Please use this identifier to cite or link to this item: http://hdl.handle.net/2122/5191
AuthorsBagnato, E.* 
Allard, P.* 
Parello, F.* 
Aiuppa, A.* 
Calabrese, S.* 
Hammouya, G.* 
TitleMercury gas emissions from La Soufrière Volcano, Guadeloupe Island (Lesser Antilles)
Issue Date2009
Series/Report no.3-4/266(2009)
DOI10.1016/j.chemgeo.2009.06.011
URIhttp://hdl.handle.net/2122/5191
KeywordsMercury
Fumaroles
Volcanic plume
Trace metals
Gaseous and particulate mercury
Emission rate
Subject Classification01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects 
04. Solid Earth::04.08. Volcanology::04.08.01. Gases 
04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring 
AbstractQuantifying mercury (Hg) emissions from active volcanoes is of particular interest for better constraining the global cycle and environmental impact of this highly toxic element. Here we report on the abundance of total gaseous (TGM=Hg0 (g)+HgII (g)) and particulate (Hg(p)) mercury in the summit gas emissions of La Soufrière andesitic volcano (Guadeloupe island, Lesser Antilles), where enhanced degassing of mixed hydrothermalmagmatic volatiles has been occurring since 1992 from the Southern summit crater.We demonstrate that Hg in volcanic plume occurs predominantly as gaseous mercury, with a mean TGM/Hg(p) mass ratio of ~63. Combining the mean TGM/H2S mass ratio of the volcanic plume (~3.2×10−6), measured close to the source vent, with the H2S plume flux (~0.7 t d−1), determined simultaneously, allows us to estimate a gaseous mercury emission rate of 0.8 kg yr−1 from La Soufrière summit dome. Somewhat lower TGM/Stot mass ratio in fumarolic gases from the source vent (4.4×10−7) suggests that plume chemical composition is not well represented by the emission source (fumaroles) due to chemical processes prior to (or upon) discharge. Current mercury emission from La Soufrìere volcano represents a very small contribution to the estimated global volcanic budget for this element.
Appears in Collections:Papers Published / Papers in press

Files in This Item:
File Description SizeFormat 
Bagnato et al. Chem.Geol_2009.pdfMain article919.32 kBAdobe PDFView/Open    Request a copy
Show full item record

Page view(s)

153
checked on Apr 26, 2017

Download(s)

24
checked on Apr 26, 2017

Google ScholarTM

Check

Altmetric