Please use this identifier to cite or link to this item: http://hdl.handle.net/2122/11685
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dc.date.accessioned2018-04-10T09:17:10Zen
dc.date.available2018-04-10T09:17:10Zen
dc.date.issued2017en
dc.identifier.urihttp://hdl.handle.net/2122/11685en
dc.description.abstractWe show the results of a study on the volatiles dissolved inmineral waters discharged over a 200 km-long transect along the Rodna-Bârgău area and Călimani-Gurghiu-Harghita volcanic chain (Eastern Carpathians, Romania). All of the collected mineral water samples carry dissolved gas with carbon dioxide content up to 1.99 cm3STP/gH2O, and heliumcontent up to 2.3 × 10−5 cm3STP/gH2O. Carbon (δ13CTDIC total dissolved inorganic carbon, ranging from−15.6 to 5.32‰vs. VPDB), He systematics (He isotopes in the range of 0.38–0.99 Ra, Ra=air-normalized 3He/4He ratio) and CO2/3He ratio spanning over four orders ofmagnitude fromMORB-like values of 2.92× 109 to crustal-type values of 3.02 × 1013, coherently indicate the presence of fluids fromdifferent crustal sources (e.g. sediments, hydrocarbon reservoirs) besidesminor, but detectable contributions ofmantle/magmatic-derived fluids (up to 16.45%). Our investigations show that the wide range of chemical and isotopic composition can be explained in terms of mixings among different gas sources feeding the groundwater and the contemporary occurrence of gas-water interactions like degassing and deposition of carbonates, affecting the circulating waters after their infiltration.en
dc.language.isoEnglishen
dc.relation.ispartofChemical Geologyen
dc.relation.ispartofseries/469 (2017)en
dc.subjectEastern Carpathiansen
dc.subjectDissolved gasesen
dc.subjectGas-water interactionsen
dc.subjectHelium 13CTDICen
dc.titleGeochemistry of dissolved gases from the Eastern Carpathians - Transylvanian Basin boundaryen
dc.typearticleen
dc.description.statusPublisheden
dc.type.QualityControlPeer-revieweden
dc.description.pagenumber117-128en
dc.subject.INGVgas geochemistryen
dc.identifier.doi10.1016/j.chemgeo.2016.12.019en
dc.relation.referencesAlthaus, T., Niedermann, S., Erzinger, J., 2000. Noble gas studies of fluids and gas exhalations in the East Carpathians, Romania. Chem. Erde 60, 189–207. Baciu, C., Caracausi, A., Etiope, G., Italiano, F., 2007. Mud volcanoes and methane seeps in Romania: main features and gas flux. Ann. Geophys. 50, 501–512. Băncilă, I., 1958. Geology of Eastern Carpathians. Editura Științifică, București (In Romanian). Bányai, J., 1934. The Mineral Waters From Szeklerland (Kül.ErdélyiMúzeum, XXXIX, 1-13. In Hungarian). Barry, P.H., Hilton, D.R., Fischer, T.P., de Moor, J.M., Mangasini, F., Ramirez, C., 2013. Helium and carbon isotope systematic of cold “mazuku” CO2 vents and hydrothermal gases and fluids from Rungwe Volcanic Province, southern Tanzania. Chem. Geol. 339, 141–156. Benavente, O., Tassi, F., Reich, M., Aguilera, F., Capecchiacci, F., Gutierez, F., Vaselli, O., Rizzo, A., 2016. Chemical and isotopic features of cold and thermal fluids discharged in the Southern Volcanic Zone between 32.5°S and 36°S: insights into the physical and chemical processes controlling fluid geochemistry in geothermal systems of Central Chile. Chem. Geol. 420, 97–113. Birke, P.,Marin, E.P., Pinti, D., Castro, C.M., 2016. Origin and evolution of geothermal fluids from Las Tres Virgenes and Cerro Prieto fields, Mexico, Co-genetic volcanic activity and paleoclimatic constraints. Appl. Geochem. 