Please use this identifier to cite or link to this item:
http://hdl.handle.net/2122/399| DC Field | Value | Language |
|---|---|---|
| dc.contributor.authorall | Aiuppa, A.; Dipartimento Chimica e Fisica della Terra ed applicazioni, Università di Palermo, Palermo, Italy | en |
| dc.contributor.authorall | Inguaggiato, S.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia | en |
| dc.contributor.authorall | McGonigle, A. J. S.; Department of Geography, University of Cambridge, Cambridge, UK | en |
| dc.contributor.authorall | O'Dwyer, M.; Department of Physics and Astronomy, University of Glasgow, Glasgow, UK | en |
| dc.contributor.authorall | Oppenheimer, C.; Department of Geography, University of Cambridge, Cambridge, UK | en |
| dc.contributor.authorall | Padgett, M. J.; Department of Physics and Astronomy, University of Glasgow, Glasgow, UK | en |
| dc.contributor.authorall | Rouwet, D.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia | en |
| dc.contributor.authorall | Valenza, M.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia | en |
| dc.date.accessioned | 2005-09-12T14:03:01Z | en |
| dc.date.available | 2005-09-12T14:03:01Z | en |
| dc.date.issued | 2005 | en |
| dc.identifier.uri | http://hdl.handle.net/2122/399 | en |
| dc.description.abstract | We present here new measurements of sulfur dioxide and hydrogen sulfide emissions from Vulcano, Etna, and Stromboli (Italy), made by direct sampling at vents and by filter pack and ultraviolet spectroscopy in downwind plumes. Measurements at the F0 and FA fumaroles on Vulcano yielded SO2/H2S molar ratios of 0.38 and 1.4, respectively, from which we estimate an H2S flux of 6 to 9 for the summit crater. For Mt. Etna and Stromboli, we found SO2/H2S molar ratios of 20 and 15, respectively, which combined with SO2 flux measurements, suggest H2S emission rates of 50 to 113 and 4 to 8, respectively. We observe that source and plume SO2/H2S ratios at Vulcano are similar, suggesting that hydrogen sulfide is essentially inert on timescales of seconds to minutes. This finding has important implications for estimates of volcanic total sulfur budget at volcanoes since most existing measurements do not account for H2S emission. | en |
| dc.format.extent | 539 bytes | en |
| dc.format.extent | 665710 bytes | en |
| dc.format.mimetype | text/html | en |
| dc.format.mimetype | application/pdf | en |
| dc.language.iso | English | en |
| dc.publisher.name | Elsevier | en |
| dc.relation.ispartof | Geochimica et Cosmochimica Acta | en |
| dc.relation.ispartofseries | 7/69(2005) | en |
| dc.subject | H2S atmospheric budget | en |
| dc.subject | volcanic degassing | en |
| dc.title | H2S fluxes from Mt. Etna, Stromboli, and Vulcano (Italy) and implications for the sulfur budget at volcanoes | en |
| dc.type | article | en |
| dc.description.status | Published | en |
| dc.type.QualityControl | Peer-reviewed | en |
| dc.description.pagenumber | 1861–1871 | en |
| dc.identifier.URL | http://www.sciencedirect.com/ | en |
| dc.subject.INGV | 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects | en |
| dc.subject.INGV | 04. Solid Earth::04.08. Volcanology::04.08.01. Gases | en |
| dc.subject.INGV | 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring | en |
| dc.subject.INGV | 05. General::05.02. Data dissemination::05.02.01. Geochemical data | en |
| dc.identifier.doi | 10.1016/j.gca.2004.09.018 | en |
