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Isotopic, chemical and dissolved gas constraints on spring water from Popocatepetl volcano (Mexico): evidence of gas–water interaction between magmatic component and shallow fluids
Author(s)
Language
English
Status
Published
Peer review journal
Yes
Title of the book
Issue/vol(year)
141(2005)
Publisher
Elsevier
Pages (printed)
91– 108
Issued date
2005
Alternative Location
Subjects
Abstract
Geochemical research was carried out on cold and hot springs at Popocatepetl (Popo) volcano (Mexico) in 1999 to identify a possible relationship with magmatic activity. The chemical and isotopic composition of the fluids is compatible with strong gas–water interaction between deep and shallow fluids. In fact, the isotopic composition of He and dissolved carbon species is consistent with a magmatic origin.
The presence of a geothermal system having a temperature of 80–1008 C was estimated on the basis of liquid geothermometers. A large amount of dissolved CO2 in the springs was also detected and associated with high CO2 degassing.
The presence of a geothermal system having a temperature of 80–1008 C was estimated on the basis of liquid geothermometers. A large amount of dissolved CO2 in the springs was also detected and associated with high CO2 degassing.
References
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Volcano. Appl. Geochem. 13 (7), 841–850.
Appelo, C.A.J., 1988. WATEQP program. Instituut Voor Aardwetenschappen,Vrije Universitei Amsterdam.
Capasso, G., Inguaggiato, S., 1998. A simple method for determination of dissolved gases in natural waters. An application to thermal waters from Vulcano Island. Appl. Geochem. 13 (5), 631–642.
Capasso, G., Favara, Inguaggiato, S., 1997. Chemical features and isotopic composition of gaseous manifestations on Vulcano Island (Aeolian Islands, Italy): an interpretative model of fluid
circulation. Geochim. Cosmoch. Acta 61 (16), 3425– 3440.
Capasso, G., Favara, R., Inguaggiato, S., 2000. Interaction between fumarolic gases and thermal groundwaters at Vulcano Island (Italy): evidences from chemical composition of dissolved gases
in waters. J. Volcanol. Geotherm. Res. 102 (3–4), 309–3180.
Capasso, G., D’Alessandro, W., Favara, R., Inguaggiato, S., Parello, F., 2001. Interaction between the deep fluids and the shallow groundwaters on the vulcano island (Italy). J. Volcanol. Geotherm. Res. 108 (1–4), 189–200.
Capasso, G., Carapezza, M.L., Federico, C., Inguaggiato, S., Rizzo, A., 2004. The 2002–2003 eruption at Stromboli volcano (Italy):
precursory changes in the carbon and helium isotopic composition of both fumarole gases and thermal waters. Bull. Volcanol. (in press).
Carapezza, M.L., Inguaggiato, S., Brusca, L., Longo, M., 2004. Geochemical precursors of the activity of an open-conduict volcano: Stromboli 2002–2003 eruptive events. Geophys. Res.
Lett. 31, L07620.
Cortes, A., Durazo, J., Farvolden, R., 1997. Studies of Isotopic hydrology of the basin of Mexico and vicinity: annotated bibliography and interpretation. J. Hydrol. 198, 346–376.
Chiodini, G., Frondini, F., Marini, L., 1995. Theoretical geothermometers and PCO2 indicators for aqueous solutions coming from hydrothermal systems of medium–low temperature hosted
in carbonate-evaporite rocks: application to the thermal springs of the Etruscan Swell, Italy. Appl. Geochem. 10, 337–346.
Chiodini, G., Cioni, R., Guidi, M., Magro, G., Marini, L., Raco, B., 2000. Gas chemistry of the lake Piccolo of Monticchio, Mt. Vulture, in December 1996. In: Villari, L. (Ed.), Data related to eruptive activity, unrest phenomena and other observations on the Italian active volcanoes 196: miscellaneous. Acta Vulcanologica,
vol. 12, pp. 139–142.
CNA (Commission Nacional de Agua), 2001. www.inegi.gob.mx.
Craig, H., 1961. Isotope variation in meteoric waters. Science 133,1702–1703.