65, 36–53. Brauer, K., Geissler, W., Kampf, H., Niedermann, S., Rman, N., 2016. Helium and carbon isotope signatures of gas exhalations in the westernmost Pannonian Basin (SE Austria/ NE Slovenia): evidence for active litospheric mantle degassing. Chem. Geol. 422, 60–70. Capasso, G., Inguaggiato, S., 1998. A simple method for the determination of dissolved gases in natural waters. An application to thermal waters from Vulcano Island. Appl. Geochem. 13 (5), 631–642. Chintăuan, I., 1998. Bistrița-Năsăud, Mineral Waters and Spas. Muzeul Judeţean Bistriţa- Năsăud, Bistrița (In Romanian). Chiodini, G., Frondini, F., Cardellini, C., Parello, f., Peruzzi, L., 2000. Rate of diffuse carbon dioxide Earth degassing estimated from the carbon balance of regional aquifers: the case of central Apennine, Italy. J. Geophys. Res. 105 (B4), 8423–8434. Chiodini, G., Cardellini, C., Amato, A., Boschi, E., Caliro, S., Frondini, F., Ventura, G., 2004. Carbon dioxide Earth degassing and seismogenesis in central and southern Italy. Geophys. Res. Lett. 31, L07615. http://dx.doi.org/10.1029/004GL019480. Chiodini, G., Caliro, S., Cardellini, C., Frondini, F., Inguaggiato, S., Matteucci, F., 2011. Geochemical evidence for and characterization of CO2 rich gas sources on the epicentral area of Abruzzo 2009 earthquakes. Earth Planet. Sci. Lett. 304, 389–398.Chiodini, G., Cardellini, C., Caliro, S., Chiarabba, C., Frondini, F., 2013. Advective heat transport associated with regional Earth degassing in central Apennine (Italy). Earth Planet. Sci. Lett. 373, 65–74. Crăciun, P., Barnes, I., Bandrabur, T., 1989. Stable isotopes in hydrogeothermal structures in Romania. Stud. Teh. Econ. Ser. E 15, 17–39. De Leeuw, G.A.M., Hilton, D.R., Fischer, T.P., Walker, J.A., 2007. The He-CO2 isotope and relative abundance characteristics of geothermal fluids in El Salvador and Honduras: new constraints on volatile mass balance of the Central Americal Volcanic Arc. Earth Planet. Sci. Lett. 258, 132–146. Deines, P., Langmuir, D., Harmon, S.R., 1974. Stable carbon isotope ratios and the existence of a gas phase in the evolution of carbonate ground waters. Geochim. Cosmochim. Acta 38, 1147–1164. Dunai, T.J., Baur, H., 1995. Helium, neon and argon systematics of the European subcontinental mantle: implications for its geochemical evolution. Geochim. Cosmochim. Acta 59, 2767–2783. Etiope, G., Baciu, C., Caracausi, A., Italiano, F., Cosma, C., 2004. Gas flux to the atmosphere from mud volcanoes in eastern Romania. Terra Nova 16, 179–184. Etiope, G., Baciu, C., Schoell, M., 2011. Extreme methane deuterium, nitrogen and helium enrichment in natural gas from Homorod seep (Romania). Chem. Geol. 280, 89–96. Frunzeti, N., 2013. Geogenic Emissions of Greenhouse Gases in the Southern Part of the Eastern Carpathians. PhD Thesis. Babeș-Bolyai University, Faculty of Environmental Science and Engineering, Cluj-Napoca (In Romanian). Gamo, T., Tsunogai, U., Ichibayashi, S., Chiba, H., Obata, H., Oomori, T., Noguchi, T., Baker, E., Doi, T., Maruo,M., Sano, Y., 2010.Microbial carbon isotope fractionation to produce extraordinarily heavy methane in aging hydrothermal plumes over the southwestern Okinawa Trough. Geochem. J. 44, 477–487. Giggenbach, W.F., Sano, Y., Schmincke, H.U., 1991. CO2-rich gases from Lakes Nyos and Monoun, Cameroon; Laacher See, Germany; Dieng, Indonesia, and Mt. Gambier, Australia- variations on common theme. J. Volcanol. Geotherm. Res. 45, 311–323. Harangi, S., Molnár, M., Vinkler, A.P., Kiss, B., Jull, A.J.T., Leonard, A.G., 2010. Radiocarbon dating of the last volcanic eruption of Ciomadul Volcano, Southeast Carpathians, Eastern- Central Europe. Radiocarbon 52 (2–3), 1498–1507. Hilton, D., Fischer, T.P., Marty, B., 2002. Noble gases and volatile recycling at subduction zones. Rev.Mineral. Geochem. 