Please use this identifier to cite or link to this item: http://hdl.handle.net/2122/10297
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dc.contributor.authorallSurl, L.; Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich, NR4 7TJ, UKen
dc.contributor.authorallDonohoue, D.; Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich, NR4 7TJ, UK - now at: Department of Chemistry, Lawrence University, Appleton, Wisconsin, 54911, USAen
dc.contributor.authorallAiuppa, A.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italiaen
dc.contributor.authorallBobrowski, N.; Institut für Umweltphysik, Universität Heidelberg, Im Neuenheimer Feld 229, 69120 Heidelberg, Germanyen
dc.contributor.authorallvon Glasow, R.; Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich, NR4 7TJ, UKen
dc.date.accessioned2016-04-13T13:04:39Zen
dc.date.available2016-04-13T13:04:39Zen
dc.date.issued2015-03-09en
dc.identifier.urihttp://hdl.handle.net/2122/10297en
dc.description.abstractVolcanoes are an important source of inorganic halogen species into the atmosphere. Chemical processing of these species generates oxidised, highly reactive, halogen species which catalyse considerable O3 destruction within volcanic plumes. A campaign of ground-based in situ O3, SO2 and meteorology measurements was undertaken at the summit of Mount Etna volcano in July/August 2012. At the same time, spectroscopic measurements were made of BrO and SO2 columns in the plume downwind. Depletions of ozone were seen at all in-plume measurement locations, with average O3 depletions ranging from 11–35 nmol mol􀀀1 (15–45 %). Atmospheric processing times of the plume were estimated to be between 1 and 4 min. A 1-D numerical model of early plume evolution was also used. It was found that in the early plume O3 was destroyed at an approximately constant rate relative to an inert plume tracer. This is ascribed to reactive halogen chemistry, and the data suggests the majority of the reactive halogen that destroys O3 in the early plume is generated within the crater, including a substantial proportion generated in a high-temperature “effective source region” immediately after emission. The model could approximately reproduce the main measured features of the ozone chemistry. Model results show a strong dependence of the near-vent bromine chemistry on the presence or absence of volcanic NOx emissions and suggest that near-vent ozone measurements can be used as a qualitative indicator of NOx emission.en
dc.language.isoEnglishen
dc.relation.ispartofAtmospheric Chemistry and Physics (ACP)en
dc.relation.ispartofseries/15(2015)en
dc.subjectMount Etnaen
dc.subjectPlumeen
dc.subjectdepletion of ozoneen
dc.titleQuantification of the depletion of ozone in the plume of Mount Etnaen
dc.typearticleen
dc.description.statusPublisheden
dc.type.QualityControlPeer-revieweden
dc.description.pagenumber2613–2628en
dc.subject.INGV04. Solid Earth::04.08. Volcanology::04.08.01. Gasesen
dc.identifier.doi10.5194/acp-15-2613-2015en
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dc.description.obiettivoSpecifico4V. Vulcani e ambienteen
dc.description.journalTypeJCR Journalen
dc.description.fulltextopenen
dc.relation.issn1680-7316en
dc.relation.eissn1680-7324en
dc.contributor.authorSurl, L.en
dc.contributor.authorDonohoue, D.en
dc.contributor.authorAiuppa, A.en
dc.contributor.authorBobrowski, N.en
dc.contributor.authorvon Glasow, R.en
dc.contributor.departmentCentre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich, NR4 7TJ, UKen
dc.contributor.departmentCentre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich, NR4 7TJ, UK - now at: Department of Chemistry, Lawrence University, Appleton, Wisconsin, 54911, USAen
dc.contributor.departmentIstituto Nazionale di Geofisica e Vulcanologia, Sezione Palermo, Palermo, Italiaen
dc.contributor.departmentInstitut für Umweltphysik, Universität Heidelberg, Im Neuenheimer Feld 229, 69120 Heidelberg, Germanyen
dc.contributor.departmentCentre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich, NR4 7TJ, UKen
item.openairetypearticle-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.grantfulltextopen-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
crisitem.author.deptCentre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich, NR4 7TJ, UK-
crisitem.author.deptCentre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich, NR4 7TJ, UK - now at: Department of Chemistry, Lawrence University, Appleton, Wisconsin, 54911, USA-
crisitem.author.deptIstituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione Palermo, Palermo, Italia-
crisitem.author.deptSchool of Environmental Sciences, University of East Anglia, Norwich, NR4 7TJ, UK-
crisitem.author.orcid0000-0002-0254-6539-
crisitem.author.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
crisitem.classification.parent04. Solid Earth-
crisitem.department.parentorgIstituto Nazionale di Geofisica e Vulcanologia-
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