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Please use this identifier to cite or link to this item: http://hdl.handle.net/2122/7573

Authors: Dallai, L.*
Cioni, R.*
Boschi, C.*
D'Oriano, C.*
Title: Carbonate-derived CO2 purging magma at depth: Influence on the eruptive activity of Somma-Vesuvius, Italy
Title of journal: Earth and Planetary Science Letters
Series/Report no.: 1-2/310(2011)
Publisher: Elsevier
Issue Date: 1-Oct-2011
DOI: 10.1016/j.epsl.2011.07.013
URL: http://www.sciencedirect.com/science/article/pii/S0012821X11004298
Keywords: stable-isotope
magma geochemistry
CO2-degassing
Vesuvius
Abstract: Mafic phenocrysts from selected products of the last 4 ka volcanic activity at Mt. Vesuvius were investigated for their chemical and O-isotope composition, as a proxy for primary magmas feeding the system. 18O/16O ratios of studied Mg-rich olivines suggest that near-primary shoshonitic to tephritic melts experienced a flux of sedimentary carbonate-derived CO2, representing the early process of magma contamination in the roots of the volcanic structure. Bulk carbonate assimilation (physical digestion) mainly occurred in the shallow crust, strongly influencing magma chamber evolution. On a petrological and geochemical basis the effects of bulk sedimentary carbonate digestion on the chemical composition of the near-primary melts are resolved from those of carbonate-released CO2 fluxed into magma. An important outcome of this process lies in the effect of external CO2 in changing the overall volatile solubility of the magma, enhancing the ability of Vesuvius mafic magmas to rapidly rise and explosively erupt at the surface.
Appears in Collections:04.08.03. Magmas
04.08.05. Volcanic rocks
Papers Published / Papers in press

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