47:319–370. http://dx.doi.org/10.2198/rmg.2002.47.9. Hoefs, J., 2009. Stable Isotope Geochemistry. Springer, Berlin-Heidelberg, p. 285. Holocher, J., Peeters, F., Aeschbach-Hertig, W., Hofer, M., Brennwald, M., Kinzelbach, W., Kipfer, R., 2002. Experimental investigations on the formation of excess air in quasi-saturated porous media. Geochim. Cosmochim. Acta 66, 4103–4117. Ianovici, V., Rădulescu, D., Patrulius, D., 1968. Geologic map 1:200 000 teritoriul 4.Vișeu, Institutul Geologic București, In Romanian.Inguaggiato, S., Censi, P., D'Alessandro,W., Zuddas, P., 2016. Geochemical characterization of gases along the dead sea rift: evidences of mantle-CO2 degassing. J. Volcanol. Geotherm. Res. 320, 50–57. Inguaggiato, S., Rizzo, A., 2004. Dissolved helium isotope ratios in ground-waters: a new technique based on gas-water re-equilibration and its application to Stromboli volcanic system. Appl. Geochem. 19, 665–673. Ionescu, A., 2015. Geogenic Methane in Petroliferous and Geothermal Areas in Romania: Origin and Emission to the Atmosphere. PhD Thesis. Babeș-Bolyai University, Faculty of Environmental Science and Engineering, Cluj-Napoca. Italiano, F., Martinelli, G., Nuccio, P.M., 2001. Anomalies of mantle-derived helium during the 1997–1998 seismic swarm of Umbria-Marche, Italy. Geophys. Res. Lett. 28, 839–842. Italiano, F., Bonfanti, P., Ditta,M., Petrini, R., Slejko, F., 2009. Helium and carbon isotopes is the dissolved gases of Friuli Region (NE Italy): geochemical evidence of CO2 production and degassing over a seismically active area. Chem. Geol. 266, 76–85. Italiano, F., Sasmaz, A., Yuce, G., Okan, O., 2013. Thermal fluids along the East Anatolian Fault Zone (EAFZ): geochemical features and relationships with the tectonic setting. Chem. Geol. 339:103–114. http://dx.doi.org/10.1016/j.chemgeo.2012.07.027. Italiano, F., Yuce, G., Uysal, I.T., Gasparon, M., Morelli, G., 2014. Insights into mantle-type volatiles contribution from dissolved gases in artesian waters of the Great Artesian Basin, Australia. Chem. Geol. 378–379, 75–88. Jánosi, C., Péter, É., Herczeg, Á., Potozky, L., Köllő, M., Kolumbán, G., Unger, Z., Somlósi, L., Jánosi, K., 2005. Spas of Szeklerland. BKL, Szombathely, p. 179 (In Hungarian). Kis, B.M., 2013. Hydrogeochemistry of Mineral Waters From the Eastern Carpathians- Transylvanian Basin Boundary. PhD Thesis. Babeș-Bolyai University, Faculty of Environmental Science and Engineering, Cluj-Napoca. Kis, B.M., Baciu, C., 2013. A hydrochemical approach to the mineral waters from the Eastern Carpathians. Ecoterra 35, 8–14. Klemperer, S., Kennedy, M., Sastry, S., Makovsky, Y., Harinarayana, T., Leech, M., 2013. Mantle fluids in the Karakorum fault: helium isotope evidence. Earth Planet. Sci. Lett. 366, 59–70. Krézsek, C., Bally, A.W., 2006. The Transylvanian Basin (Romania) and its relation to the Carpathian fold and thrust belt: insights in gravitational salt tectonics. Mar. Pet. Geol. 