Deines, P., Langmuir, D., Herman, R.S., 1974. Stable carbon isotope ratio and the esistence of a gas phase in the evolution of carbonate
groundwaters. Geochim. Cosmochim. Acta 38, 1147– 1164.
Delgado-Granados, H., Piedad Sanchez, N., Galvan, L., Julio, P., Alvarez, J.M., Cardenas, L., 1998. CO2 flux measurements at Popocatepetl volcano: II. Magnitude of emissions and significance
(abstract). EOS Trans., AGU 79 (45), 926 (Fall Meeting Suppl.).
Delgado-Granados, H., Cardenas Gonzalez, L., Piedad Sanchez, N., 2001. Sulfur dioxide emission rate, passively degassing erupting volcano. J. Volcanol. Geotherm. Res. 108, 107–120.
Dyck, W., 1976. The use of helium in mineral exploration. J. Geophys. Explor. 5, 3–20.
Favara, R., Grassa, F., Inguaggiato, S., Pecoraino, G., Capasso, G.,2002. A simple method to determine the d13C of total dissolved
inorganic carbon. Geofis. Int. 41 (3), 313–320.
Fournier, R.O., 1973. Silica in thermal waters: laboratory and field investigations. Proceedings, International Symposium on Hydrogeochemistry and Biogeochemistry, Tokyo. Clark, Washington, DC, vol. 1, pp. 122–129.
Giammanco, S., Inguaggiato, S., Valenza, M., 1998a. Soil and fumarole gases of Mount Etna: geochemistry and relations with volcanic activity. J. Volcanol. Geotherm. Res. 81, 297–310.
Giammanco, S., Gurrieri, S., Valenza, M., 1998b. Anomalous soil CO2 degassing in relation to faults and eruptive fissures on Mount Etna (Sicily, Italy). Bull. Volcanol. 60, 252–259.
Giggenbach, W.F., 1991. Isotopic composition of geothermal water and steam discharges. Application of Geochemistry in Geothermal
Reservoir Development. UNITAR, pp. 253–273
(F. D’Amore coordinator).
Goff, F., Janik, C.J., Delgado, H., Werner, C., Counce, D.,Stimac, J.A., Siebe, C., Love, S.P., Williams, S.N., Fischer, T., Johnson, L., 1980. Geochemical surveillance of magmatic volatiles at Popocatepetl volcano, Mexico. Geol. Soc. Am.
Bull. 110, 695–710.
Inguaggiato, S., Rizzo, A., 2004. Dissolved helium isotope ratio in ground-waters: a new technique based on gas–water reequilibration
and its application to Stromboli volcanic system.
Appl. Geochem. 19, 665–673.
Inguaggiato, S., Martin Del Pozzo, A.L., Aguayo, A., Garcia, E., Espinasa, R., Favara, R., Capasso, G., 1999. Popocatepetl volcano (Mexico): preliminary geochemical characterization of
volcanic fluids and comparison with Italian volcanic systems (Etna, Vulcano). Abstract book V32A-14, AGU Fall Meeting, San Francisco, December.
Inguaggiato, S., Pecoraino, G., D’Amore, F., 2000. Chemical and isotopical characterization of fluid manifestations of Ischia Island (Italy). J. Volcanol. Geotherm. Res. 99, 151–178.
Inguaggiato, S., Capasso, G., Favara, R., Martin Del Pozzo, A.L., Aguayo, A., 2001. Water–rock interaction processes at Popocatepetl volcano, Mexico. In: Rosa Cidu, A.A. (Ed.), Proceeding
of the Tenth International Symposium on "Water–rock Interaction",WRI-10/Villasimius/Italy/10–15 July 2001. Water Rock Interaction, vol. 2. Balkema Publishers, pp. 859–862.
Jahne, B., Heinz, G., Dietrich, W., 1987. Measurements of the diffusion coefficients of sparingly soluble gases in water. J. Geophys. Res. 92 (C-10), 10767–10776.
Jenne, E.A., Ball, J.W., Burchard, J.M., Vivit, D.V., Barks, J.H.,1980. Geochemical modeling: apparent solubility controls on Ba, Zn, Cd, Pb and F in waters of Missouri tri-State mining
area. In: Heniphill, D.D. (Ed.), Trace Substances in Environmental Health, vol. 14. University of Missouri, Columbia, pp. 353–361.