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R. Carroll and J. R. Halloway), pp. 1-66, Mineralogical Society of America. Symonds R., Mizutani Y., and Briggs P. H. (1996) Long term geochemical surveillance of fumaroles of Showa-Shinzan dome, Usu volcano, Japan. J. Volcanol. Geotherm. Res. 73, 177-211. Symonds R., Gerlach T. M., and Reed M. H. (2001) Magmatic gas scrubbing: implications for volcano monitoring. J. Volcanol. Geotherm. Res. 108, 303-341. Toda K., Ohira S., Tanaka T., and Nishimura T. (2004) Field instrument for simultaneous large dynamic range measurement of atmospheric hydrogen sulfide, methanethiol and sulfur dioxide. Environ. Sci. Technol. 38, 1529-1536. Warneck P. (1988) Chemistry of the Natural Atmosphere. Academic Press. Williams S. N., Schaefer S. J., Calvache V., and Lopez D. (1992) Global carbon dioxide emission to the atmosphere by volcanoes. Geochim. Cosmochim. Acta 56, 1765-1770. | en |
| dc.description.fulltext | partially_open | en |
| dc.contributor.author | Aiuppa, A. | en |
| dc.contributor.author | Inguaggiato, S. | en |
| dc.contributor.author | McGonigle, A. J. S. | en |
| dc.contributor.author | O'Dwyer, M. | en |
| dc.contributor.author | Oppenheimer, C. | en |
| dc.contributor.author | Padgett, M. J. | en |
| dc.contributor.author | Rouwet, D. | en |
| dc.contributor.author | Valenza, M. | en |
| dc.contributor.department | Dipartimento Chimica e Fisica della Terra ed applicazioni, Università di Palermo, Palermo, Italy | en |
| dc.contributor.department | Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia | en |
| dc.contributor.department | Department of Geography, University of Cambridge, Cambridge, UK | en |
| dc.contributor.department | Department of Physics and Astronomy, University of Glasgow, Glasgow, UK | en |
| dc.contributor.department | Department of Physics and Astronomy, University of Glasgow, Glasgow, UK | en |
| dc.contributor.department | Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia | en |
| dc.contributor.department | Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italia | en |
| item.openairetype | article | - |
| item.cerifentitytype | Publications | - |
| item.languageiso639-1 | en | - |
| item.grantfulltext | restricted | - |
| item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
| item.fulltext | With Fulltext | - |
| crisitem.author.dept | Istituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Palermo, Palermo, Italia | - |
| crisitem.author.dept | Istituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Palermo, Palermo, Italia | - |
| crisitem.author.dept | Department of Geography, University of Cambridge, Downing Place, CB2 3EN Cambridge, UK | - |
| crisitem.author.dept | Department of Physics and Astronomy, University of Glasgow, Glasgow, UK | - |
| crisitem.author.dept | Department of Physics and Astronomy, University of Glasgow, Glasgow, UK | - |
| crisitem.author.dept | Istituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Bologna, Bologna, Italia | - |
| crisitem.author.dept | DiSTeM, Universit a degli Studi di Palermo, Palermo, Italy | - |
| crisitem.author.orcid | 0000-0002-0254-6539 | - |
| crisitem.author.orcid | 0000-0003-3726-9946 | - |
| crisitem.author.orcid | 0000-0003-4506-7260 | - |
| crisitem.author.orcid | 0000-0003-3366-3882 | - |
| crisitem.author.parentorg | Istituto Nazionale di Geofisica e Vulcanologia | - |
| crisitem.author.parentorg | Istituto Nazionale di Geofisica e Vulcanologia | - |
| crisitem.author.parentorg | Istituto Nazionale di Geofisica e Vulcanologia | - |
| crisitem.classification.parent | 01. Atmosphere | - |
| crisitem.classification.parent | 04. Solid Earth | - |
| crisitem.classification.parent | 04. Solid Earth | - |
| crisitem.classification.parent | 05. General | - |
| crisitem.department.parentorg | Istituto Nazionale di Geofisica e Vulcanologia | - |
| crisitem.department.parentorg | Istituto Nazionale di Geofisica e Vulcanologia | - |
| crisitem.department.parentorg | Istituto Nazionale di Geofisica e Vulcanologia | - |
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