23, 405–442. Krézsek, C., Filipescu, S., 2005. Middle to late Miocene sequence stratigraphy of the Transylvanian Basin (Romania). Tectonophysics 410, 431–463. Krézsek, C., Filipescu, S., Silye, L., Mațenco, L., Doust, H., 2010. Miocene facies associations and sedimentary evoltion of the Southern Transylvanian Basi (Romania): implications for hydrocarbon exploration. Mar. Pet. Geol. 27, 191–214. Mamyrin, B.A., Tolstikhin, I.N., 1984. Helium isotope in nature. Developments in Geochemistry vol. 3. Elsevier, Amsterdam. Marrero-Diaz, R., Lopez, D., Perez, N., Custodio, E., Hirochika, S., Melian, G., Padron, E., Hernandez, P., Calvo, D., Barrancos, J., Padilla, G., Sortino, F., 2015. Carbon dioxide and heliumdissolved gases in groundwater at central Tenerife Island, Canary Islands: chemical and isotopic characterization. Bull. Volcanol. 77:86. http://dx.doi.org/10. 1007/s00445-015-0969-0. Marty, B., Jambon, A., 1987. C/3He in volatile fluxes from the solid Earth: implications for carbon geodynamics. Earth Planet. Sci. Lett. 83, 16–26. Molnar-Amărăscu, R., Pricăjan, A., 1961. Geological and hydrogeological conditions of the mineral waters from the Eastern Carpathians. Apele și nămolurile terapeutice din R.P.R. Inst. Balneol.-Fizioter, București, pp. 543–701 (In Romanian). Mook, W.G., Bommerson, J.C., Staverman, W.H., 1974. Carbon isotope fractionation between dissolved bicarbonate and gaseous carbon dioxide. Earth Planet. Sci. Lett. 22, 169–176. Mosonyi, E., 1998. Studiul geologic-structural al metamorfitelor de peversantulsudic al Masivului Rodna. PhD Thesis. p. 232. Mutihac, V., 1990. Structurageologică a teritoriuluiRomâniei. Ed.Tech, București, p. 419. Nițoi, E., Munteanu, M., Marincea, Ș., 2000. The enclaves in the East Carpathian Neogene Intrusions (Romania); their significance for the genesis of the calc-alkaline magmas. An. Inst. Geol. Rom. 72, 67–76. Ohba, T., Sawa, T., Taira, N., Yang, T.F., Lee, H.F., Lan, T.F., Ohwada, M., Morikawa, N., Kazahaya, K., 2010. Magmatic fluids on Tatun volcanic group, Taiwan. Appl. Geochem. 25, 513–523. O'Nions, R.K., Oxburgh, E.R., 1988. Helium, volatile fluxes and development of continental crust, Earth Planet. Sci. Lett. 90, 331–347. Ozima, M., Podosek, F.A., 2004. Noble Gas Geochemistry. Cambridge University Press, Cambridge, p. 302. Panaiotu, C.G., Pécskay, Z., Hambach, U., Seghedi, I., Panatoiu, C.E., Tetsumaru, I., Orleanu, M., Szakács, A., 2004. Short-lived quaternary volcanismin the PerșaniMountains (Romania) revealed by combined K-Ar and paleomagnetic data. Geol. Carpath. 55, 333–339. Papp, D.C., 2000. Deuterium and salinity of the present free waters from the Rodna- Bargau Mountains, Romania: an assessment for their origin and underground dynamics. J. Geochem. Explor. 69-70, 429–433. Paucă, M., 1967. Contributions to the genesis of Miocene saline deposits from Romania. D.S. Inst. Geol. Geofiz. 53 (2), 159–184 (In Romanian). Pécskay, Z., Lexa, J., Szakács, A., Seghedi, I., Balogh, K., Konecny, V., Zelenka, T., Kovacs, M., Póka, T., Fülöp, A., Márton, E., Cvethovic, V., 2006. Geochronology of Neogene magmatism in the Carpathian arc and Intra-Carpathian area. Geol. Carpath. 