Langmuir, C.H., Vocke, R.D., Hanson, G.N., Hart, H.R., 1978. A general mixing equation with applications to Icelandic basalts. Gunter Faure–Principles of Isotope Geology, Earth Planet. Sci.
Lett., vol. 37. John Wiley and Sons, pp. 380–392.
Love, S.P., Goff, F., Counce, D., Siebe, C., Delgado, H., 1998. Passive infrared spectroscopy of the eruption plume at Popocatepetl volcano, Mexico. Nature 396, 563–567.
Marini, L., Chiodini, G., Cioni, R., 1986. New geothermometers for carbonate-evaporite geothermal reservoirs. Geothermics 15,
77–86.
Martin-Del Pozzo, A.L., Aceves, F., Espinasa, R., Aguayo, A., Butron, M.A., Inguaggiato, S., Morales, P., Cienfuegos, E., 2002a. Influence of volcanic activity on spring water chemistry
at Popocatepetl Volcano, Mexico. Chem. Geol. 190, 207–229.
Martin-Del Pozzo, A.L., Inguaggiato, S., Aceves, F., Saenz, H.,Aguayo, A., 2002b. Spring Water and CO2 interaction at Popocatepetl Volcano, Mexico. Geofis. Int. 41 (3), 345–351.
Marty, B., Jambon, A., 1987. C/3He in volatile fluxes from the solid earth: implications for carbon geodynamics. Earth Planet. Sci. Lett. 83, 16–26.
Marty, B., Trull, T., Lussiez, P., Basile, I., Tanguy, J.C., 1994. He,Ar, O, Sr and Nd isotope constraints on the origin and evolution of Mount Etna magmatism. Earth Planet. Sci. Lett. 126, 23– 39.
Mook, W.G., Bemmerson, J.C., Steverman, W.H., 1974. Carbon isotope fractionation between dissolved bicarbonate and gaseous carbon dioxide. Earth Planet. Sci. Lett. 22, 169–176.
Nakai, S., Wakita, H., Nuccio, P.M., Italiano, F., 1997. MORB-type neon in an enriched mantle beneath Etna, Sicily. Earth Planet. Sci. Lett. 153, 57–66.
Nielsen, H., Pilot, J., Grinenko, L.N., Grinenko, V.A., Lein, A.Yu., Smith, J.W., Pankina, R.G., 1991. Litospheric sources of sulphur. In: Krouse, H.R., Grinenko, V.A. (Eds.), SCOPE 43—Stable isotopes: natural and anthropogenic sulfur in the
environment. Wiley, Chichester, pp. 65–132.
Robin, C., Boudal, C., 1987. A gigantic Bezymianny-type event at the beginning of modern Volcan Popocatepetl. J. Volcanol. Geotherm. Res. 31, 115–130.
Sano, Y., Marty, B., 1995. Origin of carbon in fumarolic gas from island arcs. Chem. Geol. 119, 265–274.
Sano, Y., Wakita, H., 1985. Geographical distribution of 3He/4He in Japan: implications for arc tectonics and incipient magmatism.
J. Geophys. Res. 90, 8729–8741.
Sakai, H., 1968. Isotopic properties of sulphur compounds in hydrothermal processes. Geochem. J. 2, 29–49.
SPP, 1981. Carta de climas. Secretaria de Programmacion y Presuppuesto, Mexico City.
Taran, Y., Inguaggiato, S., Varley, N.R., Capasso, G., Favara, R., 2002. Helium and carbon isotopes in thermal waters of the Jalisco Block, Mexico. Geofis. Int. 41, 459–466.
Varekamp, J.C., Kreulen, R., Poorter, R.P.E., Van Bergen, M.J., 1992. Carbon sources in arc volcanism, with implications for the carbon cycle. Terra Nova 4, 363–373.
Varley, N.R., Armienta, A., 2001. The absence of diffuse degassing at Popocatepetl volcano (Mexico). Chem. Geol. 177, 157–173.
Varley, N.R., Taran, Y., 2003. Degassing processes of Popocatepetl and Volcan de Colima, Mexico. In: Oppenheimer, C., Pyle, D.M., Barclay, J. (Eds.), Volcanic Degassing. Geol. Soc. London Spec. Publ. 213, 263–280.
