the processes involved in the rock formation. We present here a new data analysis technique, based on X-ray microtomography measurements and on shape preferred orientation analysis, to obtain the orientation distribution functions of the constituents of volcanic rocks. This procedure proved to be very suitable for volcanic samples, where diffraction-based techniques, developed for crystallographic preferred orientation studies, are of limited utilization, in addition to the fact that they cannot provide any information about vesicles or bubbles. Moreover the analysis performed directly in three dimensions (3D) overcomes the problems that usually occur when employing stereological methods for the analysis of the images obtained via microscopy-based techniques. In this study, two scoriae (from Stromboli and Etna) and a tube pumice (from Campi Flegrei) were measured via X-ray microtomography and then the resulting volumes were analyzed following the proposed procedure. Results highlight little preferred orientation for the vesicles in the two scoria samples, whereas the pumice shows a marked preferred orientation. Crystals (also divided by mineral species) were taken into account as well and in the two scoria samples there is no crystal preferred orientation, in contrast with the pumice, where crystal preferred orientation features are very similar to the ones found for the vesicles. Overall we found strong differences in preferred orientation: weak for vesicles in scoriae, showing an axial symmetry with the axis parallel to the elongation axis of the sample, and a stronger and more complex orientation texture in the pumice sample for both crystals and vesicles. The promising results obtained suggest that this procedure is potentially very useful for the analysis of preferred orientation in volcanic rocks and geomaterials in general.

X-ray computed microtomography is an excellent tool for the three-dimensional analysis of rock microstructure. Digital images are acquired, visualized, and processed to identify and measure several discrete features and constituents of rock samples, by means of mathematical algorithms and computational methods. In this paper, we present digital images of volcanic rocks collected with X-ray computed microtomography techniques and studied by means of a software library, called Pore3D, custom-implemented at the Elettra Synchrotron Light Laboratory of Trieste (Italy). Using the Pore3D software, we analyzed the fabrics and we quantified the characteristics of the main constituents (vesicles, crystals, and glassy matrix) of four different types of pyroclasts: frothy pumice, tube pumice, scoria, and “crystalline” scoria. We identified the distinctive features of these different types of volcanic rocks. The frothy pumices show vesicles that coalesce in isotropic aggregates, especially toward the sample interior, while the scoriae have a low porosity and an abundance of isolated vesicles. In the “crystalline” scoria sample most of the vesicle separation is due to the presence of crystals of different types, while the tube pumice shows an anisotropic distribution of vesicles and crystals at the microscale, as also observed at the scale of the hand sample. Quantitative analysis and textural information may supply an additional tool to investigate the eruptive processes and the origin of volcanic rocks.