57 (6), 511–530.Peltz, S., Vasiliu, C., Udrescu, C., Bratosin, I., 1971. Petrology of the magmatites from the Neogene subvolcanic zone of the Eastern Carpathians. An.I.G.G.XXXIX, pp. 13–18. Peltz, S., Popescu, I., Ștefănescu, M., Patrulius, D., Seghedi, I., Ticleanu, N., Mihăilă, N., Peltz M., Ștefănescu, M., Popescu, A., 1983. Geologic Map 1:50000 Băile Chirui, Inst.de Geol.Geofiz., București. Pik, R., Marty, B., 2008. Helium isotopic signature of modern and fossil fluids associated with the Corinth rift fault zone (Greece): implication for fault connectivity in the lower crust. Chem. Geol. 266, 67–75. Pinti, D.L., Beland-Otis, C., Tremblay, A., Castro, M.C., Hall, C.M., Marcil, J.S., Lavoie, J.Y., Lapointe, R., 2011. Fossil brines preserved in the St-Lawrence Lowlands Quebec, Canada as revealed by their chemistry and noble gas isotopes. Geochim. Cosmochim. Acta 75, 4228–4243. Polyak, B.G., Tolstikhin, I.N., 1985. Isotopic composition of the Earth's helium and the problem of tectogenesis. Chem. Geol. 52, 9–33. Pricăjan, A., 1972. The Mineral and ThermalWaters From Romania. Ed.Tech, București (In Romanian). Rădulescu, D., Dumitrescu, R., 1982. Endogene Petrology of Romania. Universitatea din București, Facultatea de Geologie și Geografie, București. Rădulescu, D., Peltz, S., Popescu, A., 1973. Lower compartment of the structure of the Călimani, Gurghiu and Harghita Mountains: the volcano-sedimentary formation. Ann. Inst. Geol. XLI, 15–26. Răileanu, G., Rădulescu, D., 1967. Geological Map 1:200 000 11. Bistrița Area, Geological Institute, București. In Romanian. Ray, M.C., Hilton, D.R., Munoz, J., Fischer, T.P., Shaw, A.M., 2009. The effects of volatile recycling, degassing and crustal contamination on helium and carbon geochemistry of hydrothermal fluids from the Southern Volcanic Zone of Chile. Chem. Geol. 266, 38–49. Săndulescu, M., 1984. Geotectonica României. Editura Technică, București, p. 366 (In Romanian). Sano, Y., Fischer, T.P., 2013. The analysis and interpretation of noble gases in modern hydrothermal systems. In: Burnard, P. (Ed.), The Noble Gases as Geochemical Tracers. Springer Verlag, Berlin Heidelberg, pp. 249–317. Sano, Y., Marty, B., 1995. Origin of carbon in fumarolic gas from island arcs. Chem. Geol. 119, 265–274. Sano, Y., Wakita, H., 1985. Geographical distribution of 3He4He ratios in Japan: implications for arc-tectonisc and incipient magmatism. J. Geophys. Res. 90, 8729–8741. Sano, Y., Takahata, N., Igasashi, G., Koizumo, N., Sturchio, N.C., 1998. Helium degassing related to the Kobe earthquake. Chem. Geol. 150, 171–179. Sano, Y., Kosigu, T., Takahata, N., Yokochi, R., 2004. Helium isotopes in Pacific waters from adjacent region of Honshu, Japan. J. Oceanogr. 60 (652-630). Sano, Y., Marty, B., Burnard, P., 2013. Noble gases in the atmosphere. In: Burnard, P. (Ed.), The Noble Gases as Geochemical Tracers. Springer Verlag, Berlin Heidelberg, pp. 249–317. Sano, Y., Wakita, H., 1988. Precise measurement of helium isotopes in terrestrial gases. Bull. Chem. Soc. Jpn. 61, 153–1157. Seghedi, I., Szakács, A., 1994. Upper Pliocene to Quaternary basaltic volcanism in the Perșani Mountains. Rom. J. Petrol. 76, 101–107. Seghedi, I., Szakács, A., Mason, P.R.D., 1995. Petrogenesis and magmatic evolution in the East Carpathian Neogene volcanic arc (Romania). Acta Vulcanol. 