Werner C., Janik C.J., Goff F., Counce D., Johnson L., Siebe C., Delgado H., Williams S., Fischer T., 1997. Geochemistry of summit fumerole vapors and flanking thermal minerals waters at
Popocatepetl volcano, Mexico. Los Alamos National Laboratory. Series report LA-13289-MS, 33 pp.
Armienta, M.A., Martin Del Pozzo, A.L., Espinasa, R., Cruz, O.,Ceniceros, N., Aguayo, A., Butron, M.A., 1998. Geochemistry of Ash Leachates durino the 1994–1996 activity of Popocatepetl
Volcano. Appl. Geochem. 13 (7), 841–850.
Appelo, C.A.J., 1988. WATEQP program. Instituut Voor Aardwetenschappen,Vrije Universitei Amsterdam.
Capasso, G., Inguaggiato, S., 1998. A simple method for determination of dissolved gases in natural waters. An application to thermal waters from Vulcano Island. Appl. Geochem. 13 (5), 631–642.
Capasso, G., Favara, Inguaggiato, S., 1997. Chemical features and isotopic composition of gaseous manifestations on Vulcano Island (Aeolian Islands, Italy): an interpretative model of fluid
circulation. Geochim. Cosmoch. Acta 61 (16), 3425– 3440.
Capasso, G., Favara, R., Inguaggiato, S., 2000. Interaction between fumarolic gases and thermal groundwaters at Vulcano Island (Italy): evidences from chemical composition of dissolved gases
in waters. J. Volcanol. Geotherm. Res. 102 (3–4), 309–3180.
Capasso, G., D’Alessandro, W., Favara, R., Inguaggiato, S., Parello, F., 2001. Interaction between the deep fluids and the shallow groundwaters on the vulcano island (Italy). J. Volcanol. Geotherm. Res. 108 (1–4), 189–200.
Capasso, G., Carapezza, M.L., Federico, C., Inguaggiato, S., Rizzo, A., 2004. The 2002–2003 eruption at Stromboli volcano (Italy):
precursory changes in the carbon and helium isotopic composition of both fumarole gases and thermal waters. Bull. Volcanol. (in press).
Carapezza, M.L., Inguaggiato, S., Brusca, L., Longo, M., 2004. Geochemical precursors of the activity of an open-conduict volcano: Stromboli 2002–2003 eruptive events. Geophys. Res.
Lett. 31, L07620.
Cortes, A., Durazo, J., Farvolden, R., 1997. Studies of Isotopic hydrology of the basin of Mexico and vicinity: annotated bibliography and interpretation. J. Hydrol. 198, 346–376.
Chiodini, G., Frondini, F., Marini, L., 1995. Theoretical geothermometers and PCO2 indicators for aqueous solutions coming from hydrothermal systems of medium–low temperature hosted
in carbonate-evaporite rocks: application to the thermal springs of the Etruscan Swell, Italy. Appl. Geochem. 10, 337–346.
Chiodini, G., Cioni, R., Guidi, M., Magro, G., Marini, L., Raco, B., 2000. Gas chemistry of the lake Piccolo of Monticchio, Mt. Vulture, in December 1996. In: Villari, L. (Ed.), Data related to eruptive activity, unrest phenomena and other observations on the Italian active volcanoes 196: miscellaneous. Acta Vulcanologica,
vol. 12, pp. 139–142.
CNA (Commission Nacional de Agua), 2001. www.inegi.gob.mx.
Craig, H., 1961. Isotope variation in meteoric waters. Science 133,1702–1703.
Deines, P., Langmuir, D., Herman, R.S., 1974. Stable carbon isotope ratio and the esistence of a gas phase in the evolution of carbonate
groundwaters. Geochim. Cosmochim. Acta 38, 1147– 1164.
Delgado-Granados, H., Piedad Sanchez, N., Galvan, L., Julio, P., Alvarez, J.M., Cardenas, L., 1998. CO2 flux measurements at Popocatepetl volcano: II. Magnitude of emissions and significance
(abstract). EOS Trans., AGU 79 (45), 926 (Fall Meeting Suppl.).
