Earth-prints repository, logo   DSpace

About DSpace Software
|earth-prints home page | roma library | bologna library | catania library | milano library | napoli library | palermo library
Please use this identifier to cite or link to this item:

Authors: Zambardi, T.*
Sonke, J. E.*
Toutain, J. P.*
Sortino, F.*
Shinohara, H.*
Title: Mercury emissions and stable isotopic compositions at Vulcano Island (Italy)
Title of journal: Earth and Planetary Science Letters
Series/Report no.: 1-2/277 (2009)
Publisher: ELSEVIER
Issue Date: Jan-2009
DOI: 10.1016/j.epsl.2008.10.023
Keywords: mercury
Abstract: Sampling and analyses methods for determining the stable isotopic compositions of Hg in an active volcanic system were tested and optimized at the volcanic complex of Vulcano (Aeolian Islands, Italy). Condensed gaseous fumarole Hg(fum) T , plume gaseous elemental Hg(g) 0 and plume particulate Hg(p) II were obtained at fumaroles F0, F5, F11, and FA. The average total Hg emissions, based on HgT/SO2 in condensed fumarolic gases and plumes, range from 2.5 to 10.1 kg y−1, in agreement with published values [Ferrara, R., Mazzolai, B., Lanzillotta, E., Nucaro, E., Pirrone, N., 2000. Volcanoes as emission sources of atmospheric mercury in the Mediterranean Basin. Sci. Total Environ. 259(1–3), 115–121; Aiuppa, A., Bagnato, E., Witt, M.L.I., Mather, T.A., Parello, F., Pyle, D.M., Martin, R.S., 2007. Real-time simultaneous detection of volcanic Hg and SO2 at La Fossa Crater, Vulcano (Aeolian Islands, Sicily). Geophys. Res. Lett. 34(L21307).]. Plume Hg(p) II increases with distance from the fumarole vent, at the expense of Hg(g) 0 and indicates significant in-plume oxidation and condensation of fumarole Hg(fum) T . Relative to the NIST SRM3133 Hg standard, the stable isotopic compositions of Hg are δ202Hg(fum) T =−0.74‰±0.18 (2SD, n=4) for condensed gaseous fumarole Hg(fum) T , δ202Hg(g) 0 =−1.74‰±0.36 (2SD, n=1) for plume gaseous elemental Hg(g) 0 at the F0 fumarole, and δ202Hg(p) II =−0.11‰±0.18 (2SD, n=4) for plume particulate Hg(p) II . The enrichment of Hg(p) II in the heavy isotopes and Hg(g) 0 in the light isotopes relative to the total condensed fumarolic Hg(fum) T gas complements the speciation data and demonstrates a gas-particle fractionation occurring after the gas expulsion inambient T° atmosphere. A first order Rayleigh equilibriumcondensation isotope fractionation model yields a fractionation factor αcond-gas of 1.00135±0.00058.
Appears in Collections:05.02.01. Geochemical data
Papers Published / Papers in press

Files in This Item:

File SizeFormatVisibility
HgVulcano.pdf496.67 kBAdobe PDFView/Open

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Share this record




Stumble it!



Valid XHTML 1.0! ICT Support, development & maintenance are provided by CINECA. Powered on DSpace Software. CINECA