Università La Sapienza Roma

In this paper, a sensitivity analysis and procedure development for volcanic-plume sulfur dioxide and ash retrievals using ground thermal infrared camera have been carried out. The semiconductor device camera, considered as a reference, has a spectral range of 8–14 μm with noise equivalent temperature difference that is better than 100 mK at 300 K. The camera will be used to monitor and assess the hazards of Mt. Etna volcano to mitigate the risk and impact of volcanic eruptions on the civil society and transports. A minimum number of filters have been selected for sulfur dioxide (SO2) and volcanic ash retrievals. The sensitivity study has been carried out to determine the SO2 and volcanic ash minimum concentration detectable by the system varying the camera geometry and the atmospheric profiles. Results show a meaningful sensitivity increase considering high instrument altitudes and low camera-elevation angles. For all geometry configurations and monthly profiles, the sensitivity limit varies between 0.5 and 2 g · m−2 for SO2 columnar abundance and between 0.02 and 1 for ash optical depth. Two procedures to detect SO2 and ash, based on the least square fit method and on the brightness temperature difference (BTD) algorithm, respectively, have also been proposed. Results show that high concentration of atmospheric water vapor columnar content significantly reduces the ash-plume effect on the BTD. A water vapor-correction procedure introduced improves the ash retrievals and the cloud discrimination in every season, considering all the camera geometries.

A retrieval of tropospheric volcanic ash from Mt Etna has been carried out, using measurements from the Moderate Resolution Imaging Spectroradiometer (MODIS). The NASA-MODIS satellite instrument acquires images in the 0.4 to 14 μm spectral range with a spatial resolution of 1 km at nadir. The eruption which occurred on 24 November 2006 is considered as a test case in this work. In order to derive the ash plume optical thickness, the particle effective radius and the total mass, the Brightness Temperature Difference procedure has been applied to MODIS channels 31 (centered at 11 μm) and 32 (centered at 12 μm). Channel 5 (centered at 1.24 μm) has been used to refine the cloud discrimination, exploiting the distinct reflectivity of meteorological and volcanic clouds in the near infrared spectral range. The detection of volcanic ash pixels has been significantly improved by applying an atmospheric water vapor correction to MODIS data. This procedure doubles the number of pixels identified as containing volcanic ash compared to the original method. The retrieved mean ash optical thickness at 0.55 μm, mean particle effective radius and the total ash mass in the plume are 0.4, 3.5 μm and 3620 tons, respectively. A detailed sensitivity analysis has been carried out to investigate errors in the retrieval caused by the uncertainty in various parameters: surface temperature and emissivity, plume geometry (altitude and thickness), ash type and atmospheric water vapor. Results show that the largest contributions to retrieval errors are from uncertainty in surface parameters, aerosol type and atmospheric water vapor. The total tropospheric volcanic ash retrieval errors are estimated to be 30%, 30% and 40% for mean AOT, mean effective radius and total mass retrieval, respectively.

We present the results of laboratory experiments on the aggregation and disaggregation of colliding volcanic ash particles. Ash particles of different composition and size <90 µm were held in turbulent suspension and filmed in high speed while colliding, aggregating, and disaggregating, forming a growing layer of electrostatically bound particles along a vertical plate. At room conditions and regardless of composition, 60–80% of the colliding particles smaller than 32 µm remained aggregated. In contrast, aggregation of particles larger than 63 µm was negligible, and, when a layer formed, periods when disaggregation (mainly by collisions or drag) exceeded aggregation occurred twice as frequently than for smaller particles. An empirical relationship linking the aggregation index, i.e., the effective fraction of aggregated particles surviving disaggregation, to the mean particle collision kinetic energy is provided. Our results have potential implications on the dynamics of volcanic plumes and ash mobility in the environment.

The mineralogy of thermometamorphic granites is relatively simple, making it possible to track the spatial distribution of chemical and mineralogical variations in these rocks and investigate the processes that underpin these metamorphic reactions.We have undertaken a detailed investigation of metagranites from the contact aureole that fringes a quartz diorite intrusion of Late Permian age, emplaced into Carboniferous peraluminous granites of the Gennargentu Igneous Complex (Sardinia, Italy). New data are presented including the petrography of metagranites within a 500 m zone adjacent to the quartz diorite intrusion, the compositions of minerals and bulk-rocks, and the oxygen isotope compositions of separated minerals. We have used these data to assess the mobility of elements, expressed as oxide, in the aureole, and the physical conditions of fluid-assisted thermometamorphism. Modal variations and the oscillatory zoning of plagioclase demonstrate that the shallow (P 200MPa) quartz diorite intrusion was emplaced through a number of magmatic injections.The border zone of the quartz diorite intrusion presents evidence of two main processes: hybridization between andesite and rhyolite magmas and volatile saturation of the mingled magma. Modal differences in the contact zone with respect to the protolith (i.e. peraluminous granite), variations in mineral composition, temperature constraints and K2O, Na2O, SiO2 and Al2O3 indicate that a relatively large volume of the host granite (up to 400 m from the contact) was metasomatized by high-temperature (650^3508C) fluids derived from the mingled zone of the quartz diorite intrusion. In detail, the metasomatic K2O-rich fluid reacted with albite to form K-feldspar, and triggered the recrystallization of quartz and plagioclase to higher calcium concentrations. The progressive increase in the MgO/(MgOþFeO) of chlorite closer to the contact indicates that this phase also recrystallized. The iron released during chlorite recrystallization was buffered by hematite formation in the pores of metasomatic K-feldspar. The Gennargentu metagranites provide evidence that metasomatic fluids can play a major role in driving metamorphic reactions in contact aureoles. For instance, the expected increase of Ca in plagioclase owing to thermal equilibration was not achieved in the high-T zone of the aureole because of fluid-assisted removal of cations.We conclude that caution should be taken when interpreting the processes that underpin contact metamorphism in terms of thermally driven, ionic diffusion alone, because the role of fluids may be significant, if not overwhelming, in the domains closest to the magmatic source.