Delgado-Granados, H., Cardenas Gonzalez, L., Piedad Sanchez, N., 2001. Sulfur dioxide emission rate, passively degassing erupting volcano. J. Volcanol. Geotherm. Res. 108, 107–120.
Dyck, W., 1976. The use of helium in mineral exploration. J. Geophys. Explor. 5, 3–20.
Favara, R., Grassa, F., Inguaggiato, S., Pecoraino, G., Capasso, G.,2002. A simple method to determine the d13C of total dissolved
inorganic carbon. Geofis. Int. 41 (3), 313–320.
Fournier, R.O., 1973. Silica in thermal waters: laboratory and field investigations. Proceedings, International Symposium on Hydrogeochemistry and Biogeochemistry, Tokyo. Clark, Washington, DC, vol. 1, pp. 122–129.
Giammanco, S., Inguaggiato, S., Valenza, M., 1998a. Soil and fumarole gases of Mount Etna: geochemistry and relations with volcanic activity. J. Volcanol. Geotherm. Res. 81, 297–310.
Giammanco, S., Gurrieri, S., Valenza, M., 1998b. Anomalous soil CO2 degassing in relation to faults and eruptive fissures on Mount Etna (Sicily, Italy). Bull. Volcanol. 60, 252–259.
Giggenbach, W.F., 1991. Isotopic composition of geothermal water and steam discharges. Application of Geochemistry in Geothermal
Reservoir Development. UNITAR, pp. 253–273
(F. D’Amore coordinator).
Goff, F., Janik, C.J., Delgado, H., Werner, C., Counce, D.,Stimac, J.A., Siebe, C., Love, S.P., Williams, S.N., Fischer, T., Johnson, L., 1980. Geochemical surveillance of magmatic volatiles at Popocatepetl volcano, Mexico. Geol. Soc. Am.
Bull. 110, 695–710.
Inguaggiato, S., Rizzo, A., 2004. Dissolved helium isotope ratio in ground-waters: a new technique based on gas–water reequilibration
and its application to Stromboli volcanic system.
Appl. Geochem. 19, 665–673.
Inguaggiato, S., Martin Del Pozzo, A.L., Aguayo, A., Garcia, E., Espinasa, R., Favara, R., Capasso, G., 1999. Popocatepetl volcano (Mexico): preliminary geochemical characterization of
volcanic fluids and comparison with Italian volcanic systems (Etna, Vulcano). Abstract book V32A-14, AGU Fall Meeting, San Francisco, December.
Inguaggiato, S., Pecoraino, G., D’Amore, F., 2000. Chemical and isotopical characterization of fluid manifestations of Ischia Island (Italy). J. Volcanol. Geotherm. Res. 99, 151–178.
Inguaggiato, S., Capasso, G., Favara, R., Martin Del Pozzo, A.L., Aguayo, A., 2001. Water–rock interaction processes at Popocatepetl volcano, Mexico. In: Rosa Cidu, A.A. (Ed.), Proceeding
of the Tenth International Symposium on "Water–rock Interaction",WRI-10/Villasimius/Italy/10–15 July 2001. Water Rock Interaction, vol. 2. Balkema Publishers, pp. 859–862.
Jahne, B., Heinz, G., Dietrich, W., 1987. Measurements of the diffusion coefficients of sparingly soluble gases in water. J. Geophys. Res. 92 (C-10), 10767–10776.
Jenne, E.A., Ball, J.W., Burchard, J.M., Vivit, D.V., Barks, J.H.,1980. Geochemical modeling: apparent solubility controls on Ba, Zn, Cd, Pb and F in waters of Missouri tri-State mining
area. In: Heniphill, D.D. (Ed.), Trace Substances in Environmental Health, vol. 14. University of Missouri, Columbia, pp. 353–361.
Langmuir, C.H., Vocke, R.D., Hanson, G.N., Hart, H.R., 1978. A general mixing equation with applications to Icelandic basalts. Gunter Faure–Principles of Isotope Geology, Earth Planet. Sci.
Lett., vol. 37. John Wiley and Sons, pp. 380–392.