7 (2), 135–143. Seghedi, I., Downes, H., Szakács, A., Mason, P.R.D., Theilwall, M.F., Rosu, E., Pécskay, Z., Márton, E., Panaiotu, C., 2004. Neogene-Quaternary magmatism and geodynamics in the Carpathian-Pannonian region: a synthesis. Lithos 72, 117–146. Shaw, A.M., Hilton, D.R., Fischer, T.P., Walker, J.A., Alvarado, E.G., 2003. Contrasting He-C relationships in Nicaraga and Costa Rica: insights into C cycling through subduction zones. Earth Planet. Sci. Lett. 214, 499–513. Sherwood-Lollar, B., Ballentine, C., O'Nions, R., 1997. The fate of mantle-derived carbon in a continental sedimentary basin: integration of C/He relationships and stable isotope signatures. Geochim. Cosmochim. Acta 61 (11), 2295–2307. Szakács, A., Seghedi, I., 1995a. Genetic types of volcaniclastics in the Călimani-Gurghiu- Harghita volcanic chain (Eastern Carpathians). Romanian J. Stratigr. 76 (7), 157–159. Szakács, A., Seghedi, I., 1995b. The Călimani-Gurghiu-Harghita volcanic chain, East Carpathians, Romania: volcanological features. Acta Vulcanol. 7 (2), 145–153. Ticleanu, N., Peltz, S., Popescu, A., Gheorghian, M., Andreescu, I., 1980. Geological map 1: 50000 Odorhei, Geological Institute, București. In Romanian. Ureche, I., 1999. Petrology of the NeogeneMagmatites From BârgăuMountains. PhDThesis. Babeș-Bolyai University, Faculty of Biology and Geology, Cluj-Napoca (In Romanian). Vaselli, O., Minissale, A., Tassi, F., Magro, G., Seghedi, I., Ioane, D., Szakács, A., 2002. A geochemical traverse across the Eastern Carpathians (Romania): constraints on the origin and evolution of themineral waters and gas discharge. Chem. Geo. 182, 637–654. Yang, T.F., Lan, T.F., Lee, H.F., Fu, C.C., Chuang, P.C., Lo, C., Chen, C.H., Chen, C.T.A., Lee, C.S., 2005. Gas composition and helium isotopic ratios on fluid samples around Kueishantao NE offshore Taiwan and its tectonic implications. Geochem. J. 39, 469–480. Zhang, J., Quay, P.D.,Wilbur, D.O., 1995. Carbon isotope fractionation during gas-water exchange and dissolution of CO2. Geochim. Cosmochim. Acta 59, 107–114.en
dc.description.obiettivoSpecifico6A. Geochimica per l'ambienteen
dc.description.journalTypeJCR Journalen
dc.contributor.authorItaliano, Francescoen
dc.contributor.authorKis, Boglarka-Mercedeszen
dc.contributor.authorBaciu, Calinen
dc.contributor.authorIonescu, Arturen
dc.contributor.authorHarangi, Szabolcsen
dc.contributor.authorPalcsu, Lászlóen
dc.contributor.departmentIstituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Palermo, Palermo, Italiaen
dc.contributor.departmentEötvös University Budapest, Hungary; Babeş-Bolyai University, Cluj-Napoca, Romaniaen
dc.contributor.departmentBabeş-Bolyai University, Cluj-Napoca, Romaniaen
dc.contributor.departmentBabeş-Bolyai University, Cluj-Napoca, Romaniaen
dc.contributor.departmentEötvös University Budapest, Hungary;en
dc.contributor.departmentEötvös University Budapest, Hungary;en
item.openairetypearticle-
item.cerifentitytypePublications-
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item.grantfulltextrestricted-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
crisitem.author.deptIstituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Palermo, Palermo, Italia-
crisitem.author.deptMTA‐ELTE Volcanology Research Group, Budapest, Hungary-
crisitem.author.deptEötvös University Budapest, Hungary;-
crisitem.author.orcid0000-0002-9465-6398-
crisitem.author.orcid0000-0003-4458-1639-
crisitem.author.orcid0000-0002-2543-2155-
crisitem.author.orcid0000-0003-2372-4581-
crisitem.author.orcid0000-0002-6542-7537-
crisitem.author.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
crisitem.department.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
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