Please use this identifier to cite or link to this item:
http://hdl.handle.net/2122/329| DC Field | Value | Language |
|---|---|---|
| dc.contributor.authorall | Aiuppa, A.; Dipartimento CFTA, Universita` di Palermo | en |
| dc.contributor.authorall | Federico, C.; Dipartimento CFTA, Universita` di Palermo | en |
| dc.contributor.authorall | Giudice, G.; Dipartimento CFTA, Universita` di Palermo | en |
| dc.contributor.authorall | Gurrieri, S.; Dipartimento CFTA, Universita` di Palermo | en |
| dc.contributor.authorall | Paonita, A.; Dipartimento CFTA, Universita` di Palermo | en |
| dc.contributor.authorall | Valenza, M.; Dipartimento CFTA, Universita` di Palermo | en |
| dc.date.accessioned | 2005-08-01T14:07:50Z | en |
| dc.date.available | 2005-08-01T14:07:50Z | en |
| dc.date.issued | 2004 | en |
| dc.identifier.uri | http://hdl.handle.net/2122/329 | en |
| dc.description.abstract | This paper deals with sulfur, chlorine and fluorine abundances in the eruptive volcanic plume of the huge October 2002– January 2003 eruption of Mount Etna, aiming at relating the relevant compositional variations observed throughout with changes in eruption dynamics and degassing mechanisms. The recurrent sampling of plume acidic volatiles by filter-pack methodology revealed that, during the study period, S/Cl and Cl/F ratios ranged from 0.1–6.8 and 0.9–5.6, respectively. Plume S/Cl ratios increased by a factor of f10 as volcanic activity drifted from paroxysmal lava fountaining (mid- and late November) to passive degassing and minor effusion (early January), and then decreased to the low values (S/Cl = 0.1) typical of the final stages of the eruption. Parallel variations in chlorine to fluorine ratios were also observed. A theoretical model is proposed for quantitative interpretation of these changes in plume composition. The model calculates the composition of a volatile phase exsolving from an ascending Etna magma, based on knowledge of solubilities and abundances in the undegassed melt of sulfur and halogens [T.M. Gerlach, EOS 72 (1991), 249, 254–255]. According to this model, degassing of Etnean basaltic melt at high pressures and depths (>100 MPa, 3 km) is likely to release a CO2+H2O-rich vapor phase with S/Cl molar ratios f1. Extensive sulfur and chlorine degassing from the melt would take place at shallower depth ( P < 20 MPa, 0.6 km), with S/Cl ratios in the vapor phase increasing as pressure drops to 0.1 MPa. Comparisons between model compositions and volcanic plume data demonstrate that the chemical trends observed during the eruption may be explained by increased degassing due to depressurization of a basaltic magma batch ascending toward the surface. | en |
| dc.format.extent | 532 bytes | en |
| dc.format.extent | 728204 bytes | en |
| dc.format.mimetype | text/html | en |
| dc.format.mimetype | application/pdf | en |
| dc.language.iso | English | en |
| dc.publisher.name | Elsevier | en |
| dc.relation.ispartof | Earth and Planetary Science Letters | en |
| dc.relation.ispartofseries | 222 (2004) | en |
| dc.subject | magmatic degassing | en |
| dc.subject | volcanic plume | en |
| dc.subject | basaltic eruption | en |
| dc.title | Plume chemistry provides insights into mechanisms of sulfur and halogen degassing in basaltic volcanoes | en |
| dc.type | article | en |
| dc.description.status | Published | en |
| dc.type.QualityControl | Peer-reviewed | en |
| dc.description.pagenumber | 469-483 | en |
| dc.identifier.URL | http://www.elsevier.com/wps/find/ | en |
| dc.subject.INGV | 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring | en |
| dc.identifier.doi | doi:10.1016/j.epsl.2004.03.020 | en |
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Carroll, Solubility and fluid-melt partitioning of Cl in hydrous phonolitic melts, Geochim. Cosmochim. Acta 64 (2000) 2851– 2862. | en |
| dc.description.fulltext | partially_open | en |
| dc.contributor.author | Aiuppa, A. | en |
| dc.contributor.author | Federico, C. | en |
| dc.contributor.author | Giudice, G. | en |
| dc.contributor.author | Gurrieri, S. | en |
| dc.contributor.author | Paonita, A. | en |
| dc.contributor.author | Valenza, M. | en |
| dc.contributor.department | Dipartimento CFTA, Universita` di Palermo | en |
| dc.contributor.department | Dipartimento CFTA, Universita` di Palermo | en |
| dc.contributor.department | Dipartimento CFTA, Universita` di Palermo | en |
| dc.contributor.department | Dipartimento CFTA, Universita` di Palermo | en |
| dc.contributor.department | Dipartimento CFTA, Universita` di Palermo | en |
| dc.contributor.department | Dipartimento CFTA, Universita` di Palermo | en |
| item.openairetype | article | - |
| item.cerifentitytype | Publications | - |
| item.languageiso639-1 | en | - |
| item.grantfulltext | open | - |
| item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
| item.fulltext | With Fulltext | - |
| crisitem.author.dept | Istituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Palermo, Palermo, Italia | - |
| crisitem.author.dept | Istituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Palermo, Palermo, Italia | - |
| crisitem.author.dept | Istituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione OE, Catania, Italia | - |
| crisitem.author.dept | Istituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Palermo, Palermo, Italia | - |
| crisitem.author.dept | Istituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Palermo, Palermo, Italia | - |
| crisitem.author.dept | DiSTeM, Universit a degli Studi di Palermo, Palermo, Italy | - |
| crisitem.author.orcid | 0000-0002-0254-6539 | - |
| crisitem.author.orcid | 0000-0001-8887-2580 | - |
| crisitem.author.orcid | 0000-0002-9410-4139 | - |
| crisitem.author.orcid | 0000-0003-4085-0440 | - |
| crisitem.author.orcid | 0000-0001-9124-5027 | - |
| crisitem.author.parentorg | Istituto Nazionale di Geofisica e Vulcanologia | - |
| crisitem.author.parentorg | Istituto Nazionale di Geofisica e Vulcanologia | - |
| crisitem.author.parentorg | Istituto Nazionale di Geofisica e Vulcanologia | - |
| crisitem.author.parentorg | Istituto Nazionale di Geofisica e Vulcanologia | - |
| crisitem.author.parentorg | Istituto Nazionale di Geofisica e Vulcanologia | - |
| crisitem.classification.parent | 04. Solid Earth | - |
| Appears in Collections: | Article published / in press | |
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