Love, S.P., Goff, F., Counce, D., Siebe, C., Delgado, H., 1998. Passive infrared spectroscopy of the eruption plume at Popocatepetl volcano, Mexico. Nature 396, 563–567.
Marini, L., Chiodini, G., Cioni, R., 1986. New geothermometers for carbonate-evaporite geothermal reservoirs. Geothermics 15,
77–86.
Martin-Del Pozzo, A.L., Aceves, F., Espinasa, R., Aguayo, A., Butron, M.A., Inguaggiato, S., Morales, P., Cienfuegos, E., 2002a. Influence of volcanic activity on spring water chemistry
at Popocatepetl Volcano, Mexico. Chem. Geol. 190, 207–229.
Martin-Del Pozzo, A.L., Inguaggiato, S., Aceves, F., Saenz, H.,Aguayo, A., 2002b. Spring Water and CO2 interaction at Popocatepetl Volcano, Mexico. Geofis. Int. 41 (3), 345–351.
Marty, B., Jambon, A., 1987. C/3He in volatile fluxes from the solid earth: implications for carbon geodynamics. Earth Planet. Sci. Lett. 83, 16–26.
Marty, B., Trull, T., Lussiez, P., Basile, I., Tanguy, J.C., 1994. He,Ar, O, Sr and Nd isotope constraints on the origin and evolution of Mount Etna magmatism. Earth Planet. Sci. Lett. 126, 23– 39.
Mook, W.G., Bemmerson, J.C., Steverman, W.H., 1974. Carbon isotope fractionation between dissolved bicarbonate and gaseous carbon dioxide. Earth Planet. Sci. Lett. 22, 169–176.
Nakai, S., Wakita, H., Nuccio, P.M., Italiano, F., 1997. MORB-type neon in an enriched mantle beneath Etna, Sicily. Earth Planet. Sci. Lett. 153, 57–66.
Nielsen, H., Pilot, J., Grinenko, L.N., Grinenko, V.A., Lein, A.Yu., Smith, J.W., Pankina, R.G., 1991. Litospheric sources of sulphur. In: Krouse, H.R., Grinenko, V.A. (Eds.), SCOPE 43—Stable isotopes: natural and anthropogenic sulfur in the
environment. Wiley, Chichester, pp. 65–132.
Robin, C., Boudal, C., 1987. A gigantic Bezymianny-type event at the beginning of modern Volcan Popocatepetl. J. Volcanol. Geotherm. Res. 31, 115–130.
Sano, Y., Marty, B., 1995. Origin of carbon in fumarolic gas from island arcs. Chem. Geol. 119, 265–274.
Sano, Y., Wakita, H., 1985. Geographical distribution of 3He/4He in Japan: implications for arc tectonics and incipient magmatism.
J. Geophys. Res. 90, 8729–8741.
Sakai, H., 1968. Isotopic properties of sulphur compounds in hydrothermal processes. Geochem. J. 2, 29–49.
SPP, 1981. Carta de climas. Secretaria de Programmacion y Presuppuesto, Mexico City.
Taran, Y., Inguaggiato, S., Varley, N.R., Capasso, G., Favara, R., 2002. Helium and carbon isotopes in thermal waters of the Jalisco Block, Mexico. Geofis. Int. 41, 459–466.
Varekamp, J.C., Kreulen, R., Poorter, R.P.E., Van Bergen, M.J., 1992. Carbon sources in arc volcanism, with implications for the carbon cycle. Terra Nova 4, 363–373.
Varley, N.R., Armienta, A., 2001. The absence of diffuse degassing at Popocatepetl volcano (Mexico). Chem. Geol. 177, 157–173.
Varley, N.R., Taran, Y., 2003. Degassing processes of Popocatepetl and Volcan de Colima, Mexico. In: Oppenheimer, C., Pyle, D.M., Barclay, J. (Eds.), Volcanic Degassing. Geol. Soc. London Spec. Publ. 213, 263–280.
Werner C., Janik C.J., Goff F., Counce D., Johnson L., Siebe C., Delgado H., Williams S., Fischer T., 1997. Geochemistry of summit fumerole vapors and flanking thermal minerals waters at
Popocatepetl volcano, Mexico. Los Alamos National Laboratory. Series report LA-13289-MS, 33 pp.
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